A sodium zinc thiostannate Na2ZnSn2S6 is reported with its interesting structural features and property characteristics. It crystallizes in the polar space group Fdd2 （No. 43） with the unit cell parameters ofa=12.94...A sodium zinc thiostannate Na2ZnSn2S6 is reported with its interesting structural features and property characteristics. It crystallizes in the polar space group Fdd2 （No. 43） with the unit cell parameters ofa=12.945（3） A, b=23.556（5） A, c=7.2774（15）/k and Z=8. In its structure, Zn-centered penta-tetrahedra [ZnSn4S15]Z2- clusters arrange regularly along the diagonals of ab and ac planes to form a 3D tunnel structure with charge-balanced Na＋ cations located inside the tunnels. Note that SnS4 tetrahedra connect with each other by sharing comers to form infinite ∞[SnS3]n chains that are rarely found in known alkali-thiostannates. Remarkably, NazZnSnzS6 exhibits the good NLO performances, such as large SHG response （4 times that of AgGaS2 at 55-88 μm under the 2.09 μm radiation）, wide infrared （IR） transmission region （0.35-25 μm） and relatively high laser damage threshold （77.5 MW/cm2, -2 times that of AgGaS2）. Theoretical calculations have also been performed to investigate the structure-property relationship and the results indicate that the origin of NLO effect can be attributed to the penta-tetrahedra [ZnSn4S15]12- clusters.展开更多
基金supported by the Western Light Foundation of Chinese Acad-emy of Scienees(Grant No.XBBS201318)the National Natural Science Foundation of China(Grant Nos.51402352,51425206&91622107)+3 种基金the National Key Research Project(Grant Nos.2016YFB1102302 & 2016YFB0402104)Xinjiang Key Resealvh and Development Program(Grant No.2016B02021)Major Program of Xinjiang Uygur Autonomous Region of China during the 13th Five-Year Plan Period(Grant No.2016A02003)Fund of Key Laboratory of Opmelectronic Materials Chemistry and Physics,Chinese Academy of Sciences(Grant No.2008DP173016).
文摘A sodium zinc thiostannate Na2ZnSn2S6 is reported with its interesting structural features and property characteristics. It crystallizes in the polar space group Fdd2 （No. 43） with the unit cell parameters ofa=12.945（3） A, b=23.556（5） A, c=7.2774（15）/k and Z=8. In its structure, Zn-centered penta-tetrahedra [ZnSn4S15]Z2- clusters arrange regularly along the diagonals of ab and ac planes to form a 3D tunnel structure with charge-balanced Na＋ cations located inside the tunnels. Note that SnS4 tetrahedra connect with each other by sharing comers to form infinite ∞[SnS3]n chains that are rarely found in known alkali-thiostannates. Remarkably, NazZnSnzS6 exhibits the good NLO performances, such as large SHG response （4 times that of AgGaS2 at 55-88 μm under the 2.09 μm radiation）, wide infrared （IR） transmission region （0.35-25 μm） and relatively high laser damage threshold （77.5 MW/cm2, -2 times that of AgGaS2）. Theoretical calculations have also been performed to investigate the structure-property relationship and the results indicate that the origin of NLO effect can be attributed to the penta-tetrahedra [ZnSn4S15]12- clusters.
