A new ruthenium（II） complex with two different types oftridentate ligands was synthesized, 2,2′：6′,2″-terpyridine （tpy） and 2,6-Bis（（N-benzyl）aminomethyl）pyridine （bbap）： [Ru（tpy）（bbap）]2＋ （1）. T...A new ruthenium（II） complex with two different types oftridentate ligands was synthesized, 2,2′：6′,2″-terpyridine （tpy） and 2,6-Bis（（N-benzyl）aminomethyl）pyridine （bbap）： [Ru（tpy）（bbap）]2＋ （1）. This compound was designed to form intramolecular π-π stacking interaction between tpy and substituted benzyl groups of bbap. The single-crystal X-ray diffraction analysis revealed that 1 crystallized with orthorhombic space group Aea2 and the ruthenium center has a distorted octahedral coordination geometry with fully chelated tpy and bbap ligands. Simultaneously, in the crystal structure of 1, the central part of ligating tpy was stacked and sandwiched with a pair of capped benzyl substituent groups of bbap, the nearest atomic distance being N...C = 3.28 A.展开更多
In this paper, the quantum entanglement between a single mode binomial field and a cascade three-level atom is calculated mechanically without the rotating wave approximation. The numerical results indicate that the q...In this paper, the quantum entanglement between a single mode binomial field and a cascade three-level atom is calculated mechanically without the rotating wave approximation. The numerical results indicate that the quantum entanglement at the first few periods is reduced notably due to the fact that the atom is initially in the superposition state. With increasing field parameter 17, the period of the entanglement evolution becomes obvious and the quantum decoherence phenomenon emerges in a short time.展开更多
文摘A new ruthenium（II） complex with two different types oftridentate ligands was synthesized, 2,2′：6′,2″-terpyridine （tpy） and 2,6-Bis（（N-benzyl）aminomethyl）pyridine （bbap）： [Ru（tpy）（bbap）]2＋ （1）. This compound was designed to form intramolecular π-π stacking interaction between tpy and substituted benzyl groups of bbap. The single-crystal X-ray diffraction analysis revealed that 1 crystallized with orthorhombic space group Aea2 and the ruthenium center has a distorted octahedral coordination geometry with fully chelated tpy and bbap ligands. Simultaneously, in the crystal structure of 1, the central part of ligating tpy was stacked and sandwiched with a pair of capped benzyl substituent groups of bbap, the nearest atomic distance being N...C = 3.28 A.
基金supported by the National Natural Science Foundation of China (Grant No. 1097602/A06)
文摘In this paper, the quantum entanglement between a single mode binomial field and a cascade three-level atom is calculated mechanically without the rotating wave approximation. The numerical results indicate that the quantum entanglement at the first few periods is reduced notably due to the fact that the atom is initially in the superposition state. With increasing field parameter 17, the period of the entanglement evolution becomes obvious and the quantum decoherence phenomenon emerges in a short time.
