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比热和直流磁化率证明N^+H…O^-氢键的电子自旋翻转在D-和L-丙氨酸单晶中的不对称相变(英文) 被引量:2
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作者 王文清 沈新春 +3 位作者 吴季兰 龚䶮 申国华 赵洪凯 《物理化学学报》 SCIE CAS CSCD 北大核心 2012年第4期773-780,共8页
为了解决D-和L-丙氨酸在约270K相变的分岐和机理,对其单晶、多晶粉末及原料利用微分扫描量热仪测定比热.用三线法以蓝宝石作校正,并与手册的D-和L-丙氨酸标准比热值比较.在单晶中,实验观察到吸热相变峰最高处时的温度及热焓为:D-丙氨酸,... 为了解决D-和L-丙氨酸在约270K相变的分岐和机理,对其单晶、多晶粉末及原料利用微分扫描量热仪测定比热.用三线法以蓝宝石作校正,并与手册的D-和L-丙氨酸标准比热值比较.在单晶中,实验观察到吸热相变峰最高处时的温度及热焓为:D-丙氨酸,Tc=272.02K,△H=1.87J·mol-1;L-丙氨酸,Tc=271.85K,△H=1.46J·mol-1;热焓差为0.41J·mol-1.参比晶体D-缬氨酸,Tc=273.59K,△H=1.75J·mol-1;L-缬氨酸,Tc=273.76K,△H=1.57J·mol-1;热焓差为0.18J·mol-1.实验发现已测量过的单晶磨成多晶粉末后再测,相变峰消失.说明相变与晶格有关.变温中子衍射排除了D→L的构型相变,但发现N+H…O-氢键沿D-和L-丙氨酸单晶的c轴反向变化.变温偏振拉曼散射反映相变机制与N+H…O-中电子的轨道磁偶极矩相关,观察到偏振光的不对称散射.在外加磁场强度H为+1T和-1T下,变温测定D-和L-丙氨酸晶体的直流磁化率,证明在270K有电子自旋翻转的相变.电子自旋的向上或向下,取决于晶格中NH+3的扭曲振动及N+H…O-氢键沿晶体c轴的方向.由于自旋的定轴性,可以解释单晶和多晶粉末比热结果的分岐. 展开更多
关键词 比热 直流磁化率 N+H…O-氢键 电子自旋翻转 不对称相变 D-和L-丙氨酸单晶
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Perturbation to Unified Symmetry and Adiabatic Invariants for Relativistic Hamilton Systems 被引量:1
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作者 ZHANG Ming-Jiang FANG Jian-Hui LU Kai PANG Ting LIN Peng 《Communications in Theoretical Physics》 SCIE CAS CSCD 2009年第6期961-966,共6页
Based on the concept of adiabatic invariant, the perturbation to unified symmetry and adiabatic invariants for relativistic Hamilton systems are studied. The definition of the perturbation to unified symmetry for the ... Based on the concept of adiabatic invariant, the perturbation to unified symmetry and adiabatic invariants for relativistic Hamilton systems are studied. The definition of the perturbation to unified symmetry for the system is presented, and the criterion of the perturbation to unified symmetry is given. Meanwhile, the Noether adiabatic invariants, the generalized Hojman adiabatic invariants, and the Mei adiabatic invariants for the perturbed system are obtained. 展开更多
关键词 unified symmetry PERTURBATION adiabatic invariant relativistic Hamilton system
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Scheme to Implement Optimal Asymmetric Economical Phase-Covariant Quantum Cloning in Cavity QED
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作者 ZHANG Wen-Hai DAI Jie-Lin YE Liu 《Communications in Theoretical Physics》 SCIE CAS CSCD 2008年第6期1473-1476,共4页
We propose an experimentally feasible scheme to implement the optimal asymmetric economical 1→2 phase-covariant quantum cloning in two dimensions based on the cavity QED technique. The protocol is very simple and onl... We propose an experimentally feasible scheme to implement the optimal asymmetric economical 1→2 phase-covariant quantum cloning in two dimensions based on the cavity QED technique. The protocol is very simple and only two atoms are required. Our scheme is insensitive to the cavity field states and cavity decay. During the processes, the cavity is only virtually excited and it thus greatly prolongs the efficient decoherent time. Therefore, it may be realized in experiment. 展开更多
关键词 optimal asymmetric economical phase-covariant cloning cavity QED
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A Numerical Study of Tidal Asymmetry: Preferable Asymmetry of Nonlinear Mechanisms in Xiangshan Bay, East China Sea
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作者 XU Peng MAO Xinyan +1 位作者 JIANG Wensheng ZHOU Liangming 《Journal of Ocean University of China》 SCIE CAS 2014年第5期733-741,共9页
In-situ measurements in Xiangshan Bay, the East China Sea, show that the duration of the rising tide is shorter than that of the falling tide around the bay mouth, while it becomes much longer in the inner bay. A fini... In-situ measurements in Xiangshan Bay, the East China Sea, show that the duration of the rising tide is shorter than that of the falling tide around the bay mouth, while it becomes much longer in the inner bay. A finite volume coastal ocean model(FVCOM) with an unstructured mesh was applied to simulate the asymmetric tidal field of Xiangshan Bay. The model reproduced the observed tidal elevations and currents successfully. Several numerical experiments were conducted to clarify the roles of primary mechanisms underlying the asymmetric tidal field. According to the model results, the time-varying channel depth and nonlinear advection prefer shorter duration of the rising tide in Xiangshan Bay, while the time-varying bay width favors longer duration of the rising tide. The overtides generated by these two opposite types of nonlinear mechanisms are out of phase, resulting in smaller M4 amplitude than the sumfold of each individual contribution. Although the bottom friction as a nonlinear mechanism contributes little to the generation of overtide M4, it is regarded as a mechanism that could cause a shorter duration of the rising tide, for it can slow down the M2 phase speed much more than it slows down the M4 phase speed. The time-varying depth, nonlinear advection and bottom friction are dominating factors around the bay mouth, while the time-varying width dominates in the inner bay, causing the tidal elevation asymmetry to be inverted along the bay. 展开更多
关键词 FVCOM tidal asymmetry Xiangshan Bay nonlinear mechanisms
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Generalized Coherent States for Position-Dependent Effective Mass Systems
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作者 Naila Amir Shahid Iqbal 《Communications in Theoretical Physics》 SCIE CAS CSCD 2016年第12期615-620,共6页
A generalized scheme for the construction of coherent states in the context of position-dependent effective mass systems has been presented. This formalism is based on the ladder operators and associated algebra of th... A generalized scheme for the construction of coherent states in the context of position-dependent effective mass systems has been presented. This formalism is based on the ladder operators and associated algebra of the system which are obtained using the concepts of supersymmetric quantum mechanics and the property of shape invariance. In order to exemplify the general results and to analyze the properties of the coherent states, several examples have been considered. 展开更多
关键词 generalized coherent states supersymmetric quantum mechanics shape invariance ladder operators position-dependent effective mass systems non-linear oscillators Mandel parameter subPoissonian statistics
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