According to IPCC （Intergovemmental Panel on Climate Change） Fourth Report, carbon dioxide emissions from the combustion of fossil fuels have been identified as the major contributor to global warming and climate ch...According to IPCC （Intergovemmental Panel on Climate Change） Fourth Report, carbon dioxide emissions from the combustion of fossil fuels have been identified as the major contributor to global warming and climate change. One of the new approaches for capturing carbon dioxide and subsequently lowering the emissions is based on gas hydrate crystallization. Gas hydrates have a large capacity for the storage of gases which also resemble an attractive method for gas filtration. The basis of the separation is the selective partition of the target component between the hydrate phase and the gaseous phase. It is expected that carbon dioxide is preferentially encaged into the hydrate crystal phase compared to the other components. In the present paper, after a comparison of gas hydrates with existing capture technologies, a novel apparatus for gas hydrate production is illustrated and results of a first set of experimental applications of the reactor for CO2 hydrate formation and separation are presented. In particular, the effects of two different promoters were investigated. Results show that the reactor allows a good level of temperature control, resulting in rapid hydrate formation and mild operating conditions. Results are a basis for setting up a procedure for CO2 separation and capture.展开更多
文摘According to IPCC （Intergovemmental Panel on Climate Change） Fourth Report, carbon dioxide emissions from the combustion of fossil fuels have been identified as the major contributor to global warming and climate change. One of the new approaches for capturing carbon dioxide and subsequently lowering the emissions is based on gas hydrate crystallization. Gas hydrates have a large capacity for the storage of gases which also resemble an attractive method for gas filtration. The basis of the separation is the selective partition of the target component between the hydrate phase and the gaseous phase. It is expected that carbon dioxide is preferentially encaged into the hydrate crystal phase compared to the other components. In the present paper, after a comparison of gas hydrates with existing capture technologies, a novel apparatus for gas hydrate production is illustrated and results of a first set of experimental applications of the reactor for CO2 hydrate formation and separation are presented. In particular, the effects of two different promoters were investigated. Results show that the reactor allows a good level of temperature control, resulting in rapid hydrate formation and mild operating conditions. Results are a basis for setting up a procedure for CO2 separation and capture.
