Acrylonitrile-methyl methacrylate （AN-MMA） copolymer/silica nanocomposites were synthesized by in-situ emulsion polymerization initiated by 2,2＇-azobis（2-amidinopropane） dihydrochloride absorbed onto colloidal si...Acrylonitrile-methyl methacrylate （AN-MMA） copolymer/silica nanocomposites were synthesized by in-situ emulsion polymerization initiated by 2,2＇-azobis（2-amidinopropane） dihydrochloride absorbed onto colloidal silica particles, and the mesoporous carbon materials were prepared through carbonization of the obtained AN-MMA copolymer/silica nanocomposites, followed by HF etching. Thermogravimetric analysis of AN-MMAcopolymer/silica nanocomposltes snoweO mat me caroon ylelCl or copolymer was slgnuy oecreaseo as Silica parucle incorporated. N2 adsorption-desorption, scan electron microscopy （SEM） and transmission electron microscopy （TEM） were used to characterize the structure and morphology of the mesoporous carbon materials. Both SEM and展开更多
The chemical industry is nowadays predominantly using fossil raw materials,but the alternative use of bio-based resources is investigated to account for the foreseeable scarcity of fossil feedstocks.A main challenge o...The chemical industry is nowadays predominantly using fossil raw materials,but the alternative use of bio-based resources is investigated to account for the foreseeable scarcity of fossil feedstocks.A main challenge of using biobased feedstocks is the complexity of the impurity profile.For an economic production of bio-based chemicals,the use of intensified processes is inevitable and approaches are needed for the various process intensification techniques to identify their applicability to be used for the production of bio-based components.In the presented study,an approach is shown for the reactive distillation(RD) technology to identify the most critical bio-based impurities and their impact on the reactive distillation process.The investigated case-study is the production of n-butyl acrylate from acrylic acid and n-butanol.Among all initially identified impurities,the key impurities,having the biggest impact on the product purity in the reactive distillation process,are found.These impurities are then studied in more detail and an operating window depending on the impurity concentration is identified for the reactive distillation column.Furthermore,an integrated design of upstream and downstream processes is facilitated,as the presented results can be used in the development of the fermentation processes for the production of the bio-based reactants by decreasing the concentration of the critical impurities.展开更多
20125312环保产品PA6BCF地毯丝Chemical Fiber Internatioal,2010,62(1),p.6(英)2012年1月在德国汉诺威的Domotex地毯展览会上,德国Xentrys Leune公司展出其PA6BCF地毯丝,展品不仅是地毯丝的特种产品,而且,也作为建筑行业可持续发展的...20125312环保产品PA6BCF地毯丝Chemical Fiber Internatioal,2010,62(1),p.6(英)2012年1月在德国汉诺威的Domotex地毯展览会上,德国Xentrys Leune公司展出其PA6BCF地毯丝,展品不仅是地毯丝的特种产品,而且,也作为建筑行业可持续发展的合作伙伴。Xentrys公司作为比利时Dom o集团的一部分,是首家得到IBC(Institute for Construction and the Environment)严格按照EN15804验证的"环保产品声明"(EPD)的地毯丝生产企业。展开更多
基金Supported by the Program for New Century Excellent Talents in University (NCET-07-0738)
文摘Acrylonitrile-methyl methacrylate （AN-MMA） copolymer/silica nanocomposites were synthesized by in-situ emulsion polymerization initiated by 2,2＇-azobis（2-amidinopropane） dihydrochloride absorbed onto colloidal silica particles, and the mesoporous carbon materials were prepared through carbonization of the obtained AN-MMA copolymer/silica nanocomposites, followed by HF etching. Thermogravimetric analysis of AN-MMAcopolymer/silica nanocomposltes snoweO mat me caroon ylelCl or copolymer was slgnuy oecreaseo as Silica parucle incorporated. N2 adsorption-desorption, scan electron microscopy （SEM） and transmission electron microscopy （TEM） were used to characterize the structure and morphology of the mesoporous carbon materials. Both SEM and
基金funding from the European Union Seventh Framework Programme (FP7/2007-2013) under grant agreement no.241718,Eurobioref
文摘The chemical industry is nowadays predominantly using fossil raw materials,but the alternative use of bio-based resources is investigated to account for the foreseeable scarcity of fossil feedstocks.A main challenge of using biobased feedstocks is the complexity of the impurity profile.For an economic production of bio-based chemicals,the use of intensified processes is inevitable and approaches are needed for the various process intensification techniques to identify their applicability to be used for the production of bio-based components.In the presented study,an approach is shown for the reactive distillation(RD) technology to identify the most critical bio-based impurities and their impact on the reactive distillation process.The investigated case-study is the production of n-butyl acrylate from acrylic acid and n-butanol.Among all initially identified impurities,the key impurities,having the biggest impact on the product purity in the reactive distillation process,are found.These impurities are then studied in more detail and an operating window depending on the impurity concentration is identified for the reactive distillation column.Furthermore,an integrated design of upstream and downstream processes is facilitated,as the presented results can be used in the development of the fermentation processes for the production of the bio-based reactants by decreasing the concentration of the critical impurities.
文摘20125312环保产品PA6BCF地毯丝Chemical Fiber Internatioal,2010,62(1),p.6(英)2012年1月在德国汉诺威的Domotex地毯展览会上,德国Xentrys Leune公司展出其PA6BCF地毯丝,展品不仅是地毯丝的特种产品,而且,也作为建筑行业可持续发展的合作伙伴。Xentrys公司作为比利时Dom o集团的一部分,是首家得到IBC(Institute for Construction and the Environment)严格按照EN15804验证的"环保产品声明"(EPD)的地毯丝生产企业。
