The reaction of triplet fusion,also named triplet-triplet annihilation,has attracted a lot of research interests because of its wide applications in photocatalytic,solar cells,and bioimaging.As for the singlet oxygen ...The reaction of triplet fusion,also named triplet-triplet annihilation,has attracted a lot of research interests because of its wide applications in photocatalytic,solar cells,and bioimaging.As for the singlet oxygen photosensitization,the reactive singlet oxygen species are generated through the energy transfers from photosensitizer(PS)to ground triplet oxygen molecule.In this work,we computed the electronic coupling for singlet oxygen photosensitization using the nonadiabatic coupling from the quantum chemical calculation.Then we utilized the molecular orbital(MO)overlaps to approximate it,where the MOs were computed from isolated single molecules.As demonstrated with quantitative results,this approach well describes the distribution of the coupling strength as the function of the intermolecular distance between the sensitizer and O_(2),providing us a simple but effective way to predict the coupling of triplet fusion reactions.展开更多
A novel radio-over-fiber(ROF) scheme to simultaneously generate and transmit the 3rd generation telecommunication(3G) and millimeter-wave(MMW) signals by using a single dual-electrode Mach-Zehnder modulator(MZM) is pr...A novel radio-over-fiber(ROF) scheme to simultaneously generate and transmit the 3rd generation telecommunication(3G) and millimeter-wave(MMW) signals by using a single dual-electrode Mach-Zehnder modulator(MZM) is proposed.There is no apparent nonlinearity induced by the ROF system.By employing this analog ROF signal transmission technique,highly transparent fiber-wireless convergence networks can be realized,which are ideal for multi-standard wireless system operation.展开更多
基金the supports from the Chinese Academy of Sciences(CAS)Institute of Chemistry,CAS+3 种基金the supports from the National Natural Science Foundation of China(No.21933011)the Beijing Municipal Science&Technology Commission(No.Z191100007219009)the K.C.Wong Education Foundationthe support from the National Natural Science Foundation of China(No.21773073)。
文摘The reaction of triplet fusion,also named triplet-triplet annihilation,has attracted a lot of research interests because of its wide applications in photocatalytic,solar cells,and bioimaging.As for the singlet oxygen photosensitization,the reactive singlet oxygen species are generated through the energy transfers from photosensitizer(PS)to ground triplet oxygen molecule.In this work,we computed the electronic coupling for singlet oxygen photosensitization using the nonadiabatic coupling from the quantum chemical calculation.Then we utilized the molecular orbital(MO)overlaps to approximate it,where the MOs were computed from isolated single molecules.As demonstrated with quantitative results,this approach well describes the distribution of the coupling strength as the function of the intermolecular distance between the sensitizer and O_(2),providing us a simple but effective way to predict the coupling of triplet fusion reactions.
基金supported by the National Natural Science Foundation of China(No.61371061)the Zhejiang Provincial Natural Science Foundation of China(Nos.LY12F01010 and LQ13F010007)the Open Fund of the Information and Communication Engineering of Top Key Discipline of Zhejiang Province
文摘A novel radio-over-fiber(ROF) scheme to simultaneously generate and transmit the 3rd generation telecommunication(3G) and millimeter-wave(MMW) signals by using a single dual-electrode Mach-Zehnder modulator(MZM) is proposed.There is no apparent nonlinearity induced by the ROF system.By employing this analog ROF signal transmission technique,highly transparent fiber-wireless convergence networks can be realized,which are ideal for multi-standard wireless system operation.
