The high order compact d if ference method is developed for solving the perturbation equations based on Navi er Stokes equations, and is used in studying complex evolution processes from w all negative pulse to the ...The high order compact d if ference method is developed for solving the perturbation equations based on Navi er Stokes equations, and is used in studying complex evolution processes from w all negative pulse to the turbulent coherent structure in the channel flow. Th is method contains three dimensional coupling difference scheme with high accur acy and high resolution, and the high order time splitting methods. Compared with the general spectral method, the method can be used to research turbule nt coherent structure under more general boundary conditions and in flow domains . In this paper, the generation and evolution of the turbulent coherent structur es ind uced by wall pulse in the channel flow are simulated, and the basic characterist ics and rules of the turbulent coherent structure are shown. Computational r esults indicate that a wall negative pulse is more convenient than the resonant three wave model.展开更多
The title compound of karounidiol (C30H48O2), a main active triterpene component of snakegourd seed, was isolated from unsaponifiable matter of the seed oil of Trichosanthes kirilowii Maxim., and characterized by X-ra...The title compound of karounidiol (C30H48O2), a main active triterpene component of snakegourd seed, was isolated from unsaponifiable matter of the seed oil of Trichosanthes kirilowii Maxim., and characterized by X-ray diffraction analysis. It crystallizes in orthorhombic system, space group P212121 with C30H48O2CH3OHH2O (C31H54O4), a = 7.515(1), b = 14.407(1), c = 27.799(2) , V = 3009.8(5) 3, Z = 4, Dx = 1.087 g/cm3, Mr = 490.77, F(000) = 1088 and = 0.086 mm-1. The final R = 0.0840 and wR = 0.2289 for 2752 observed reflections (|F|2 ≥ 2|F|2). The molecular crystal structure of karounidiol shows relative stereochemistry of (3,13,14, 20)-3,29-dihydroxy-13-methyl-26-norolean-7,9(11)-diene. The molecule is composed of five six- membered rings with ring junctures of A/B trans, C/D trans and D/E cis.展开更多
Sandu Bay is located in the East China Sea and is characterized by high-density fish farming and kelp culture. Despite this, little is known about the impacts of these different mariculture practices on the local envi...Sandu Bay is located in the East China Sea and is characterized by high-density fish farming and kelp culture. Despite this, little is known about the impacts of these different mariculture practices on the local environment. We investigated the temporal variation in macrobenthos and environmental conditions at three sites in the bay (fish farming site, kelp culture site, and a control site). We collected water and sediment samples during nine cruises between May 2009 and February 2010. The density of macrobenthos peaked at the fish farming site in July (655 ind./mE) whereas density did not fluctuate as widely at the other two sites. Biomass varied significantly at both the control and kelp culture sites, but had only a single peak at the fish farming site in June (21.90 g/mE). The dominant species varied throughout the study period at the control and kelp culture sites, whereas a single terebellid species (Lysilla pacifica) dominated the macrobenthos at the fish farming site. The diversity index H' increased at the control site beginning in February then decreased after May, whereas H' was low at the other sites in December. The mean dissolved oxygen level was highest at the control site (6.59 mg/L) and lowest at the fish farming site (5.54 mg/L). DO levels were lowest at all sites in summer (July and August). The sediment acid volatile sulfide content was higher at the fish farming site (1.46 mg/g dry weight) than those at the kelp culture and control sites (1.22 and 0.14 mg/g, respectively). Our results suggest that mariculture practices have a clear impact on the benthic environment/ community in Sandu Bay.展开更多
The chemical fractions,i.e.,water soluble(WS),exchangeable(Ex),carbonate(Car),weakly organic(WO),Fe-Mn oxide(FMO),strongly organic(SO),residual(Res) fraction,of Pb in irrigated soils in South China were investigated b...The chemical fractions,i.e.,water soluble(WS),exchangeable(Ex),carbonate(Car),weakly organic(WO),Fe-Mn oxide(FMO),strongly organic(SO),residual(Res) fraction,of Pb in irrigated soils in South China were investigated by a modified Tessier sequential extraction technique.The results show that the chemical fraction of Pb in soil is mainly the Res fraction and followed by FMO fraction,and the WS,WO,FMO,and SO fractions in topsoils(0-10 cm) are higher than those in subsoils(30-40 cm).The sum of contents of WS and Ex fractions(SWE) in topsoils is significantly positively related with that in subsoils,indicating the strong mobility of Pb in WS and Ex fractions in soils,and the SWE in soils is higher than the German trigger value for the transfer path soil-plant,indicating the high bioavailability of Pb in soils of this area.Fortunately,SWE and the ratio of WS and Ex fractions(RWE) to the sum of all fractions generally decrease with the soil depth in soil profile and the RWE in soil profile is lower than 0.5%,indicating the low pollution risk for Pb in groundwater.In addition,soil particles,pH and Fe2O3 play an important role in the impact of mobility and chemical fractions of Pb in soils.展开更多
The potential energy landscape of the neutral Ni_(2)(CO)_(5) complex was re-examined.A new C_(2v) structure with double bridging carbonyls is found to compete with the previously proposed triply carbonyl-bridged D_(3h...The potential energy landscape of the neutral Ni_(2)(CO)_(5) complex was re-examined.A new C_(2v) structure with double bridging carbonyls is found to compete with the previously proposed triply carbonyl-bridged D_(3h) isomer for the global minimum of Ni_(2)(CO)_(5).Despite that the tri-bridged isomer possesses the more favored(18,18)configuration,where both metal centers satisfy the 18-electron rule,the neutral Ni_(2)(CO)_(5) complex prefers the di-bridged geometry with(18,16)configuration.The isomerization energy decomposition analysis reveals that the structural preference is a consequence of the maximization of electrostatic and orbital interactions.展开更多
Since China opening to outside world,the economy in the Pearl(Zhujiang)River Delta(PRD)has been dou-ble digit growth.It has been known as one of mature fast growth areas in the world and become the model and hope of C...Since China opening to outside world,the economy in the Pearl(Zhujiang)River Delta(PRD)has been dou-ble digit growth.It has been known as one of mature fast growth areas in the world and become the model and hope of Chi-nese reformand opening to outside wo rld.The regional development in PRD is the outcome of polarization effects .The polar-ization effects actually are extension of international regional divis ion and a combination of Hongkong’s i nfluence and re-form and open-door policies on the ma inland.Since the 1990s,driven by knowledge-based economy,the PRD has f urther adjusted the industrial structure a nd achieved good progress in upgradi ng industrial structure.Its high te chnology industry has developed quickly and the econom ic internationalization has deepen ed,meanwhile,the region is going th rough transforma-tion and some new trends have begun to appear,which include:university t owns springing up,industrial globalization and the construction of Hi-tech develop ment zones.The paper suggests that w ith the economic growth changing fro m relying on the low level production elements to relying on high level production ele ments,the regional policies in Guan gdong Province should develop correspondingly:1)make a plan to prohibite the blind con struction in innovative spatial con struc-tions;2)make measures to attract the overseas talents to establish a pool of talen t;3)work out the favorable policies for absorbing larger capital;4)formulate the policy of attracting a cluster of industries to speed up the upgrade of industrial development.展开更多
Spatial distribution of soil salinity can be estimated based on its environmental factors because soil salinity is strongly affected and indicated by environmental factors. Different with other properties such as soil...Spatial distribution of soil salinity can be estimated based on its environmental factors because soil salinity is strongly affected and indicated by environmental factors. Different with other properties such as soil texture, soil salinity varies with short-term time. Thus, how to choose powerful environmental predictors is especially important for soil salinity. This paper presents a similarity-based prediction approach to map soil salinity and detects powerful environmental predictors for the Huanghe(Yellow) River Delta area in China. The similarity-based approach predicts the soil salinities of unsampled locations based on the environmental similarity between unsampled and sampled locations. A dataset of 92 points with salt data at depth of 30–40 cm was divided into two subsets for prediction and validation. Topographical parameters, soil textures, distances to irrigation channels and to the coastline, land surface temperature from Moderate Resolution Imaging Spectroradiometer(MODIS), Normalized Difference Vegetation Indices(NDVIs) and land surface reflectance data from Landsat Thematic Mapper(TM) imagery were generated. The similarity-based prediction approach was applied on several combinations of different environmental factors. Based on three evaluation indices including the correlation coefficient(CC) between observed and predicted values, the mean absolute error and the root mean squared error we found that elevation, distance to irrigation channels, soil texture, night land surface temperature, NDVI, and land surface reflectance Band 5 are the optimal combination for mapping soil salinity at the 30–40 cm depth in the study area(with a CC value of 0.69 and a root mean squared error value of 0.38). Our results indicated that the similarity-based prediction approach could be a vital alternative to other methods for mapping soil salinity, especially for area with limited observation data and could be used to monitor soil salinity distributions in the future.展开更多
In traditional urban geography, city contact research is a classic study element in city research. In general, researchers use the traditional gravity model to characterize the contacts that exist between two cities. ...In traditional urban geography, city contact research is a classic study element in city research. In general, researchers use the traditional gravity model to characterize the contacts that exist between two cities. The traditional gravity model assumes ideal conditions, but these preconditions and their results often do not exist in realistic conditions. Thus, we used a modified gravity model to characterize the city contacts within a specific region. This model considers factors such as intercity complementarities, government intervention, and the diversity of the transportation infrastructure which is characterized as the transportation distance instead of the traditional Euclidean distance. We applied this model to an empirical study of city contact in the Zhujiang(Pearl) River Delta(PRD) of China. The regression results indicated that the modified gravity model could measure city contact more accurately and comprehensively than the traditional gravity model, i.e., it yielded a higher adjusted R2 value(0.379) than the traditional gravity model result(0.259). Our study also suggests that, in addition to urban-regional and metropolitan development, the complementarities of the basic functions of cities at the administrative and market levels, as well as the corporeal and immaterial levels, play very significant roles in the characterization of city contact. Given the complexity of city contact, it will be necessary to consider more relevant influential factors in the modified gravity model to characterize the features of city contact in the future.展开更多
In this paper the operation of a three level H-bridge converter as well as its parallel operations is analyzed and simulated on the computer. Based on the simulation results the operating behavior between (a) a thre...In this paper the operation of a three level H-bridge converter as well as its parallel operations is analyzed and simulated on the computer. Based on the simulation results the operating behavior between (a) a three level H-bridge neutral point clamped convener, (b) a three level back-to-back H-bridge neutral point clamped convener, (c) two three level H-bridge neutral point clamped converters parallel connected is being compared. From the simulation results it is obvious that in the first two cases the ripples, the distortion in primary and secondary winding currents, and the power factor are quite satisfactory and almost identical to each other. In the third case as compared with the first two, it is observed that current harmonics with higher amplitude appear in the primary winding of the transformer.展开更多
Concrete footbridges, due to their mass, stiffness and damping, are perceived as strucaires more resistant to vibration caused by dynamic action of the users. In order to verify the dynamic behaviour of concrete footb...Concrete footbridges, due to their mass, stiffness and damping, are perceived as strucaires more resistant to vibration caused by dynamic action of the users. In order to verify the dynamic behaviour of concrete footbridges, a series of field tests and numerical analyses have been carried out. In the paper, the results of the dynamic field tests of three medium span concrete footbridges with different structural systems (frame, beam and arch footbridges) and their dynamic characteristics (mass, stiffness and damping) are presented. The field tests were carried out for different types of vibration excitation caused by walking, running and jumping persons. Furthermore, the vibrational comfort criteria for footbridges are shortly described and verified for examined structures. The study were supplemented by numerical calculation of natural mode shapes and frequencies of the structures using the 3D FEA (finite element analysis) models with elastic supports elements in order to ensure the compatibility of the calculated and measured mode shapes of the footbridges.展开更多
文摘The high order compact d if ference method is developed for solving the perturbation equations based on Navi er Stokes equations, and is used in studying complex evolution processes from w all negative pulse to the turbulent coherent structure in the channel flow. Th is method contains three dimensional coupling difference scheme with high accur acy and high resolution, and the high order time splitting methods. Compared with the general spectral method, the method can be used to research turbule nt coherent structure under more general boundary conditions and in flow domains . In this paper, the generation and evolution of the turbulent coherent structur es ind uced by wall pulse in the channel flow are simulated, and the basic characterist ics and rules of the turbulent coherent structure are shown. Computational r esults indicate that a wall negative pulse is more convenient than the resonant three wave model.
基金the State Science and Technology Commission (No. 96-903-02-02)
文摘The title compound of karounidiol (C30H48O2), a main active triterpene component of snakegourd seed, was isolated from unsaponifiable matter of the seed oil of Trichosanthes kirilowii Maxim., and characterized by X-ray diffraction analysis. It crystallizes in orthorhombic system, space group P212121 with C30H48O2CH3OHH2O (C31H54O4), a = 7.515(1), b = 14.407(1), c = 27.799(2) , V = 3009.8(5) 3, Z = 4, Dx = 1.087 g/cm3, Mr = 490.77, F(000) = 1088 and = 0.086 mm-1. The final R = 0.0840 and wR = 0.2289 for 2752 observed reflections (|F|2 ≥ 2|F|2). The molecular crystal structure of karounidiol shows relative stereochemistry of (3,13,14, 20)-3,29-dihydroxy-13-methyl-26-norolean-7,9(11)-diene. The molecule is composed of five six- membered rings with ring junctures of A/B trans, C/D trans and D/E cis.
基金Supported by the Special Research Fund for the National Non-Profit in East China Sea Fisheries Research Institute (No. 2008M16)
文摘Sandu Bay is located in the East China Sea and is characterized by high-density fish farming and kelp culture. Despite this, little is known about the impacts of these different mariculture practices on the local environment. We investigated the temporal variation in macrobenthos and environmental conditions at three sites in the bay (fish farming site, kelp culture site, and a control site). We collected water and sediment samples during nine cruises between May 2009 and February 2010. The density of macrobenthos peaked at the fish farming site in July (655 ind./mE) whereas density did not fluctuate as widely at the other two sites. Biomass varied significantly at both the control and kelp culture sites, but had only a single peak at the fish farming site in June (21.90 g/mE). The dominant species varied throughout the study period at the control and kelp culture sites, whereas a single terebellid species (Lysilla pacifica) dominated the macrobenthos at the fish farming site. The diversity index H' increased at the control site beginning in February then decreased after May, whereas H' was low at the other sites in December. The mean dissolved oxygen level was highest at the control site (6.59 mg/L) and lowest at the fish farming site (5.54 mg/L). DO levels were lowest at all sites in summer (July and August). The sediment acid volatile sulfide content was higher at the fish farming site (1.46 mg/g dry weight) than those at the kelp culture and control sites (1.22 and 0.14 mg/g, respectively). Our results suggest that mariculture practices have a clear impact on the benthic environment/ community in Sandu Bay.
基金Project(41103059) supported by the National Natural Science Foundation of ChinaProject(2010CB428806-2) supported by the National Basic Research Program of China
文摘The chemical fractions,i.e.,water soluble(WS),exchangeable(Ex),carbonate(Car),weakly organic(WO),Fe-Mn oxide(FMO),strongly organic(SO),residual(Res) fraction,of Pb in irrigated soils in South China were investigated by a modified Tessier sequential extraction technique.The results show that the chemical fraction of Pb in soil is mainly the Res fraction and followed by FMO fraction,and the WS,WO,FMO,and SO fractions in topsoils(0-10 cm) are higher than those in subsoils(30-40 cm).The sum of contents of WS and Ex fractions(SWE) in topsoils is significantly positively related with that in subsoils,indicating the strong mobility of Pb in WS and Ex fractions in soils,and the SWE in soils is higher than the German trigger value for the transfer path soil-plant,indicating the high bioavailability of Pb in soils of this area.Fortunately,SWE and the ratio of WS and Ex fractions(RWE) to the sum of all fractions generally decrease with the soil depth in soil profile and the RWE in soil profile is lower than 0.5%,indicating the low pollution risk for Pb in groundwater.In addition,soil particles,pH and Fe2O3 play an important role in the impact of mobility and chemical fractions of Pb in soils.
基金supported by the National Natural Science Foundation of China(No.21571119 and No.21603130)the Shanxi Province Science Foundation for Youths(No.201901D211395)+1 种基金the 1331 Engineering of Shanxi Provincethe Start-up fund from Shanxi Normal University。
文摘The potential energy landscape of the neutral Ni_(2)(CO)_(5) complex was re-examined.A new C_(2v) structure with double bridging carbonyls is found to compete with the previously proposed triply carbonyl-bridged D_(3h) isomer for the global minimum of Ni_(2)(CO)_(5).Despite that the tri-bridged isomer possesses the more favored(18,18)configuration,where both metal centers satisfy the 18-electron rule,the neutral Ni_(2)(CO)_(5) complex prefers the di-bridged geometry with(18,16)configuration.The isomerization energy decomposition analysis reveals that the structural preference is a consequence of the maximization of electrostatic and orbital interactions.
文摘Since China opening to outside world,the economy in the Pearl(Zhujiang)River Delta(PRD)has been dou-ble digit growth.It has been known as one of mature fast growth areas in the world and become the model and hope of Chi-nese reformand opening to outside wo rld.The regional development in PRD is the outcome of polarization effects .The polar-ization effects actually are extension of international regional divis ion and a combination of Hongkong’s i nfluence and re-form and open-door policies on the ma inland.Since the 1990s,driven by knowledge-based economy,the PRD has f urther adjusted the industrial structure a nd achieved good progress in upgradi ng industrial structure.Its high te chnology industry has developed quickly and the econom ic internationalization has deepen ed,meanwhile,the region is going th rough transforma-tion and some new trends have begun to appear,which include:university t owns springing up,industrial globalization and the construction of Hi-tech develop ment zones.The paper suggests that w ith the economic growth changing fro m relying on the low level production elements to relying on high level production ele ments,the regional policies in Guan gdong Province should develop correspondingly:1)make a plan to prohibite the blind con struction in innovative spatial con struc-tions;2)make measures to attract the overseas talents to establish a pool of talen t;3)work out the favorable policies for absorbing larger capital;4)formulate the policy of attracting a cluster of industries to speed up the upgrade of industrial development.
基金Under the auspices of Special Fund for Ocean Public Welfare Profession Scientific Research(No.201105020)National Natural Science Foundation of China(No.41471178,41023010,41431177)National Key Technology Innovation Project for Water Pollution Control and Remediation(No.2013ZX07103006)
文摘Spatial distribution of soil salinity can be estimated based on its environmental factors because soil salinity is strongly affected and indicated by environmental factors. Different with other properties such as soil texture, soil salinity varies with short-term time. Thus, how to choose powerful environmental predictors is especially important for soil salinity. This paper presents a similarity-based prediction approach to map soil salinity and detects powerful environmental predictors for the Huanghe(Yellow) River Delta area in China. The similarity-based approach predicts the soil salinities of unsampled locations based on the environmental similarity between unsampled and sampled locations. A dataset of 92 points with salt data at depth of 30–40 cm was divided into two subsets for prediction and validation. Topographical parameters, soil textures, distances to irrigation channels and to the coastline, land surface temperature from Moderate Resolution Imaging Spectroradiometer(MODIS), Normalized Difference Vegetation Indices(NDVIs) and land surface reflectance data from Landsat Thematic Mapper(TM) imagery were generated. The similarity-based prediction approach was applied on several combinations of different environmental factors. Based on three evaluation indices including the correlation coefficient(CC) between observed and predicted values, the mean absolute error and the root mean squared error we found that elevation, distance to irrigation channels, soil texture, night land surface temperature, NDVI, and land surface reflectance Band 5 are the optimal combination for mapping soil salinity at the 30–40 cm depth in the study area(with a CC value of 0.69 and a root mean squared error value of 0.38). Our results indicated that the similarity-based prediction approach could be a vital alternative to other methods for mapping soil salinity, especially for area with limited observation data and could be used to monitor soil salinity distributions in the future.
基金Under the auspices of National Natural Science Foundation of China(No.41271177)Guangdong Natural Science Foundation(No.S2012010008902)
文摘In traditional urban geography, city contact research is a classic study element in city research. In general, researchers use the traditional gravity model to characterize the contacts that exist between two cities. The traditional gravity model assumes ideal conditions, but these preconditions and their results often do not exist in realistic conditions. Thus, we used a modified gravity model to characterize the city contacts within a specific region. This model considers factors such as intercity complementarities, government intervention, and the diversity of the transportation infrastructure which is characterized as the transportation distance instead of the traditional Euclidean distance. We applied this model to an empirical study of city contact in the Zhujiang(Pearl) River Delta(PRD) of China. The regression results indicated that the modified gravity model could measure city contact more accurately and comprehensively than the traditional gravity model, i.e., it yielded a higher adjusted R2 value(0.379) than the traditional gravity model result(0.259). Our study also suggests that, in addition to urban-regional and metropolitan development, the complementarities of the basic functions of cities at the administrative and market levels, as well as the corporeal and immaterial levels, play very significant roles in the characterization of city contact. Given the complexity of city contact, it will be necessary to consider more relevant influential factors in the modified gravity model to characterize the features of city contact in the future.
文摘In this paper the operation of a three level H-bridge converter as well as its parallel operations is analyzed and simulated on the computer. Based on the simulation results the operating behavior between (a) a three level H-bridge neutral point clamped convener, (b) a three level back-to-back H-bridge neutral point clamped convener, (c) two three level H-bridge neutral point clamped converters parallel connected is being compared. From the simulation results it is obvious that in the first two cases the ripples, the distortion in primary and secondary winding currents, and the power factor are quite satisfactory and almost identical to each other. In the third case as compared with the first two, it is observed that current harmonics with higher amplitude appear in the primary winding of the transformer.
文摘Concrete footbridges, due to their mass, stiffness and damping, are perceived as strucaires more resistant to vibration caused by dynamic action of the users. In order to verify the dynamic behaviour of concrete footbridges, a series of field tests and numerical analyses have been carried out. In the paper, the results of the dynamic field tests of three medium span concrete footbridges with different structural systems (frame, beam and arch footbridges) and their dynamic characteristics (mass, stiffness and damping) are presented. The field tests were carried out for different types of vibration excitation caused by walking, running and jumping persons. Furthermore, the vibrational comfort criteria for footbridges are shortly described and verified for examined structures. The study were supplemented by numerical calculation of natural mode shapes and frequencies of the structures using the 3D FEA (finite element analysis) models with elastic supports elements in order to ensure the compatibility of the calculated and measured mode shapes of the footbridges.