基于整体-局部位移方法,建立了一种高阶剪切变形理论。整体位移部分采用的是R eddy理论的位移模式(1984),局部位移为L I X Y等(1997)建立的1,2-3理论的局部函数。这一理论使满足自由表面条件的R eddy理论进一步满足层间位移、应力连续,...基于整体-局部位移方法,建立了一种高阶剪切变形理论。整体位移部分采用的是R eddy理论的位移模式(1984),局部位移为L I X Y等(1997)建立的1,2-3理论的局部函数。这一理论使满足自由表面条件的R eddy理论进一步满足层间位移、应力连续,同时有效减少了1,2-3理论的未知数个数。基于此理论深入开展了有限元法研究,建立了满足C1连续条件的精化三节点三角形单元(每个节点参数为9个)。计算结果表明:建立的精化单元能准确计算整体位移和层间应力。展开更多
To investigate the influence of bluff body shape on wall pressure distribution in a vortex flowmeter,experiments were conducted on a specially designed test section in a closed water rig at Reynolds numbers of 6.2...To investigate the influence of bluff body shape on wall pressure distribution in a vortex flowmeter,experiments were conducted on a specially designed test section in a closed water rig at Reynolds numbers of 6.2×10 4-9.3×10 4.The cross sections of the bluff bodies were semicircular,square,and triangular shaped,and there were totally 21 pressure tappings along the conduit to acquire the wall pressures.It is found that the variation trends of wall pressures are basically identical regardless of the bluff body shapes.The wall pressures begin to diverge from 0.3D(D is the inner diameter of the vortex flowmeter) in front of the bluff body due to the diversity in shape,and all reach the minimum values at 0.3D behind the bluff body.A discrepancy between the triangular or square cylinder and the semicircular cylinder in wall pressure change is observed at 0-0.1D behind the bluff body.It is also found that the wall pressures and irrecoverable pressure loss coefficients increase with flow rates,and the triangular cylinder causes the smallest irrecoverable pressure loss at a fixed flow rate.展开更多
This work tries to identify the relationship between geometric configuration of monolith catalysts, and transfer and reaction performances for selective catalytic reduction of N2O with CO. Monolith catalysts with five...This work tries to identify the relationship between geometric configuration of monolith catalysts, and transfer and reaction performances for selective catalytic reduction of N2O with CO. Monolith catalysts with five different channel shapes (circle, regular triangle, rectangle, square and hexagon), was investigated to make a comprehensive comparison of their pressure drop, heat transfer Nu number, mass transfer Sh number and N2O conversion. It was found that monolith catalysts have a much lower pressure drop than that of traditional packed bed, and for monolith catalysts with different channel shapes, pressure drop decreases in the order of regular triangle > rectangle > square > hexagon > circle. The order of Nu is in regular triangle > rectangle ≈ square > hexagon > circle, similar to that of Sh. N2O conversion follows the order of regular triangle > rectangular ≈ square ≈ circle > hexagon. The results indicate that chemical reaction including internal diffusion is the controlling step in the selective catalytic reduction of N2O removal with CO. In addition, channel size and gas velocity also have influence on N2O conversion and pressure drop.展开更多
The theoretical calculation and spectroscopic experiments indicate a kind of triangular three bonding supramolecular complexes CBr4…X^-…-H-C, which consist of carbon tetrabromide, halide, and protic solvent molecule...The theoretical calculation and spectroscopic experiments indicate a kind of triangular three bonding supramolecular complexes CBr4…X^-…-H-C, which consist of carbon tetrabromide, halide, and protic solvent molecule （referring to dichloromethane, chloroform and acetonitrile）, can be formed in solution. The strength of halogen and hydrogen bonds in the triangular complexes using halide as common acceptor obeys the order of iodide〉bromide〉chloride. The halogen and hydrogen bonds work weak-cooperatively. Charge transfer bands of halogen bonding complexes between CBra and halide are observed in UV-Vis absorption spectroscopy in three solvents, and then the stoichiometry of 1：1, formation constants K and molar extinction coefficients ε of the halogen bonding complexes are obtained by Benesi-Hildebrand method. The K and ε show a dependence on the solvent dielectric constant and, on the whole, obey an order of iodide〉bromide〉chloride in the same solvents. Furthermore, the C-H vibrational frequencies of solvent molecules vary obviously with the addition of halide, which indicates the C-H…X- interaction. The experimental data indicate that the halogen bond and hydrogen bond coexist by sharing a common halide acceptor as predicted by calculation.展开更多
文摘基于整体-局部位移方法,建立了一种高阶剪切变形理论。整体位移部分采用的是R eddy理论的位移模式(1984),局部位移为L I X Y等(1997)建立的1,2-3理论的局部函数。这一理论使满足自由表面条件的R eddy理论进一步满足层间位移、应力连续,同时有效减少了1,2-3理论的未知数个数。基于此理论深入开展了有限元法研究,建立了满足C1连续条件的精化三节点三角形单元(每个节点参数为9个)。计算结果表明:建立的精化单元能准确计算整体位移和层间应力。
基金Project(51006125) supported by the National Natural Science Foundation of China
文摘To investigate the influence of bluff body shape on wall pressure distribution in a vortex flowmeter,experiments were conducted on a specially designed test section in a closed water rig at Reynolds numbers of 6.2×10 4-9.3×10 4.The cross sections of the bluff bodies were semicircular,square,and triangular shaped,and there were totally 21 pressure tappings along the conduit to acquire the wall pressures.It is found that the variation trends of wall pressures are basically identical regardless of the bluff body shapes.The wall pressures begin to diverge from 0.3D(D is the inner diameter of the vortex flowmeter) in front of the bluff body due to the diversity in shape,and all reach the minimum values at 0.3D behind the bluff body.A discrepancy between the triangular or square cylinder and the semicircular cylinder in wall pressure change is observed at 0-0.1D behind the bluff body.It is also found that the wall pressures and irrecoverable pressure loss coefficients increase with flow rates,and the triangular cylinder causes the smallest irrecoverable pressure loss at a fixed flow rate.
基金Supported by the National Natural Science Foundation of China （21121064, 21076008） the Projects in the National Science ＆ Technology Pillar Program During the 12th Five-Year Plan Period （2011BAC06B04）
文摘This work tries to identify the relationship between geometric configuration of monolith catalysts, and transfer and reaction performances for selective catalytic reduction of N2O with CO. Monolith catalysts with five different channel shapes (circle, regular triangle, rectangle, square and hexagon), was investigated to make a comprehensive comparison of their pressure drop, heat transfer Nu number, mass transfer Sh number and N2O conversion. It was found that monolith catalysts have a much lower pressure drop than that of traditional packed bed, and for monolith catalysts with different channel shapes, pressure drop decreases in the order of regular triangle > rectangle > square > hexagon > circle. The order of Nu is in regular triangle > rectangle ≈ square > hexagon > circle, similar to that of Sh. N2O conversion follows the order of regular triangle > rectangular ≈ square ≈ circle > hexagon. The results indicate that chemical reaction including internal diffusion is the controlling step in the selective catalytic reduction of N2O removal with CO. In addition, channel size and gas velocity also have influence on N2O conversion and pressure drop.
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.20675009 and No. 90922023）. The basis set aug-cc-pVDZ-PP for iodine atom is downloaded at the website http：//bse.pnl.gov/ bse/portal.
文摘The theoretical calculation and spectroscopic experiments indicate a kind of triangular three bonding supramolecular complexes CBr4…X^-…-H-C, which consist of carbon tetrabromide, halide, and protic solvent molecule （referring to dichloromethane, chloroform and acetonitrile）, can be formed in solution. The strength of halogen and hydrogen bonds in the triangular complexes using halide as common acceptor obeys the order of iodide〉bromide〉chloride. The halogen and hydrogen bonds work weak-cooperatively. Charge transfer bands of halogen bonding complexes between CBra and halide are observed in UV-Vis absorption spectroscopy in three solvents, and then the stoichiometry of 1：1, formation constants K and molar extinction coefficients ε of the halogen bonding complexes are obtained by Benesi-Hildebrand method. The K and ε show a dependence on the solvent dielectric constant and, on the whole, obey an order of iodide〉bromide〉chloride in the same solvents. Furthermore, the C-H vibrational frequencies of solvent molecules vary obviously with the addition of halide, which indicates the C-H…X- interaction. The experimental data indicate that the halogen bond and hydrogen bond coexist by sharing a common halide acceptor as predicted by calculation.
