In the past several decades,SINOPEC has devoted continuously great efforts to the development of DCC technology,the only commercial process using heavy feeds aiming at propylene production.Recently,a series of researc...In the past several decades,SINOPEC has devoted continuously great efforts to the development of DCC technology,the only commercial process using heavy feeds aiming at propylene production.Recently,a series of research breakthroughs have been achieved in molecular refining.Based on the detailed analysis on the complex DCC reaction network,an innovative catalyst technology has been developed to Optimize Catalysis Kinetics (OCK in brief).The deep-cracking process can be improved with optimizing the availability of the active sites.The updated MFI and beta zeolites are used to boost the propylene selectivity.The latest generation catalyst DMMC-1 has been applied commercially.Compared with the best historical records in the past,the propylene yield upon application of the catalyst DMMC-1 increases by 2.4 m% coupled with an improved distribution of products.The DCC technology continues to assume a leading position for manufacturing propylene from heavy feedstocks.展开更多
Quenching process and design of the quenching tower in acrylonitrile production in China were studied in order to decrease the polymerization loss of acrylonitrile in the quenching tower. Based on the research of acry...Quenching process and design of the quenching tower in acrylonitrile production in China were studied in order to decrease the polymerization loss of acrylonitrile in the quenching tower. Based on the research of acrylonitrile polymerization in the quenching tower, a new quenching process was proposed to avoid the disadvantages of the original process. Two kinds of internals were installed to improve the performance of the quenching tower. Through a series of air-flow and real-flow model experiments, the new quenching process and new design were showed to be successful in enhancing the mass and heat transfer in the vapor-liquid system and decreasing the loss of acrylonitrile.Industrial application showed satisfactory results of decrease of the acrylonitrile loss in the quenching tower by about 4.5% and increase of the acrylonitrile recovery of the whole plant by more than 4%.展开更多
文摘In the past several decades,SINOPEC has devoted continuously great efforts to the development of DCC technology,the only commercial process using heavy feeds aiming at propylene production.Recently,a series of research breakthroughs have been achieved in molecular refining.Based on the detailed analysis on the complex DCC reaction network,an innovative catalyst technology has been developed to Optimize Catalysis Kinetics (OCK in brief).The deep-cracking process can be improved with optimizing the availability of the active sites.The updated MFI and beta zeolites are used to boost the propylene selectivity.The latest generation catalyst DMMC-1 has been applied commercially.Compared with the best historical records in the past,the propylene yield upon application of the catalyst DMMC-1 increases by 2.4 m% coupled with an improved distribution of products.The DCC technology continues to assume a leading position for manufacturing propylene from heavy feedstocks.
文摘Quenching process and design of the quenching tower in acrylonitrile production in China were studied in order to decrease the polymerization loss of acrylonitrile in the quenching tower. Based on the research of acrylonitrile polymerization in the quenching tower, a new quenching process was proposed to avoid the disadvantages of the original process. Two kinds of internals were installed to improve the performance of the quenching tower. Through a series of air-flow and real-flow model experiments, the new quenching process and new design were showed to be successful in enhancing the mass and heat transfer in the vapor-liquid system and decreasing the loss of acrylonitrile.Industrial application showed satisfactory results of decrease of the acrylonitrile loss in the quenching tower by about 4.5% and increase of the acrylonitrile recovery of the whole plant by more than 4%.
