The five chemical associations of heavy metals have been extracted continuously using the Tessier extracting method. Results show that Cu, Pb, Fe, Zn and Cr in the sediments are mainly distributed in residual fraction...The five chemical associations of heavy metals have been extracted continuously using the Tessier extracting method. Results show that Cu, Pb, Fe, Zn and Cr in the sediments are mainly distributed in residual fraction, while the major chemical association of Mn is carbonates. Carbonate heavy metals are converted into Fe-Mn oxides in autumn. And in the low tidal flat, after carbonates have changed into ionic heavy metals, some of the elements are transported to the overlying water. Cu, Pb, Fe and Mn have good correlations with each other, and Zn, Cr also show their similarity of chemical behavior in the sediments.展开更多
To realize a stable addition of foaming agent used for foam technology, a new adding method using the jet cavitation was introduced, and its performance was investigated experimentally under different operating condit...To realize a stable addition of foaming agent used for foam technology, a new adding method using the jet cavitation was introduced, and its performance was investigated experimentally under different operating conditions. Experimental results show that the bubble region in the jet device has a constant vapor pressure, which creates a good condition for liquid absorption, while it shrinks with increasing outlet pressure. The liquid absorption amount keeps unchanged when the outlet pressure is lower than a critical value. The critical outlet pressure increases by 40% with decreasing cavitation absorption amount, which is especially suitable for mini-flow quantitative addition of foaming agent used for foam dust suppression. Its effectiveness on suppressing mine dust was evaluated in a heading face of underground coal mines. Field application indicates that the reliable and simple foaming system adopting the new adding method makes a marked dust suppression effect. The working environment of heading face is significantly improved, ensuring the safe tunneling and personal security.展开更多
As a common pollutant of nitrogen in groundwater, nitrate contamination has become a major concern worldwide. Baseflow, one of the dominant hydrological pathways for nitrate migration to streamflow, has been confirmed...As a common pollutant of nitrogen in groundwater, nitrate contamination has become a major concern worldwide. Baseflow, one of the dominant hydrological pathways for nitrate migration to streamflow, has been confirmed as a leading nitrate source for stream water where groundwater or subsurface flow contaminated heavily by nitrate. That is, sufficient improvements of water quality may not be attained without proper management for baseflow, even if non-point sources(NPS) pollutants discharged through surface runoff are being well managed. This article reviews the primary nitrate sources, the main factors affecting its transport, and the methodologies for baseflow nitrate estimation, to give some recommendations for future works, including:(1) giving sufficient consideration for the effects of climatological, morphological, and geological factors on baseflow recessions to obtain more reliable and accurate baseflow separation;(2) trying to solve calibration and validation problems for baseflow loads determining in storm flow period;(3) developing a simple and convenient algorithm with certain physics that can be used to separate baseflow NPS pollution from the total directly in different regions, for a reliable estimation of baseflow NPS pollution at larger scale(e.g., national scale);(4) improving groundwater quality simulation module of existing NPS pollution models to have a better simulation for biogeochemical processes in shallow aquifers;(5) taking integrated measures of "source control", "process interception" and "end remediation" to prevent and control NPS nitrate pollution effectively, not just only the strict control of nutrients loss from surface runoff.展开更多
基金This work is supported by the National Natural Science Focal Projects Foundation of China(Grant No.40131020)the National Natural Science Foundation of China(Grant No.49833030)+2 种基金the Venus Program Foundation for Young Scientists of Shanghai(Grant No.97QA14023)its Tracking Program(Grant No.01QMH1406)the Dawn Program of Shanghai Ecucational Development Foundation.
文摘The five chemical associations of heavy metals have been extracted continuously using the Tessier extracting method. Results show that Cu, Pb, Fe, Zn and Cr in the sediments are mainly distributed in residual fraction, while the major chemical association of Mn is carbonates. Carbonate heavy metals are converted into Fe-Mn oxides in autumn. And in the low tidal flat, after carbonates have changed into ionic heavy metals, some of the elements are transported to the overlying water. Cu, Pb, Fe and Mn have good correlations with each other, and Zn, Cr also show their similarity of chemical behavior in the sediments.
基金Project(51474216)supported by the National Natural Science Foundation of ChinaProject supported by the Priority Academic Program Development(PAPD)of Jiangsu Higher Education Institutions,ChinaProject(2012DXS02)supported by the Fundamental Research Funds for the Central Universities,China
文摘To realize a stable addition of foaming agent used for foam technology, a new adding method using the jet cavitation was introduced, and its performance was investigated experimentally under different operating conditions. Experimental results show that the bubble region in the jet device has a constant vapor pressure, which creates a good condition for liquid absorption, while it shrinks with increasing outlet pressure. The liquid absorption amount keeps unchanged when the outlet pressure is lower than a critical value. The critical outlet pressure increases by 40% with decreasing cavitation absorption amount, which is especially suitable for mini-flow quantitative addition of foaming agent used for foam dust suppression. Its effectiveness on suppressing mine dust was evaluated in a heading face of underground coal mines. Field application indicates that the reliable and simple foaming system adopting the new adding method makes a marked dust suppression effect. The working environment of heading face is significantly improved, ensuring the safe tunneling and personal security.
基金supported by the National Natural Science Foundation of China(Grant No.41571216)the Chinese National Key Technology R&D Program(Grant No.2012BAC17B01)
文摘As a common pollutant of nitrogen in groundwater, nitrate contamination has become a major concern worldwide. Baseflow, one of the dominant hydrological pathways for nitrate migration to streamflow, has been confirmed as a leading nitrate source for stream water where groundwater or subsurface flow contaminated heavily by nitrate. That is, sufficient improvements of water quality may not be attained without proper management for baseflow, even if non-point sources(NPS) pollutants discharged through surface runoff are being well managed. This article reviews the primary nitrate sources, the main factors affecting its transport, and the methodologies for baseflow nitrate estimation, to give some recommendations for future works, including:(1) giving sufficient consideration for the effects of climatological, morphological, and geological factors on baseflow recessions to obtain more reliable and accurate baseflow separation;(2) trying to solve calibration and validation problems for baseflow loads determining in storm flow period;(3) developing a simple and convenient algorithm with certain physics that can be used to separate baseflow NPS pollution from the total directly in different regions, for a reliable estimation of baseflow NPS pollution at larger scale(e.g., national scale);(4) improving groundwater quality simulation module of existing NPS pollution models to have a better simulation for biogeochemical processes in shallow aquifers;(5) taking integrated measures of "source control", "process interception" and "end remediation" to prevent and control NPS nitrate pollution effectively, not just only the strict control of nutrients loss from surface runoff.
