刘翔退赛微博的“热”与“冷”——以钻石联赛伦敦站为例

北京时间2012年7月14时凌晨2:00,钻石联赛110米栏伦敦站决赛打响,遗憾的是,一直备受关注的刘翔突然宣布因伤为保安全退出比赛,世界一片哗然。更为热闹的是微博,大家纷纷发表看法,当然是骂声多于同情声。在这些骂声和同情声的微博内容背后,我们看到了微博的真实与无奈,微博世界里的"热"与"冷"。

Numerical simulation of diffusion process for oxidative dehydrogenation of butene to butadiene

A comprehensive single particle model which includes the mesoscale and microscale models was developed to study the influence of particle diameter on mass and heat transfer occurring within a ferrite catalyst during the oxidative dehydrogenation of butene to butadiene process. The verified model can be used to investigate the influence of catalyst diameter on the flow distribution inside the particle. The simulation results demonstrate that the mass fraction gradients of all species, temperature gradient and pressure gradient increase with the increase of the particle diameter. It means that there is a high intraparticle transfer resistance and strong diffusion when applying the large catalysts. The external particle mass transfer resistance is nearly constant under different particle diameters so that the effect of particle diameter at external diffusion can be ignored. A large particle diameter can lead to a high surface temperature, which indicates the external heat transfer resistance. Moreover, the selectivity of reaction may be changed with a variety of particle diameters so that choosing appropriate particle size can enhance the production of butadiene and optimize the reaction process.

Entropy Increase and Nature of Separation

The entropy increase (EI) and the entropy increase per unit time (EIPUT) of the solute zone are chosen as new criteria of separation efficiency in chromatography and electrophoresis. It is verified by grand canonical ensemble (GCE) that the kinetic energy distribution of the solute is a common characteristic of the entropy and the distribution of solute zones.Under the assumptions. EI of the solute system is directly proportional to the logarithm of the difference between one and one half of the substantial separation ratio. the ratio of moles of a sparated solute to its total moles. and EIPUT is direchy proportional to corrected separation rate of separation system. EI or EIPUT is a important bridge between separation efficiency of chromatography or electrophoresis and operating parameters, especially. when nonequilibriumthermodynamics(NET) would be adopted.

Matching between mechanics and thermodynamics among 4 individual strokes in a 4-stroke engine by non-circular gear mechanism

The relationship between engine mechanics and thermo-dynamics has been investigated by means of numerical simulation.The inherent mismatching between the mechanical behaviors and the thermodynamic process in internal combustion engine is identified,which is believed to be one of the important limiting factors of energy efficiency for conventional engines available in the current market.An approach for engine efficiency improvement through optimal matching between mechanics and thermodynamics(OMBMT)is proposed.An ideal matching model is defined and the conflicts due to the constraints among the mapping strokes in a 4-stroke engine are analyzed.A novel mechanical model is built for approaching optimal matching among all 4 individual strokes in a 4-stroke spark-ignition engine,which is composed of non-circular gears(NCG)and integrated with conventional slider crank engine mechanism.By means of digital mechanical model and numerical simulation,the matching gains among all 4 strokes are defined and calculated for quantifying the NCG engine efficiency improvement by comparing with a baseline engine.The potentials with the OMBMT implemented and the enhancements made by NCG mechanism for engines in terms of overall engine efficiency are reported.Based on the results achieved,it is recommended that the feasibility studies and the experimental validations should be conducted to verify the engine matching concept and effectiveness of the NCG mechanism engine model proposed,and the engine performance and NCG design parameters should be further optimized.

Numerical Convergence of the Sinc Discrete Variable Representation for Solving Molecular Vibrational States with a Conical Intersection in Adiabatic Representation

Within the Born-Oppenheimer(BO)approximation,nuclear motions of a molecule are often envisioned to occur on an adiabatic potential energy surface(PES).However,this single PES picture should be reconsidered if a conical intersection(CI)is present,although the energy is well below the CI.The presence of the CI results in two additional terms in the nuclear Hamiltonian in the adiabatic presentation,i.e.,the diagonal BO correction(DBOC)and the geometric phase(GP),which are divergent at the CI.At the same time,there are cusps in the adiabatic PESs.Thus usually it is regarded that there is numerical difficulty in a quantum dynamics calculation for treating CI in the adiabatic representation.A popular numerical method in nuclear quantum dynamics calculations is the Sinc discrete variable representation(DVR)method.We examine the numerical accuracy of the Sinc DVR method for solving the Schrodinger equation of a two dimensional model of two electronic states with a CI in both the adiabatic and diabatic representation.The results suggest that the Sinc DVR method is capable of giving reliable results in the adiabatic representation with usual density of the grid points,without special treatment of the divergence of the DBOC and the GP.The numerical uncertainty is not worse than that after the introduction of an arbitrary vector potential for accounting the GP,whose accurate form usually is not easy to obtain.

Rational construction of thermally stable single atom catalysts:From atomic structure to practical applications

As a new frontier in catalysis field,single-atom catalysts(SACs)hold unique electronic structure and high atom utilization,which have displayed unprecedented activity and selectivity toward a wide range of catalytic reactions.However,many reported SACs are susceptible to Ostwald ripening process in high temperature environment or long-term catalytic application,which will cause sintering and deactivation.This is due to the weak interaction between the metal atom and supports.The regeneration and recycling of deactivated catalysts will greatly increase the time and economic cost of industrial production.Therefore,it is necessary to develop SACs with excellent thermal stability to meet the industrial demands.Here,we discuss the fundamental comprehension of the stability of thermally stable SACs obtained from different synthesis methods.The influences of the speciation of metal centers and coordination environments on thermal stability are summarized.The importance of using novel in situ and operando characterizations to reveal dynamic structural evolution under synthesis and reaction conditions and to identify active sites of thermally stable SACs is highlighted.The mechanistic understanding of the unique role of thermally stable SACs in thermocatalytic application is also discussed.At last,a brief perspective on the remaining challenges and future directions of thermally stable SACs is presented.

Community social capital on fighting dengue fever in suburban Surabaya, Indonesia: A qualitative study

Purpose:Dengue hemorraghic fever(DHF)is a communicable disease that is difficult to manage,espe-cially in tropical countries.Social capital is believed to be able to improve the ability of entire com-munities to work together to solve a collective health problem.This study aimed to describe the existing social capital in a community and how it was used to fight DHF.Methods:Qualitative descriptive methods were used,and in-depth interviews were conducted with 13 participants.This study was conducted in the Sawahan sub-district,Surabaya,Indonesia,an endemic area that combats DHF every year.Findings:Results showed that social capital as a community feature provides the main cornerstone of collective action.The creation of social groups,intersectoral collaboration,mutual assistance in cleaning,and voluntary work were visible forms of social capital in the prevention and control of DHF.Support from strong leaders also had significant implications.Conclusions:This study showed that social capital was an important feature,which,if managed,used and accessed properly,would be able to provide ideas for solving community problems.

Review and Prospect of the UN Efforts for Sustainable Development

The present paper reviews the UN important efforts to promote global sustainable development in the chronological order since UN Conference on Human Environment in 1972, and ana- lyzes the progress and gap. The results show that the UN system has made great efforts for global sustainable development since the UN Conference on Human Environment, especially since UN Conference on Environment and Development, promoted the for- mation of important consensus and multilateral internhtional con- ventions on many fields, boosted the development of partnership in the field of sustainable development, and accelerated actions for sustainable development of many countries and regions. However, at present, the progress made is still far below the level required, prominently reflected in the slow progress toward the millen-nium development goals, the difficulties in negotiations in the field of environment and development, insufficient fulfillment of international agreements and conventions, and undesirable effects of partnership in the field of sustainable development. Based on these, the paper puts forward four suggestions for UN Conference on Sustainable Development in 2012（Rio＋20）： （1） to revitalize the ＂spirit of Rio＂ and accelerate the implementation of existing politi- cal commitments; （2） to make new political commitments focusing on climate change and other major global challenges under the Rio principles; （3） to lay out a blueprint of green economy under the Rio principles; and （4） to promote South-South cooperation as the focus of international cooperation.

The Extension and Utilization of the Pasture in the Tropical Area of China

This paper summarized the research and development of pasture in the tropical areas,and simply generalized the problems and methods for improvement and expected the advancement of the tropical pasture.

Effect of an electrostatic field on gas adsorption and diffusion in tectonic coal

The characteristics of adsorption, desorption, and diffusion of gas in tectonic coal are important for the prediction of coal and gas outbursts. Three types of coal samples, of which both metamorphic grade and degree of damage is different, were selected from Tongchun, Qilin, and Pingdingshan mines. Using a series of experiments in an electrostatic field, we analyzed the characteristics of gas adsorption and diffusion in tectonic coal. We found that gas adsorption in coal conforms to the Langmuir equation in an electrostatic field. Both the depth of the adsorption potential well and the coal molecular electroneg- ativity increases under the action of an electrostatic field. A Joule heating effect was caused by changing the coal-gas system conductivity in an electrostatic field. The quantity of gas adsorbed and AP result from competition between the depth of the adsorption potential well, the coal molecular electronegativ- ity, and the Joule heating effect. △P peaks when the three factors control behavior equally. Compared with anthracite, the impact of the electrostatic field on the gas diffusion capacity of middle and high rank coals is greater. Compared with the original coal, the gas adsorption quantity,△P, and the gas diffusion capacity of tectonic coal are greater in an electrostatic field. In addition, the smaller the particle size of tectonic coal, the larger the△P.

Research and Development of Heat-Resistant Materials for Advanced USC Power Plants with Steam Temperatures of 700℃ and Above

Materials-development projects for advanced ultra-supercritical(A-USC) power plants with steam temperatures of 700℃ and above have been performed in order to achieve high efficiency and low CO_2 emissions in Europe, the US, Japan, and recently in China and India as well. These projects involve the replacement of martensitic 9%–12% Cr steels with nickel(Ni)-base alloys for the highest temperature boiler and turbine components in order to provide sufficient creep strength at 700℃ and above. To minimize the requirement for expensive Ni-base alloys, martensitic 9%–12% Cr steels can be applied to the next highest temperature components of an A-USC power plant, up to a maximum of 650℃. This paper comprehensively describes the research and development of Ni-base alloys and martensitic 9%–12% Cr steels for thick section boiler and turbine components of A-USC power plants, mainly focusing on the long-term creep-rupture strength of base metal and welded joints, strength loss in welded joints, creep-fatigue properties, and microstructure evolution during exposure at elevated temperatures.

Research and Development of Hot Primary Air Heater for Coal-Fired Boilers in Power Plant

The reasons of introducing cold air into pulverizer are analyzed for boilers with large capacity and high parameters. The temperature rises of the exhaust gas are calculated when varying the amount of the cold air. The hot primary air heater, a new technology, is developed to eliminate the cold air from the pulverized coal system. The applications, advantages and disadvantages are introduced in detail for the new device and system. It is concluded that introducing cold air into pulverizer is one of the major factors that causes the exhaust gas temperature of boilers with large capacity to be high. The amount of the cold air could be reduced signif icantly, even to zero in some cases by adopting the hot primary air heater, which drops the exhaust gas temperature of the boiler effectively. The hot primary air heater, which could play part roles of the steam-air heater or the hot air recirculation system, could also be used to adjust the exhaust gas temperature within the range of 20 ℃ by controlling the flow rate of the cooling medium. Moreover, the startup period of the steam-air heater or the hot air recirculation system will be shortened, which is a unique advantage of the hot primary air heater among the measures to drop the exhaust gas temperature.

Uncertainty and Sensitivity Analysis for the HELIOS Loop within the LACANES Benchmark

Within the OECD/NEA Benchmarking of Thermal-Hydraulic Loop Models for Lead-Alloy Cooled Advanced Nuclear Energy Systems （LACANES）, the Institute for Neutron Physics and Reactor Technology takes part in the validation process of system codes and the characterization of the thermal-hydraulic behavior of an experimental loop operated with liquid lead-bismuth-eutectics. To confirm the calculations, the results were compared to experimental data obtained from the HELIOS facility at the Seoul National University and to the results of other benchmark participants. The comparison showed that the calculations are within measurement tolerance but nevertheless discrepancies among the participants exist. The pressure drop estimation is determined by a variety of empirical correlations for the friction and the form loss coefficients. Hence, uncertainty and sensitivity measures were applied to find out which parameter is more relevant for the overall pressure drop. In the frame of this investigation, the system code TRACE and the software system for uncertainty and sensitivity, SUSA, were used. The results show that the total pressure drop varies between -30 and ＋15% related to the reference case.

Effect of rib height on turbulent flow and heat transfer of kerosene in rectangular duct

The coupling effects of rib heights and fluid properties on turbulent convective heat transfer of kerosene flow through the rectangular duct on the ribbed bottom wall are studied numerically in this paper.The numerical simulation is based on the ten components surrogate model of kerosene and the Reynolds average method combined with the re-normalized group(RNG)k-εturbulence model.The turbulent vortex structures and heat transfer characteristics of kerosene flowing over rectangular ribs of different heights are obtained.The results show that three dimensional vortices are generated by the ribs,and the vortices alter local flow significantly,leading to both enhanced and reduced convective heat transfer at different locations near the ribs.In addition,it is found that with the increase of rib height,the average Nusselt number and the wall friction factor on the ribbed wall also increase.For the present study,the maximum heat transfer enhancement rate of kerosene flow is 72.16%,and the ratio of rib-to-duct height is 0.75.

Application of Program Generation Technology in Solving Heat and Flow Problems

Based on a new DIY concept for software development, an automatic program-generating technology attached on a software system called as Finite Element Program Generator （FEPG） provides a platform of developing programs, through which a scientific researcher can submit his special physico-mathematical problem to the system in a more direct and convenient way for solution. For solving flow and heat problems by using finite element method, the stabilization technologies and fraction-step methods are adopted to overcome the numerical difficul- ties caused mainly due to the dominated convection. A couple of benchmark problems are given in this paper as examples to illustrate the usage and the superiority of the automatic program generation technique, including the flow in a lid-driven cavity, the starting flow in a circular pipe, the natural convection in a square cavity, and the flow past a circular cylinder, etc. They are also shown as the verification of the algorithms.