Based on optimization wharf structure type of triangle flame pier proposed, namely＂ Spatial triangular flame pier ＋ Big span bent which taking Slant supports＂ Simulating three-dimensional pier model of a variety of...Based on optimization wharf structure type of triangle flame pier proposed, namely＂ Spatial triangular flame pier ＋ Big span bent which taking Slant supports＂ Simulating three-dimensional pier model of a variety of conditions in the actual loading by structural finite element software. Under the guidance of the three-dimensional structure of the most unfavorable load combination algorithm, three-dimensional combination algorithm is applied to the new structure by the MATLAB software programming. Search and calculate the most unfavorable combination of action effects and the corresponding intemal force of the main member, checking the feasibility of the three-dimensional algorithms, Calculating the new wharf structure structural features and stability, Providing numerical reference for the design of this sort of wharf.展开更多
The theoretical calculation and spectroscopic experiments indicate a kind of triangular three bonding supramolecular complexes CBr4…X^-…-H-C, which consist of carbon tetrabromide, halide, and protic solvent molecule...The theoretical calculation and spectroscopic experiments indicate a kind of triangular three bonding supramolecular complexes CBr4…X^-…-H-C, which consist of carbon tetrabromide, halide, and protic solvent molecule （referring to dichloromethane, chloroform and acetonitrile）, can be formed in solution. The strength of halogen and hydrogen bonds in the triangular complexes using halide as common acceptor obeys the order of iodide〉bromide〉chloride. The halogen and hydrogen bonds work weak-cooperatively. Charge transfer bands of halogen bonding complexes between CBra and halide are observed in UV-Vis absorption spectroscopy in three solvents, and then the stoichiometry of 1：1, formation constants K and molar extinction coefficients ε of the halogen bonding complexes are obtained by Benesi-Hildebrand method. The K and ε show a dependence on the solvent dielectric constant and, on the whole, obey an order of iodide〉bromide〉chloride in the same solvents. Furthermore, the C-H vibrational frequencies of solvent molecules vary obviously with the addition of halide, which indicates the C-H…X- interaction. The experimental data indicate that the halogen bond and hydrogen bond coexist by sharing a common halide acceptor as predicted by calculation.展开更多
Let N be the Lie algebra of all n x n dominant block upper triangular matrices over a field F. In this paper, we explicitly describe all Lie triple derivations of N when char（F） ≠ 2. As an application, we character...Let N be the Lie algebra of all n x n dominant block upper triangular matrices over a field F. In this paper, we explicitly describe all Lie triple derivations of N when char（F） ≠ 2. As an application, we characterize Lie derivations of N when char（F） ≠ 2.展开更多
文摘Based on optimization wharf structure type of triangle flame pier proposed, namely＂ Spatial triangular flame pier ＋ Big span bent which taking Slant supports＂ Simulating three-dimensional pier model of a variety of conditions in the actual loading by structural finite element software. Under the guidance of the three-dimensional structure of the most unfavorable load combination algorithm, three-dimensional combination algorithm is applied to the new structure by the MATLAB software programming. Search and calculate the most unfavorable combination of action effects and the corresponding intemal force of the main member, checking the feasibility of the three-dimensional algorithms, Calculating the new wharf structure structural features and stability, Providing numerical reference for the design of this sort of wharf.
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.20675009 and No. 90922023）. The basis set aug-cc-pVDZ-PP for iodine atom is downloaded at the website http：//bse.pnl.gov/ bse/portal.
文摘The theoretical calculation and spectroscopic experiments indicate a kind of triangular three bonding supramolecular complexes CBr4…X^-…-H-C, which consist of carbon tetrabromide, halide, and protic solvent molecule （referring to dichloromethane, chloroform and acetonitrile）, can be formed in solution. The strength of halogen and hydrogen bonds in the triangular complexes using halide as common acceptor obeys the order of iodide〉bromide〉chloride. The halogen and hydrogen bonds work weak-cooperatively. Charge transfer bands of halogen bonding complexes between CBra and halide are observed in UV-Vis absorption spectroscopy in three solvents, and then the stoichiometry of 1：1, formation constants K and molar extinction coefficients ε of the halogen bonding complexes are obtained by Benesi-Hildebrand method. The K and ε show a dependence on the solvent dielectric constant and, on the whole, obey an order of iodide〉bromide〉chloride in the same solvents. Furthermore, the C-H vibrational frequencies of solvent molecules vary obviously with the addition of halide, which indicates the C-H…X- interaction. The experimental data indicate that the halogen bond and hydrogen bond coexist by sharing a common halide acceptor as predicted by calculation.
文摘Let N be the Lie algebra of all n x n dominant block upper triangular matrices over a field F. In this paper, we explicitly describe all Lie triple derivations of N when char（F） ≠ 2. As an application, we characterize Lie derivations of N when char（F） ≠ 2.
