Three chiral aminopyridine ligands derived from L-proline were prepared. Careful evaluation of the corresponding aminopyridine manganese complexes in asymmetric epoxidation of olefins revealed a broad substrate scope ...Three chiral aminopyridine ligands derived from L-proline were prepared. Careful evaluation of the corresponding aminopyridine manganese complexes in asymmetric epoxidation of olefins revealed a broad substrate scope in the presence of 0.2 mol% manganese complex and 0.5 equiv. 2,2-dimethylbutyric acid, with aqueous hydrogen peroxide as an oxidant. A variety of olefins including styrenes, chromenes, and cinnamamides were transformed successfully into the target epoxides with moderate to excellent enantioselectivity（yield up to 95%, ee up to 99%）.展开更多
In this paper we propose a tripartite scheme for splitting an arbitrary 2-qubit quantum information by using two asymmetric W states as the quantum channel. In the schemem if the two recipients collaborate together, t...In this paper we propose a tripartite scheme for splitting an arbitrary 2-qubit quantum information by using two asymmetric W states as the quantum channel. In the schemem if the two recipients collaborate together, they can deterministically recover the quantum information by performing first a 4-qubit collective unitary operation and then two single-qubit unitary operations. In addition, since the asymmetric W states are employed as the quantum channel, the scheme is robust against decoherence.展开更多
The main classical schools of Chinese philosophy can be characterized as process thinking and their concepts are related to those of Whitehead＇s philosophy of organism. （Neo-）Confucianism, Daoism, and Chinese Buddh...The main classical schools of Chinese philosophy can be characterized as process thinking and their concepts are related to those of Whitehead＇s philosophy of organism. （Neo-）Confucianism, Daoism, and Chinese Buddhism all find their roots in the Yi ding with a strong emphasis on human experience of the flux of time. These Eastern and Western world views allow attempts to consciously experience experiential reality in terms of immanent transcendence. These attempts are discussed also by considering the functioning of the human brain, emphasizing the importance of brain asymmetry.展开更多
Based on a modified version of the global color symmetry model,the pion susceptibilities of vacuum needed in the QCD sum rule external-field method for the coupling of pseudoscalar current to hadron have bean calculat...Based on a modified version of the global color symmetry model,the pion susceptibilities of vacuum needed in the QCD sum rule external-field method for the coupling of pseudoscalar current to hadron have bean calculated beyond the vacuum saturation approximation.Comparison with the previous estimations has been given.展开更多
The mechanical and microstructural properties as well as crystallographic textures of asymmetrically rolled low carbon steel were studied.The modelling of plastic deformation was carried out in two scales:in the macro...The mechanical and microstructural properties as well as crystallographic textures of asymmetrically rolled low carbon steel were studied.The modelling of plastic deformation was carried out in two scales:in the macro-scale,using the finite elements method,and in the crystallographic scale,using the polycrystalline deformation model.The internal stress distribution in the rolling gap was calculated using the finite elements method and these stresses were then applied to the polycrystalline elasto-plastic deformation model.Selected mechanical properties,namely residual stress distribution,deformation work,applied force and torques,and bend amplitude,were calculated.The diffraction measurements,X-ray and electron backscatter diffraction,enabled the examination of texture heterogeneity and selected microstructure characteristics.The predicted textures agree well with those determined experimentally.The plastic anisotropy of cold rolled ferritic steel samples,connected with texture,was expressed by Lankford coefficient.展开更多
The three-body force effects on the equation of state and its iso-spin dependence of asymmetric nuclear matter and on the proton fraction in neutron star matter have been investigated within Brueckner-Hartree-Fock app...The three-body force effects on the equation of state and its iso-spin dependence of asymmetric nuclear matter and on the proton fraction in neutron star matter have been investigated within Brueckner-Hartree-Fock approach by using a microscopic three-body force. It is shown that, even in the presence of the three-body force, the empirical parabolic law of the energy per nucleon vs. isospin asymmetry is fulfilled in the whole asymmetry range and also up to high density. The three-body force provides a strong enhancement of symmetry energy at high density in agreement with relativistic approaches. It also shows that the three-body force leads to a much more rapid increasing of symmetry energy with density in relatively high density region and to a much lower threshold density for the direct URCA process to occur in a neutron star as compared to the predictions adopting only pure two-body force.展开更多
基金supported by the National Natural Science Foundation of China(21473226,21773273)Key Research Program of Frontier Sciences,CAS(QYZDJ-SSW-SLH051)Natural Science Foundation of Jiangsu Province(BK20170420)~~
文摘Three chiral aminopyridine ligands derived from L-proline were prepared. Careful evaluation of the corresponding aminopyridine manganese complexes in asymmetric epoxidation of olefins revealed a broad substrate scope in the presence of 0.2 mol% manganese complex and 0.5 equiv. 2,2-dimethylbutyric acid, with aqueous hydrogen peroxide as an oxidant. A variety of olefins including styrenes, chromenes, and cinnamamides were transformed successfully into the target epoxides with moderate to excellent enantioselectivity（yield up to 95%, ee up to 99%）.
基金supported by Program for New Century Excellent Talents in Universities of China under Grant No.NCET-06-0554the National Natural Science Foundation of China under Grant Nos.60677001 and 10747146+3 种基金the Science-Technology Fund of Anhui Province for Outstanding Youth under Grant No.06042087the Key Fund of the Ministry of Education of China under Grant No.206063the Natural Science Foundation of Guangdong Province under Grant Nos.06300345 and 7007806the Talent Foundation of High Education of Anhui Province for Outstanding Youth under Grant No.2009SQRZ056
文摘In this paper we propose a tripartite scheme for splitting an arbitrary 2-qubit quantum information by using two asymmetric W states as the quantum channel. In the schemem if the two recipients collaborate together, they can deterministically recover the quantum information by performing first a 4-qubit collective unitary operation and then two single-qubit unitary operations. In addition, since the asymmetric W states are employed as the quantum channel, the scheme is robust against decoherence.
文摘The main classical schools of Chinese philosophy can be characterized as process thinking and their concepts are related to those of Whitehead＇s philosophy of organism. （Neo-）Confucianism, Daoism, and Chinese Buddhism all find their roots in the Yi ding with a strong emphasis on human experience of the flux of time. These Eastern and Western world views allow attempts to consciously experience experiential reality in terms of immanent transcendence. These attempts are discussed also by considering the functioning of the human brain, emphasizing the importance of brain asymmetry.
文摘Based on a modified version of the global color symmetry model,the pion susceptibilities of vacuum needed in the QCD sum rule external-field method for the coupling of pseudoscalar current to hadron have bean calculated beyond the vacuum saturation approximation.Comparison with the previous estimations has been given.
基金Projects(DEC-2011/01/B/ST8/07394,DEC-2011/01/D/ST8/07399)supported by the Polish National Centre for Science(NCN)The support of the Polish Ministry of Science and Higher Education and of the French ANR 05-BLAN-0383 project
文摘The mechanical and microstructural properties as well as crystallographic textures of asymmetrically rolled low carbon steel were studied.The modelling of plastic deformation was carried out in two scales:in the macro-scale,using the finite elements method,and in the crystallographic scale,using the polycrystalline deformation model.The internal stress distribution in the rolling gap was calculated using the finite elements method and these stresses were then applied to the polycrystalline elasto-plastic deformation model.Selected mechanical properties,namely residual stress distribution,deformation work,applied force and torques,and bend amplitude,were calculated.The diffraction measurements,X-ray and electron backscatter diffraction,enabled the examination of texture heterogeneity and selected microstructure characteristics.The predicted textures agree well with those determined experimentally.The plastic anisotropy of cold rolled ferritic steel samples,connected with texture,was expressed by Lankford coefficient.
文摘The three-body force effects on the equation of state and its iso-spin dependence of asymmetric nuclear matter and on the proton fraction in neutron star matter have been investigated within Brueckner-Hartree-Fock approach by using a microscopic three-body force. It is shown that, even in the presence of the three-body force, the empirical parabolic law of the energy per nucleon vs. isospin asymmetry is fulfilled in the whole asymmetry range and also up to high density. The three-body force provides a strong enhancement of symmetry energy at high density in agreement with relativistic approaches. It also shows that the three-body force leads to a much more rapid increasing of symmetry energy with density in relatively high density region and to a much lower threshold density for the direct URCA process to occur in a neutron star as compared to the predictions adopting only pure two-body force.
