Petroleum geochemistry contributes to exploration successes by providing key constraints for geological models and critical input to exploration scenarios. One of the most important tasks in a typical exploration pr...Petroleum geochemistry contributes to exploration successes by providing key constraints for geological models and critical input to exploration scenarios. One of the most important tasks in a typical exploration program is to identify the most effective source intervals or kitchens in a basin, through oil-source correlation. The results of correlation are valid only if the geochemical parameters used address adequately the genetic characteristics of the source rocks as well as the mass transport and mixing processes of hydrocarbon fluids occurring in the carrier beds and reservoirs. This manuscript discusses four of the major contentious petroleum geochemical issues in China’s sedimentary basins. It is suggested that marine incursions played a significant role in the formation of prolific petroleum source rocks in the gigantic, dominantly freshwater, Songliao Basin. Several models are proposed to account for the occurrence of immature oils in the Cathaysian rift system including the Bohai Bay Basin, thus immature source rocks are considered a mere minor contributor to the known economic immature oil resources. Both geological and geochemical evidence are reviewed to refute a dominantly coaly source for the petroleum discovered in the Turpan Basin. Results of case studies are presented to demonstrate the importance of recognizing petroleum fluid mixing to solve the oil-source correlation issues in the structurally complex Tarim Basin. In addressing the fundamental assumptions and potential flaws of the molecular geochemical parameters commonly used for oil-source correlation, the need of a mass fraction approach is proposed to deal with such contentious issues as marine versus lacustrine, coal versus lacustrine, and mature versus immature oils.展开更多
The area of the southwestern Nansha Trough is one of the most productive areas of the southern South China Sea.It is a typical semi-deep sea area of transition from shoal to abyssal zone.To understand distributions an...The area of the southwestern Nansha Trough is one of the most productive areas of the southern South China Sea.It is a typical semi-deep sea area of transition from shoal to abyssal zone.To understand distributions and roles of nitrogen forms involved in biogeochemical cycling in this area,contents of nitrogen in four extractable forms:nitrogen in ion exchangeable form(IEF-N),nitrogen in weak acid extractable form(WAEF-N),nitrogen in strong alkali extractable form(SAEF-N) and nitrogen in strong oxidation extractable form(SOEF-N),as well as in total nitrogen content(TN) in surface sediments were determined from samples collected from the cruise in April-May 1999.The study area was divided into three regions(A,B and C) in terms of clay sediment(<4 μm) content at <40%,40%-60% and >60%,respectively.Generally,region C was the richest in the nitrogen of all forms and region A the poorest,indicating that the finer the grain size is,the richer the contents of various nitrogen are.The burial efficiency of total nitrogen in surface sediments was 28.79%,indicating that more than 70% of nitrogen had been released and participated in biogeochemical recycling through sediment-water interface.展开更多
The Tainan Basin is one of the set of Cenozoic extensional basins along northern margin of the South China Sea that experienced extension and subsequently thermal subsidence. The Tainan Basin is close to the Taiwan Ar...The Tainan Basin is one of the set of Cenozoic extensional basins along northern margin of the South China Sea that experienced extension and subsequently thermal subsidence. The Tainan Basin is close to the Taiwan Arc-Trench System and straddles a transition zone between oceanic and continental crust. A new regional multi-channel seismic profile (973-01) across the region of NE South China Sea is introduced in this paper. In seismic stratigraphy and structural geology, a model of Cenozoic tectono-sedimentation of the Tainan Basin is established. The results show that three stages can be suggested in Tainan Basin; In Stage A (Oligocene (?)-Lower Miocene) the stratigraphy shows restricted rifting, indicating crustal extension. Terrestrial sedi- ments mostly filled the faulted sags of the North Depression on the continental shelf. Structural highs, including the Central Uplift, blocked material transportation to the South Depression in abyssal basin. In Stage B the Tainan Basin (Middle-Upper Miocene) exhibits a broad subsidence resulting from the post-rifting thermal cooling. The faulted-sags in North Depression had been filled up. Terrestrial materials were transported over the structural highs and deposited directly in the South Depression through sub- marine gullies or canyons. This sedimentation resulted in a crucial change in the slope to a modem shape. In Stage C (Latest Miocene-Recent) a phase change from extension to compression took place due to the orogeny caused by the overthrusting of the Luzon volcanic arc. Many inverse structures, such as thrusts, fault bend folds, and a regional unconformity were formed. Forland basin began developing.展开更多
We reviewed ampharetid genus Anobothrus Levinsen, 1884 in China seas based upon material deposited in the Marine Biological Museum of the Chinese Academy of Sciences (Qingdao). The genus includes A. glandularis (Ha...We reviewed ampharetid genus Anobothrus Levinsen, 1884 in China seas based upon material deposited in the Marine Biological Museum of the Chinese Academy of Sciences (Qingdao). The genus includes A. glandularis (Hartmann-Schr6der, 1965), A. gracilis (Malmgren, 1866), A. mironovi Jirkov, 2008 and A. nataliae (Jirkov, 2008). A. glandularis and A. mironovi are recorded for the first time in Chinese waters. A key to Chinese species of Anobothrus is given.展开更多
The sand-conglomerate fans are the major depositional systems in the lower third member of Shahejie Formation in Shengtuo area, which formed in the deep lacustrine environment characterized by steep slope gradient, ne...The sand-conglomerate fans are the major depositional systems in the lower third member of Shahejie Formation in Shengtuo area, which formed in the deep lacustrine environment characterized by steep slope gradient, near sources and intensive tectonic activity. This work was focused on the sedimentary feature of the glutenite segment to conduct the seismic sedimentology research. The near-shore subaqueous fans and its relative gravity channel and slump turbidite fan depositions were identified according to observation and description of cores combining with the numerous data of seismic and logging. Then, the depositional model was built depending on the analysis of palaeogeomorphology. The seismic attributes which are related to the hydrocarbon but relative independent were chosen to conduct the analysis, the reservoir area of the glutenite segment was found performing a distribution where the amplitude value is relatively higher, and finally the RMS amplitude attribute was chosen to conduct the attribute predicting. At the same time, the horizontal distribution of the sedimentary facies was analyzed qualitatively. At last, the sparse spike inversion method was used to conduct the acoustic impedance inversion, and the inversion result can distinguish glutenite reservoir which is greater than 5 m. This method quantitatively characterizes the distribution area of the favorable reservoir sand.展开更多
The Shanxi Institute of Coal Chemistry,Chinese Academy of Sciences has designed and prepared a multiple confined-zone-based nickel hydrogenation catalyst by means of the atomic layer deposition(ALD)technology.In compa...The Shanxi Institute of Coal Chemistry,Chinese Academy of Sciences has designed and prepared a multiple confined-zone-based nickel hydrogenation catalyst by means of the atomic layer deposition(ALD)technology.In comparison with the non-confined-zone based catalyst,the multiple confined-zone-based nickel catalyst possesses an enhanced catalytic reactivity and catalytic stability for hydrogenation of cinnamaldehyde and nitrobenzene.展开更多
The Badain Jaran Desert exhibits the greatest difference in altitude of all of the world's deserts.On the slopes of megadunes in the desert,there are physical and chemical deposits produced by surface runoff.In ad...The Badain Jaran Desert exhibits the greatest difference in altitude of all of the world's deserts.On the slopes of megadunes in the desert,there are physical and chemical deposits produced by surface runoff.In addition,we have observed rarely-seen infiltration-excess surface runoff in the megadune depressions as well as spring streams at the base of megadunes.We used electron microscopy,energy spectrum analysis,infiltration experiments,moisture content determinations and grain-size analysis to study the mineral and chemical composition of the runoff precipitates,and grain-size of the deposits associated with the runoff,together with the hydrological balance in the megadune area,and the atmospheric precipitation mechanism responsible for groundwater recharge and for supplying water to lakes.The observations of shallow runoff and infiltration-excess surface runoff indicate the occurrence of strong and effective precipitation in summer,which would provide an important source for groundwater recharge.Several lines of evidence,such as the physical and chemical deposits resulting from shallow subsurface runoff,spring streams,infiltration-excess runoff,and gravity capillary water with a moisture content of 3-6%,demonstrate that precipitation reaches the base of the megadunes through infiltration and subsequently becomes groundwater.The chemical deposits,such as newly-formed calcite and gypsum,and gray-black physical deposits,as well as different stages in the development of fan-shaped landforms resulting from shallow subsurface runoff,indicate that groundwater recharge in the area is the result of long-term precipitation,rather than intermittent individual major rainfall events.Fine sand layers with a low infiltration capacity lead to subsurface runoff emerging at the ground surface.Five factors play an important role in maintaining a positive water balance and in replenishing groundwater via rainfall:effective rainfall as a water source,the high infiltration capacity of the sands enabling rainfall to rapidly become capillary water in the dunes,low evapotranspiration rates due to the sparse vegetation,the fact that the depth of the sand layer influenced by evaporation is shallow enough to maximize the deep infiltration of rainfall,and rapidly-moving gravity capillary water in the sandy dunes.These five factors together constitute a mechanism for groundwater recharge from rainfall,and explain the origin of the groundwater and lakes in the area.Our findings represent a significant advance in research on the hydrological cycle,including groundwater recharge conditions and recharge mechanisms,in this desert region.展开更多
文摘Petroleum geochemistry contributes to exploration successes by providing key constraints for geological models and critical input to exploration scenarios. One of the most important tasks in a typical exploration program is to identify the most effective source intervals or kitchens in a basin, through oil-source correlation. The results of correlation are valid only if the geochemical parameters used address adequately the genetic characteristics of the source rocks as well as the mass transport and mixing processes of hydrocarbon fluids occurring in the carrier beds and reservoirs. This manuscript discusses four of the major contentious petroleum geochemical issues in China’s sedimentary basins. It is suggested that marine incursions played a significant role in the formation of prolific petroleum source rocks in the gigantic, dominantly freshwater, Songliao Basin. Several models are proposed to account for the occurrence of immature oils in the Cathaysian rift system including the Bohai Bay Basin, thus immature source rocks are considered a mere minor contributor to the known economic immature oil resources. Both geological and geochemical evidence are reviewed to refute a dominantly coaly source for the petroleum discovered in the Turpan Basin. Results of case studies are presented to demonstrate the importance of recognizing petroleum fluid mixing to solve the oil-source correlation issues in the structurally complex Tarim Basin. In addressing the fundamental assumptions and potential flaws of the molecular geochemical parameters commonly used for oil-source correlation, the need of a mass fraction approach is proposed to deal with such contentious issues as marine versus lacustrine, coal versus lacustrine, and mature versus immature oils.
基金Supported by the National Basic Research Program of China (973 Program, No. 2007CB407305)Qingdao Special Project for Outstanding Scientists (No.05-2-JC-90)the 100 Talents Project of Chinese Academy of Sciences (No.2003-202)
文摘The area of the southwestern Nansha Trough is one of the most productive areas of the southern South China Sea.It is a typical semi-deep sea area of transition from shoal to abyssal zone.To understand distributions and roles of nitrogen forms involved in biogeochemical cycling in this area,contents of nitrogen in four extractable forms:nitrogen in ion exchangeable form(IEF-N),nitrogen in weak acid extractable form(WAEF-N),nitrogen in strong alkali extractable form(SAEF-N) and nitrogen in strong oxidation extractable form(SOEF-N),as well as in total nitrogen content(TN) in surface sediments were determined from samples collected from the cruise in April-May 1999.The study area was divided into three regions(A,B and C) in terms of clay sediment(<4 μm) content at <40%,40%-60% and >60%,respectively.Generally,region C was the richest in the nitrogen of all forms and region A the poorest,indicating that the finer the grain size is,the richer the contents of various nitrogen are.The burial efficiency of total nitrogen in surface sediments was 28.79%,indicating that more than 70% of nitrogen had been released and participated in biogeochemical recycling through sediment-water interface.
基金the National Basic Research Program (973)of China (No. 2007CB411704)the National Natural Science Foun-dation of China (No. 40676024)+1 种基金the Key Laboratory of MarginalSea Geologythe Chinese Academy of Sciences (Nos. KZCX3-SW-234 and MSGL0609)
文摘The Tainan Basin is one of the set of Cenozoic extensional basins along northern margin of the South China Sea that experienced extension and subsequently thermal subsidence. The Tainan Basin is close to the Taiwan Arc-Trench System and straddles a transition zone between oceanic and continental crust. A new regional multi-channel seismic profile (973-01) across the region of NE South China Sea is introduced in this paper. In seismic stratigraphy and structural geology, a model of Cenozoic tectono-sedimentation of the Tainan Basin is established. The results show that three stages can be suggested in Tainan Basin; In Stage A (Oligocene (?)-Lower Miocene) the stratigraphy shows restricted rifting, indicating crustal extension. Terrestrial sedi- ments mostly filled the faulted sags of the North Depression on the continental shelf. Structural highs, including the Central Uplift, blocked material transportation to the South Depression in abyssal basin. In Stage B the Tainan Basin (Middle-Upper Miocene) exhibits a broad subsidence resulting from the post-rifting thermal cooling. The faulted-sags in North Depression had been filled up. Terrestrial materials were transported over the structural highs and deposited directly in the South Depression through sub- marine gullies or canyons. This sedimentation resulted in a crucial change in the slope to a modem shape. In Stage C (Latest Miocene-Recent) a phase change from extension to compression took place due to the orogeny caused by the overthrusting of the Luzon volcanic arc. Many inverse structures, such as thrusts, fault bend folds, and a regional unconformity were formed. Forland basin began developing.
基金Supported by the National Natural Science Foundation of China(No.41176133)
文摘We reviewed ampharetid genus Anobothrus Levinsen, 1884 in China seas based upon material deposited in the Marine Biological Museum of the Chinese Academy of Sciences (Qingdao). The genus includes A. glandularis (Hartmann-Schr6der, 1965), A. gracilis (Malmgren, 1866), A. mironovi Jirkov, 2008 and A. nataliae (Jirkov, 2008). A. glandularis and A. mironovi are recorded for the first time in Chinese waters. A key to Chinese species of Anobothrus is given.
基金Project(41172109)supported by the National Natural Science Foundation of ChinaProject(20110003110014)supported by the ResearchFoundation for the Doctoral Program of Higher Education,China
文摘The sand-conglomerate fans are the major depositional systems in the lower third member of Shahejie Formation in Shengtuo area, which formed in the deep lacustrine environment characterized by steep slope gradient, near sources and intensive tectonic activity. This work was focused on the sedimentary feature of the glutenite segment to conduct the seismic sedimentology research. The near-shore subaqueous fans and its relative gravity channel and slump turbidite fan depositions were identified according to observation and description of cores combining with the numerous data of seismic and logging. Then, the depositional model was built depending on the analysis of palaeogeomorphology. The seismic attributes which are related to the hydrocarbon but relative independent were chosen to conduct the analysis, the reservoir area of the glutenite segment was found performing a distribution where the amplitude value is relatively higher, and finally the RMS amplitude attribute was chosen to conduct the attribute predicting. At the same time, the horizontal distribution of the sedimentary facies was analyzed qualitatively. At last, the sparse spike inversion method was used to conduct the acoustic impedance inversion, and the inversion result can distinguish glutenite reservoir which is greater than 5 m. This method quantitatively characterizes the distribution area of the favorable reservoir sand.
文摘The Shanxi Institute of Coal Chemistry,Chinese Academy of Sciences has designed and prepared a multiple confined-zone-based nickel hydrogenation catalyst by means of the atomic layer deposition(ALD)technology.In comparison with the non-confined-zone based catalyst,the multiple confined-zone-based nickel catalyst possesses an enhanced catalytic reactivity and catalytic stability for hydrogenation of cinnamaldehyde and nitrobenzene.
基金supported by the Major Projects of International Cooperation of National Natural Science Foundation of China(Grant Nos.41210002 & 40672108)the Cheung Kong Scholars Programme of the Ministry of Education of China(Grant No.801813)
文摘The Badain Jaran Desert exhibits the greatest difference in altitude of all of the world's deserts.On the slopes of megadunes in the desert,there are physical and chemical deposits produced by surface runoff.In addition,we have observed rarely-seen infiltration-excess surface runoff in the megadune depressions as well as spring streams at the base of megadunes.We used electron microscopy,energy spectrum analysis,infiltration experiments,moisture content determinations and grain-size analysis to study the mineral and chemical composition of the runoff precipitates,and grain-size of the deposits associated with the runoff,together with the hydrological balance in the megadune area,and the atmospheric precipitation mechanism responsible for groundwater recharge and for supplying water to lakes.The observations of shallow runoff and infiltration-excess surface runoff indicate the occurrence of strong and effective precipitation in summer,which would provide an important source for groundwater recharge.Several lines of evidence,such as the physical and chemical deposits resulting from shallow subsurface runoff,spring streams,infiltration-excess runoff,and gravity capillary water with a moisture content of 3-6%,demonstrate that precipitation reaches the base of the megadunes through infiltration and subsequently becomes groundwater.The chemical deposits,such as newly-formed calcite and gypsum,and gray-black physical deposits,as well as different stages in the development of fan-shaped landforms resulting from shallow subsurface runoff,indicate that groundwater recharge in the area is the result of long-term precipitation,rather than intermittent individual major rainfall events.Fine sand layers with a low infiltration capacity lead to subsurface runoff emerging at the ground surface.Five factors play an important role in maintaining a positive water balance and in replenishing groundwater via rainfall:effective rainfall as a water source,the high infiltration capacity of the sands enabling rainfall to rapidly become capillary water in the dunes,low evapotranspiration rates due to the sparse vegetation,the fact that the depth of the sand layer influenced by evaporation is shallow enough to maximize the deep infiltration of rainfall,and rapidly-moving gravity capillary water in the sandy dunes.These five factors together constitute a mechanism for groundwater recharge from rainfall,and explain the origin of the groundwater and lakes in the area.Our findings represent a significant advance in research on the hydrological cycle,including groundwater recharge conditions and recharge mechanisms,in this desert region.