The ordered weighted geometric averaging(OWGA) operator is extended to accommodate uncertain conditions where all input arguments take the forms of interval numbers. First, a possibility degree formula for the compa...The ordered weighted geometric averaging(OWGA) operator is extended to accommodate uncertain conditions where all input arguments take the forms of interval numbers. First, a possibility degree formula for the comparison between interval numbers is introduced. It is proved that the introduced formula is equivalent to the existing formulae, and also some desired properties of the possibility degree is presented. Secondly, the uncertain OWGA operator is investigated in which the associated weighting parameters cannot be specified, but value ranges can be obtained and the associated aggregated values of an uncertain OWGA operator are known. A linear objective-programming model is established; by solving this model, the associated weights vector of an uncertain OWGA operator can be determined, and also the estimated aggregated values of the alternatives can be obtained. Then the alternatives can be ranked by the comparison of the estimated aggregated values using the possibility degree formula. Finally, a numerical example is given to show the feasibility and effectiveness of the developed method.展开更多
[Objective]The aim was to study on the characteristics of soil organic carbon and nitrogen in rubber (Hevea brasiliensis Muell-Arg) plantations at different age stages in the western region of Hainan Island,so as to...[Objective]The aim was to study on the characteristics of soil organic carbon and nitrogen in rubber (Hevea brasiliensis Muell-Arg) plantations at different age stages in the western region of Hainan Island,so as to evaluate the ecological benefits of rubber plantations and provide basic data for studying the effect of tropical land utilization/cover change on the global carbon and nitrogen cycle. [Method]The situs was in Danzhou city,western region of Hainan Island,and the samples were four kinds of rubber plantations soil at different ages and one kind of control check (pepper,Piper nigrum L.) soil. In this research,four quadrats were set up in each sample,and the size of each was 20 cm×20 cm. Four specimens were gathered from four layers of 0-15,15-30,30-45,45-60,and the average of them was the last analysis result of each sample. Soil density was measured by cutting ring method,soil containing and hygroscopic water was detected by oven drying method,soil organic carbon (SOC) was measured by low temperature heated outside potassium dichromate oxidation-colorimetry method,and soil total nitrogen (STN) was detected by semimicro Kjeldahl method. [Result]SOC contents of different layers in rubber plantations soil at different age stages (including the CK pepper soil,the same as below) varied little,and the content of SOC in surface layer (0-15 cm) was higher,while the underlayer (45-60 cm) was lower than the average value; there was significant difference in SOC content among different kinds of soil,and the content was of 6.03-7.78 g/kg,tapping young trees (7 years) CK pepper mature age trees (30 years) prophase of young trees (2 years) tapping trees (16 years); there was no significant difference in SOC storage among different kinds of soil,and the storage was of 61.33-74.29 t/hm2,mature age trees (30 years) tapping young trees (7 years) prophase of young trees (2 years) CK pepper tapping trees (16 years); there was significant difference in STN content among rubber plantations soil at different age stages,the content was of 410.86-664.14 mg/kg2,CK pepper tapping young trees (7 years) prophase of young trees (2 years) mature age trees (30 years) tapping trees (16 years),and STN content of tapping trees (16 years) soil was extremely lowest; there was significant difference in C/N ratio among different kinds of soil,the ratio was of 10.94-14.47,and the ratio of tapping trees (16 years) mature age trees (30 years) tapping young trees (7 years) CK pepper prophase of young trees (2 years). [Conclusion]There wasn't unhealthy effect of rubber trees planted in tropical area on the content and storage of SOC,the content of STN and the ratio of C/N. there was no significant difference between rubber plantations and CK pepper soil,and the effects of rubber plantation on soil carbon-nitrogen was similar to that of other tropical crops (such as pepper).展开更多
The enamines, iminium ions, and oxazolidinones are thought to be the key intermediates in the proline-catalyzed reactions of aldehydes or ketones, but there is an extensive contro- versy about their roles. Here, the c...The enamines, iminium ions, and oxazolidinones are thought to be the key intermediates in the proline-catalyzed reactions of aldehydes or ketones, but there is an extensive contro- versy about their roles. Here, the corresponding transition states connecting any two of the three kinds of species are located at the wB97XD/6-311++G** level of theory. The calcula- tions demonstrate that the oxazolidinones are the predominant species in both the gas phase and solvents; there exists tautomeric equilibrium among these species and the equilibriums are controlled by the employed solvents and temperature in the reaction. These results demonstrate that the concentration and role of the mentioned species are controlled by the employed solvent and temperature. A new reaction pathway is presented herein for the trans- formation between iminium ions and oxazolidinones through iminium ion-water complex and oxazolidinone-water complex. The calculations demonstrate that the rate-limiting step in proline-catalyzed Mannich reaction between acetaldehyde/keteones and N-Boc imines is the formation of the C-C bond rather than the intermediates tautomerization. These calculations rationalize the available experimental observations and can be valuable in optimizing the experimental conditions of asymmetric organic-catalyzed reactions of aldehydes or ketones.展开更多
By establishing equivalent fixed point theorem, the boundary value problems of p Laplace equations with finite time delay are studied. It’s the first time that the functional differential equation is discussed w...By establishing equivalent fixed point theorem, the boundary value problems of p Laplace equations with finite time delay are studied. It’s the first time that the functional differential equation is discussed with p Laplacian. The topological degree and fixed point theorem on cone are used to prove the existence of solution and positive solution. The conditions are all easy to check.展开更多
According to the failure characteristics of aircraft structure, a delay-time model is an effective method to optimize maintenance for aircraft structure. To imitate the practical situation as much as possible, imperfe...According to the failure characteristics of aircraft structure, a delay-time model is an effective method to optimize maintenance for aircraft structure. To imitate the practical situation as much as possible, imperfect inspections, thresholds and repeated intervals are concerned in delay-time models. Since the suggestion by the existing delay-time models that the inspections are implemented in an infinite time span lacks practical value, a de- lay-time model with imperfect inspection within a finite time span is proposed. In the model, the nonhomogenous Poisson process is adopted to obtain the renewal probabilities between two different successive inspections on de- fects or failures. An algorithm is applied based on the Nelder-Mead downhill simplex method to solve the model. Finally, a numerical example proves the validity and effectiveness of the model.展开更多
The operator splitting method is used to deal with the Navier-Stokes equation, in which the physical process described by the equation is decomposed into two processes: a diffusion process and a convection process; a...The operator splitting method is used to deal with the Navier-Stokes equation, in which the physical process described by the equation is decomposed into two processes: a diffusion process and a convection process; and the finite element equation is established. The velocity field in the element is described by the shape function of the isoparametric element with nine nodes and the pressure field is described by the interpolation function of the four nodes at the vertex of the isoparametric element with nine nodes. The subroutine of the element and the integrated finite element code are generated by the Finite Element Program Generator (FEPG) successfully. The numerical simulation about the incompressible viscous liquid flowing over a cylinder is carded out. The solution agrees with the experimental results very well.展开更多
Wavefields in porous media saturated by two immiscible fluids are simulated in this paper.Based on the sealed system theory,the medium model considers both the relative motion between the fluids and the solid skeleton...Wavefields in porous media saturated by two immiscible fluids are simulated in this paper.Based on the sealed system theory,the medium model considers both the relative motion between the fluids and the solid skeleton and the relaxation mechanisms of porosity and saturation(capillary pressure).So it accurately simulates the numerical attenuation property of the wavefields and is much closer to actual earth media in exploration than the equivalent liquid model and the unsaturated porous medium model on the basis of open system theory.The velocity and attenuation for different wave modes in this medium have been discussed in previous literature but studies of the complete wave-field have not been reported.In our work,wave equations with the relaxation mechanisms of capillary pressure and the porosity are derived.Furthermore,the wavefield and its characteristics are studied using the numerical finite element method.The results show that the slow P3-wave in the non-wetting phase can be observed clearly in the seismic band.The relaxation of capillary pressure and the porosity greatly affect the displacement of the non-wetting phase.More specifically,the displacement decreases with increasing relaxation coefficient.展开更多
A new algorithm based on the projection method with the implicit finite difference technique was established to calculate the velocity fields and pressure.The calculation region can be divided into different regions a...A new algorithm based on the projection method with the implicit finite difference technique was established to calculate the velocity fields and pressure.The calculation region can be divided into different regions according to Reynolds number.In the far-wall region,the thermal melt flow was calculated as Newtonian flow.In the near-wall region,the thermal melt flow was calculated as non-Newtonian flow.It was proved that the new algorithm based on the projection method with the implicit technique was correct through nonparametric statistics method and experiment.The simulation results show that the new algorithm based on the projection method with the implicit technique calculates more quickly than the solution algorithm-volume of fluid method using the explicit difference method.展开更多
Abstract: Physical, chemical and biological soil properties in surface (0-5 cm) and subsurface soil (5-15 cm) were determined in a field experiment conducted with seven treatments consisted of different combinati...Abstract: Physical, chemical and biological soil properties in surface (0-5 cm) and subsurface soil (5-15 cm) were determined in a field experiment conducted with seven treatments consisted of different combinations of fertilizer N (0, 100 and 200 kg N ha^-1), P (0, 22 and 44 kg P2O5 ha^-1) and K (0, 41 and 82 kg K2O ha^-1) applied both to summer-grown maize (Zea mays L.) and winter-grown wheat (Triticum aestivum L.) crops continuously for 37 years under irrigated subtropical conditions. Application of N, P and K significantly increased water stable aggregates and had profound effects in increasing the mean weight diameter as well as the formation of macro-aggregates, which were highest in both surface (81%) and subsurface (74%) soil layers with application of 100 kg N + 22 kg P2O5 + 41 kg K2O ha^-1 (N100P22K41). The N100P22K41 treatment also enhanced total organic C (TOC) from 4.4 g kg^-1 in no-NPK control to 4.8 g kg^-1in surface layer and from 3.3 to 4.1 g kg1 in subsurface layer leading to the 20% higher TOC stocks in 0-15 cm soil. The labile C and N fractions such as water soluble C, particulate and light fraction organic matter, potentially mineralizable N and microbial biomass were also highest under the optimized balanced application of N100P22K41. Relatively higher increase in all labile fractions of C and N as proportion of TOC and total N, respectively suggested that these are potential indicators to reflect changes in management practices long before changes in TOC and TN are detectable. These results demonstrated that optimized balanced application of N, P and K is crucial for improving soil health ensuring long-term sustainability of farming systems in semiarid subtropical soils.展开更多
In acoustic logging-while-drilling (ALWD) finite difference in time domain (FDTD) simulations, large drill collar occupies, most of the fluid-filled borehole and divides the borehole fluid into two thin fluid colu...In acoustic logging-while-drilling (ALWD) finite difference in time domain (FDTD) simulations, large drill collar occupies, most of the fluid-filled borehole and divides the borehole fluid into two thin fluid columns (radius -27 mm). Fine grids and large computational models are required to model the thin fluid region between the tool and the formation. As a result, small time step and more iterations are needed, which increases the cumulative numerical error. Furthermore, due to high impedance contrast between the drill collar and fluid in the borehole (the difference is 〉30 times), the stability and efficiency of the perfectly matched layer (PML) scheme is critical to simulate complicated wave modes accurately. In this paper, we compared four different PML implementations in a staggered grid finite difference in time domain (FDTD) in the ALWD simulation, including field-splitting PML (SPML), multiaxial PML(M- PML), non-splitting PML (NPML), and complex frequency-shifted PML (CFS-PML). The comparison indicated that NPML and CFS-PML can absorb the guided wave reflection from the computational boundaries more efficiently than SPML and M-PML. For large simulation time, SPML, M-PML, and NPML are numerically unstable. However, the stability of M-PML can be improved further to some extent. Based on the analysis, we proposed that the CFS-PML method is used in FDTD to eliminate the numerical instability and to improve the efficiency of absorption in the PML layers for LWD modeling. The optimal values of CFS-PML parameters in the LWD simulation were investigated based on thousands of 3D simulations. For typical LWD cases, the best maximum value of the quadratic damping profile was obtained using one do. The optimal parameter space for the maximum value of the linear frequency-shifted factor (a0) and the scaling factor (β0) depended on the thickness of the PML layer. For typical formations, if the PML thickness is 10 grid points, the global error can be reduced to 〈1% using the optimal PML parameters, and the error will decrease as the PML thickness increases.展开更多
A novel quantitative structure-property relationship (QSPR) model for estimating the solution surface tension of 92 organic compounds at 20℃ was developed based on newly introduced atom-type topological indices. Th...A novel quantitative structure-property relationship (QSPR) model for estimating the solution surface tension of 92 organic compounds at 20℃ was developed based on newly introduced atom-type topological indices. The data set contained non-polar and polar liquids, and saturated and unsaturated compounds. The regression analysis shows that excellent result is obtained with multiple linear regression. The predictive power of the proposed model was discussed using the leave-one-out (LOO) cross-validated (CV) method. The correlation coefficient (R) and the leave-one-out cross-validation correlation coefficient (Rcv) of multiple linear regression model are 0.991 4 and 0.991 3, respectively. The new model gives the average absolute relative deviation of 1.81% for 92 substances. The result demonstrates that novel topological indices based on the equilibrium electro-negativity of atom and the relative bond length are useful model parameters for QSPR analysis of compounds.展开更多
This paper presents an experimental study on the emission characteristics and combustion instabilities of oxy-fuel combustions in a swirl-stabilized combustor. Different oxygen concentrations (Xoxy=25%~45%, where Xox...This paper presents an experimental study on the emission characteristics and combustion instabilities of oxy-fuel combustions in a swirl-stabilized combustor. Different oxygen concentrations (Xoxy=25%~45%, where Xoxy is oxygen concentra- tion by volume), equivalence ratios (φ=0.75~1.15) and combustion powers (CP=1.08~2.02 kW) were investigated in the oxy-fuel (CH4/CO2/O2) combustions, and reference cases (Xoxy=25%~35%, CH4/N2/O2 flames) were covered. The results show that the oxygen concentration in the oxidant stream significantly affects the combustion delay in the oxy-fuel flames, and the equivalence ratio has a slight effect, whereas the combustion power shows no impact. The temperature levels of the oxy-fuel flames inside the combustion chamber are much higher (up to 38.7%) than those of the reference cases. Carbon monoxide was vastly produced when Xoxy>35% or φ>0.95 in the oxy-fuel flames, while no nitric oxide was found in the exhaust gases because no N2 participates in the combustion process. The combustion instability of the oxy-fuel combustion is very different from those of the reference cases with similar oxygen content. Oxy-fuel combustions excite strong oscillations in all cases studied Xoxy=25%~45%. However, no pressure fluctuations were detected in the reference cases when Xoxy>28.6% accomplished by heavily sooting flames which were not found in the oxy-fuel combustions. Spectrum analysis shows that the frequency of dynamic pressure oscillations exhibits randomness in the range of 50~250 Hz, therefore resulting in a very small resultant amplitude. Temporal oscillations are very strong with amplitudes larger than 200 Pa, even short time fast Fourier transform (FFT) analysis (0.08 s) shows that the pressure amplitude can be larger than 40 Pa.展开更多
In the tracking problem for the maritime radiation source by a passive sensor,there are three main difficulties,i.e.,the poor observability of the radiation source,the detection uncertainty(false and missed detections...In the tracking problem for the maritime radiation source by a passive sensor,there are three main difficulties,i.e.,the poor observability of the radiation source,the detection uncertainty(false and missed detections)and the uncertainty of the target appearing/disappearing in the field of view.These difficulties can make the establishment or maintenance of the radiation source target track invalid.By incorporating the elevation information of the passive sensor into the automatic bearings-only tracking(BOT)and consolidating these uncertainties under the framework of random finite set(RFS),a novel approach for tracking maritime radiation source target with intermittent measurement was proposed.Under the RFS framework,the target state was represented as a set that can take on either an empty set or a singleton; meanwhile,the measurement uncertainty was modeled as a Bernoulli random finite set.Moreover,the elevation information of the sensor platform was introduced to ensure observability of passive measurements and obtain the unique target localization.Simulation experiments verify the validity of the proposed approach for tracking maritime radiation source and demonstrate the superiority of the proposed approach in comparison with the traditional integrated probabilistic data association(IPDA)method.The tracking performance under different conditions,particularly involving different existence probabilities and different appearance durations of the target,indicates that the method to solve our problem is robust and effective.展开更多
The boundedness is proved under more general structural conditions to solutions of elliptic variational inequalities and a priori estimates are obtained to maximum modulus of solutions for some special cases.
基金The Technological Innovation Foundation of NanjingForestry University(No.163060033).
文摘The ordered weighted geometric averaging(OWGA) operator is extended to accommodate uncertain conditions where all input arguments take the forms of interval numbers. First, a possibility degree formula for the comparison between interval numbers is introduced. It is proved that the introduced formula is equivalent to the existing formulae, and also some desired properties of the possibility degree is presented. Secondly, the uncertain OWGA operator is investigated in which the associated weighting parameters cannot be specified, but value ranges can be obtained and the associated aggregated values of an uncertain OWGA operator are known. A linear objective-programming model is established; by solving this model, the associated weights vector of an uncertain OWGA operator can be determined, and also the estimated aggregated values of the alternatives can be obtained. Then the alternatives can be ranked by the comparison of the estimated aggregated values using the possibility degree formula. Finally, a numerical example is given to show the feasibility and effectiveness of the developed method.
基金Supported by the Project of the Basic Research Operation Cost of State Level Research Institutes "Long-term Location Investigation of Basic Data for Rubber Production " ( XJSYWFZX-2008-14 and XJSYWFZX-2007-2)the Project Natural Sciences Fund of Hainan Province (807045)~~
文摘[Objective]The aim was to study on the characteristics of soil organic carbon and nitrogen in rubber (Hevea brasiliensis Muell-Arg) plantations at different age stages in the western region of Hainan Island,so as to evaluate the ecological benefits of rubber plantations and provide basic data for studying the effect of tropical land utilization/cover change on the global carbon and nitrogen cycle. [Method]The situs was in Danzhou city,western region of Hainan Island,and the samples were four kinds of rubber plantations soil at different ages and one kind of control check (pepper,Piper nigrum L.) soil. In this research,four quadrats were set up in each sample,and the size of each was 20 cm×20 cm. Four specimens were gathered from four layers of 0-15,15-30,30-45,45-60,and the average of them was the last analysis result of each sample. Soil density was measured by cutting ring method,soil containing and hygroscopic water was detected by oven drying method,soil organic carbon (SOC) was measured by low temperature heated outside potassium dichromate oxidation-colorimetry method,and soil total nitrogen (STN) was detected by semimicro Kjeldahl method. [Result]SOC contents of different layers in rubber plantations soil at different age stages (including the CK pepper soil,the same as below) varied little,and the content of SOC in surface layer (0-15 cm) was higher,while the underlayer (45-60 cm) was lower than the average value; there was significant difference in SOC content among different kinds of soil,and the content was of 6.03-7.78 g/kg,tapping young trees (7 years) CK pepper mature age trees (30 years) prophase of young trees (2 years) tapping trees (16 years); there was no significant difference in SOC storage among different kinds of soil,and the storage was of 61.33-74.29 t/hm2,mature age trees (30 years) tapping young trees (7 years) prophase of young trees (2 years) CK pepper tapping trees (16 years); there was significant difference in STN content among rubber plantations soil at different age stages,the content was of 410.86-664.14 mg/kg2,CK pepper tapping young trees (7 years) prophase of young trees (2 years) mature age trees (30 years) tapping trees (16 years),and STN content of tapping trees (16 years) soil was extremely lowest; there was significant difference in C/N ratio among different kinds of soil,the ratio was of 10.94-14.47,and the ratio of tapping trees (16 years) mature age trees (30 years) tapping young trees (7 years) CK pepper prophase of young trees (2 years). [Conclusion]There wasn't unhealthy effect of rubber trees planted in tropical area on the content and storage of SOC,the content of STN and the ratio of C/N. there was no significant difference between rubber plantations and CK pepper soil,and the effects of rubber plantation on soil carbon-nitrogen was similar to that of other tropical crops (such as pepper).
文摘The enamines, iminium ions, and oxazolidinones are thought to be the key intermediates in the proline-catalyzed reactions of aldehydes or ketones, but there is an extensive contro- versy about their roles. Here, the corresponding transition states connecting any two of the three kinds of species are located at the wB97XD/6-311++G** level of theory. The calcula- tions demonstrate that the oxazolidinones are the predominant species in both the gas phase and solvents; there exists tautomeric equilibrium among these species and the equilibriums are controlled by the employed solvents and temperature in the reaction. These results demonstrate that the concentration and role of the mentioned species are controlled by the employed solvent and temperature. A new reaction pathway is presented herein for the trans- formation between iminium ions and oxazolidinones through iminium ion-water complex and oxazolidinone-water complex. The calculations demonstrate that the rate-limiting step in proline-catalyzed Mannich reaction between acetaldehyde/keteones and N-Boc imines is the formation of the C-C bond rather than the intermediates tautomerization. These calculations rationalize the available experimental observations and can be valuable in optimizing the experimental conditions of asymmetric organic-catalyzed reactions of aldehydes or ketones.
文摘By establishing equivalent fixed point theorem, the boundary value problems of p Laplace equations with finite time delay are studied. It’s the first time that the functional differential equation is discussed with p Laplacian. The topological degree and fixed point theorem on cone are used to prove the existence of solution and positive solution. The conditions are all easy to check.
基金Supported by the National Natural Science Foundation of China(61079013)the Natural Science Fund Project in Jiangsu Province(BK2011737)~~
文摘According to the failure characteristics of aircraft structure, a delay-time model is an effective method to optimize maintenance for aircraft structure. To imitate the practical situation as much as possible, imperfect inspections, thresholds and repeated intervals are concerned in delay-time models. Since the suggestion by the existing delay-time models that the inspections are implemented in an infinite time span lacks practical value, a de- lay-time model with imperfect inspection within a finite time span is proposed. In the model, the nonhomogenous Poisson process is adopted to obtain the renewal probabilities between two different successive inspections on de- fects or failures. An algorithm is applied based on the Nelder-Mead downhill simplex method to solve the model. Finally, a numerical example proves the validity and effectiveness of the model.
文摘The operator splitting method is used to deal with the Navier-Stokes equation, in which the physical process described by the equation is decomposed into two processes: a diffusion process and a convection process; and the finite element equation is established. The velocity field in the element is described by the shape function of the isoparametric element with nine nodes and the pressure field is described by the interpolation function of the four nodes at the vertex of the isoparametric element with nine nodes. The subroutine of the element and the integrated finite element code are generated by the Finite Element Program Generator (FEPG) successfully. The numerical simulation about the incompressible viscous liquid flowing over a cylinder is carded out. The solution agrees with the experimental results very well.
基金supported by the 973 Program (Grant No.2007CB209505)the National Natural Science Foundation of China (Grant No.40674061,40704019)
文摘Wavefields in porous media saturated by two immiscible fluids are simulated in this paper.Based on the sealed system theory,the medium model considers both the relative motion between the fluids and the solid skeleton and the relaxation mechanisms of porosity and saturation(capillary pressure).So it accurately simulates the numerical attenuation property of the wavefields and is much closer to actual earth media in exploration than the equivalent liquid model and the unsaturated porous medium model on the basis of open system theory.The velocity and attenuation for different wave modes in this medium have been discussed in previous literature but studies of the complete wave-field have not been reported.In our work,wave equations with the relaxation mechanisms of capillary pressure and the porosity are derived.Furthermore,the wavefield and its characteristics are studied using the numerical finite element method.The results show that the slow P3-wave in the non-wetting phase can be observed clearly in the seismic band.The relaxation of capillary pressure and the porosity greatly affect the displacement of the non-wetting phase.More specifically,the displacement decreases with increasing relaxation coefficient.
基金Project (50975263) supported by the National Natural Science Foundation of ChinaProject (2010081015) supported by International Cooperation Project of Shanxi Province, China+1 种基金 Project (2010-78) supported by the Scholarship Council in Shanxi province, ChinaProject (2010420120005) supported by Doctoral Fund of Ministry of Education of China
文摘A new algorithm based on the projection method with the implicit finite difference technique was established to calculate the velocity fields and pressure.The calculation region can be divided into different regions according to Reynolds number.In the far-wall region,the thermal melt flow was calculated as Newtonian flow.In the near-wall region,the thermal melt flow was calculated as non-Newtonian flow.It was proved that the new algorithm based on the projection method with the implicit technique was correct through nonparametric statistics method and experiment.The simulation results show that the new algorithm based on the projection method with the implicit technique calculates more quickly than the solution algorithm-volume of fluid method using the explicit difference method.
文摘Abstract: Physical, chemical and biological soil properties in surface (0-5 cm) and subsurface soil (5-15 cm) were determined in a field experiment conducted with seven treatments consisted of different combinations of fertilizer N (0, 100 and 200 kg N ha^-1), P (0, 22 and 44 kg P2O5 ha^-1) and K (0, 41 and 82 kg K2O ha^-1) applied both to summer-grown maize (Zea mays L.) and winter-grown wheat (Triticum aestivum L.) crops continuously for 37 years under irrigated subtropical conditions. Application of N, P and K significantly increased water stable aggregates and had profound effects in increasing the mean weight diameter as well as the formation of macro-aggregates, which were highest in both surface (81%) and subsurface (74%) soil layers with application of 100 kg N + 22 kg P2O5 + 41 kg K2O ha^-1 (N100P22K41). The N100P22K41 treatment also enhanced total organic C (TOC) from 4.4 g kg^-1 in no-NPK control to 4.8 g kg^-1in surface layer and from 3.3 to 4.1 g kg1 in subsurface layer leading to the 20% higher TOC stocks in 0-15 cm soil. The labile C and N fractions such as water soluble C, particulate and light fraction organic matter, potentially mineralizable N and microbial biomass were also highest under the optimized balanced application of N100P22K41. Relatively higher increase in all labile fractions of C and N as proportion of TOC and total N, respectively suggested that these are potential indicators to reflect changes in management practices long before changes in TOC and TN are detectable. These results demonstrated that optimized balanced application of N, P and K is crucial for improving soil health ensuring long-term sustainability of farming systems in semiarid subtropical soils.
基金supported by NSFC(No.41174118)one of the major state S&T special projects(No.2008ZX05020-004)+1 种基金a Postdoctoral Fellowship of China(No.2013M530106)China Scholarship Council(No.2010644006)
文摘In acoustic logging-while-drilling (ALWD) finite difference in time domain (FDTD) simulations, large drill collar occupies, most of the fluid-filled borehole and divides the borehole fluid into two thin fluid columns (radius -27 mm). Fine grids and large computational models are required to model the thin fluid region between the tool and the formation. As a result, small time step and more iterations are needed, which increases the cumulative numerical error. Furthermore, due to high impedance contrast between the drill collar and fluid in the borehole (the difference is 〉30 times), the stability and efficiency of the perfectly matched layer (PML) scheme is critical to simulate complicated wave modes accurately. In this paper, we compared four different PML implementations in a staggered grid finite difference in time domain (FDTD) in the ALWD simulation, including field-splitting PML (SPML), multiaxial PML(M- PML), non-splitting PML (NPML), and complex frequency-shifted PML (CFS-PML). The comparison indicated that NPML and CFS-PML can absorb the guided wave reflection from the computational boundaries more efficiently than SPML and M-PML. For large simulation time, SPML, M-PML, and NPML are numerically unstable. However, the stability of M-PML can be improved further to some extent. Based on the analysis, we proposed that the CFS-PML method is used in FDTD to eliminate the numerical instability and to improve the efficiency of absorption in the PML layers for LWD modeling. The optimal values of CFS-PML parameters in the LWD simulation were investigated based on thousands of 3D simulations. For typical LWD cases, the best maximum value of the quadratic damping profile was obtained using one do. The optimal parameter space for the maximum value of the linear frequency-shifted factor (a0) and the scaling factor (β0) depended on the thickness of the PML layer. For typical formations, if the PML thickness is 10 grid points, the global error can be reduced to 〈1% using the optimal PML parameters, and the error will decrease as the PML thickness increases.
基金Projects(20775010,21075011) supported by the National Natural Science Foundation of ChinaProject(2008AA05Z405) supported by the National High Technology Research and Development Program of China+2 种基金Project(09JJ3016) supported by Hunan Provincial Natural Science Foundation,ChinaProject(09C066) supported by Scientific Research Fund of Hunan Provincial Education Department,ChinaProject(2010CL01) supported by the Foundation of Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation,China
文摘A novel quantitative structure-property relationship (QSPR) model for estimating the solution surface tension of 92 organic compounds at 20℃ was developed based on newly introduced atom-type topological indices. The data set contained non-polar and polar liquids, and saturated and unsaturated compounds. The regression analysis shows that excellent result is obtained with multiple linear regression. The predictive power of the proposed model was discussed using the leave-one-out (LOO) cross-validated (CV) method. The correlation coefficient (R) and the leave-one-out cross-validation correlation coefficient (Rcv) of multiple linear regression model are 0.991 4 and 0.991 3, respectively. The new model gives the average absolute relative deviation of 1.81% for 92 substances. The result demonstrates that novel topological indices based on the equilibrium electro-negativity of atom and the relative bond length are useful model parameters for QSPR analysis of compounds.
基金Project supported by the National Natural Science Foundation of China (No. 50576081)Zhejiang Provincial Natural Science Foundation of China (No. R107532)+1 种基金Program for the New Century Excellent Talents in University (No. NCET-07-0761)the Foundation for the Author of National Excellent Doctoral Dissertation of China (No. 200747)
文摘This paper presents an experimental study on the emission characteristics and combustion instabilities of oxy-fuel combustions in a swirl-stabilized combustor. Different oxygen concentrations (Xoxy=25%~45%, where Xoxy is oxygen concentra- tion by volume), equivalence ratios (φ=0.75~1.15) and combustion powers (CP=1.08~2.02 kW) were investigated in the oxy-fuel (CH4/CO2/O2) combustions, and reference cases (Xoxy=25%~35%, CH4/N2/O2 flames) were covered. The results show that the oxygen concentration in the oxidant stream significantly affects the combustion delay in the oxy-fuel flames, and the equivalence ratio has a slight effect, whereas the combustion power shows no impact. The temperature levels of the oxy-fuel flames inside the combustion chamber are much higher (up to 38.7%) than those of the reference cases. Carbon monoxide was vastly produced when Xoxy>35% or φ>0.95 in the oxy-fuel flames, while no nitric oxide was found in the exhaust gases because no N2 participates in the combustion process. The combustion instability of the oxy-fuel combustion is very different from those of the reference cases with similar oxygen content. Oxy-fuel combustions excite strong oscillations in all cases studied Xoxy=25%~45%. However, no pressure fluctuations were detected in the reference cases when Xoxy>28.6% accomplished by heavily sooting flames which were not found in the oxy-fuel combustions. Spectrum analysis shows that the frequency of dynamic pressure oscillations exhibits randomness in the range of 50~250 Hz, therefore resulting in a very small resultant amplitude. Temporal oscillations are very strong with amplitudes larger than 200 Pa, even short time fast Fourier transform (FFT) analysis (0.08 s) shows that the pressure amplitude can be larger than 40 Pa.
基金Project(61101186)supported by the National Natural Science Foundation of China
文摘In the tracking problem for the maritime radiation source by a passive sensor,there are three main difficulties,i.e.,the poor observability of the radiation source,the detection uncertainty(false and missed detections)and the uncertainty of the target appearing/disappearing in the field of view.These difficulties can make the establishment or maintenance of the radiation source target track invalid.By incorporating the elevation information of the passive sensor into the automatic bearings-only tracking(BOT)and consolidating these uncertainties under the framework of random finite set(RFS),a novel approach for tracking maritime radiation source target with intermittent measurement was proposed.Under the RFS framework,the target state was represented as a set that can take on either an empty set or a singleton; meanwhile,the measurement uncertainty was modeled as a Bernoulli random finite set.Moreover,the elevation information of the sensor platform was introduced to ensure observability of passive measurements and obtain the unique target localization.Simulation experiments verify the validity of the proposed approach for tracking maritime radiation source and demonstrate the superiority of the proposed approach in comparison with the traditional integrated probabilistic data association(IPDA)method.The tracking performance under different conditions,particularly involving different existence probabilities and different appearance durations of the target,indicates that the method to solve our problem is robust and effective.
文摘The boundedness is proved under more general structural conditions to solutions of elliptic variational inequalities and a priori estimates are obtained to maximum modulus of solutions for some special cases.