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金属掺杂中孔分子筛的合成及其研究 被引量:3
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作者 杜丽 刘军民 廖世军 《石油学报(石油加工)》 EI CAS CSCD 北大核心 2006年第B10期210-213,共4页
以十二烷二胺(DADD)为模板剂,TEOS为硅源,通过水热合成法制备出了具有高金属含量的中孔分子筛Zr-MSU—V和Nd—MSU—V,采用XRD、TG-DTA和TEM等对合成的分子筛进行了表征。XRD结果表明,即使当Si/Zr或Si/Nd的摩尔比达到5或20时,... 以十二烷二胺(DADD)为模板剂,TEOS为硅源,通过水热合成法制备出了具有高金属含量的中孔分子筛Zr-MSU—V和Nd—MSU—V,采用XRD、TG-DTA和TEM等对合成的分子筛进行了表征。XRD结果表明,即使当Si/Zr或Si/Nd的摩尔比达到5或20时,获得的两种分子筛Zr-MSU-V和Nd—MSU—V均能保持良好的结晶度,TEM图清楚地展示了Zr—MSU—V具有有序的层状结构;TG-DTA的结果显示,903K焙烧脱除模板剂不会破坏金属嵌入分子筛的结构,说明其具有良好的热稳定性;通过48h水热处理后的分子筛仍保持其结构有序性,说明其具有优良的水热稳定性。 展开更多
关键词 MSU—V 嵌入 中孔物质
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提高MCM-41分子筛稳定性的研究 被引量:13
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作者 高雄厚 毛学文 +2 位作者 唐荣荣 刘从华 沈师孔 《石油学报(石油加工)》 EI CAS CSCD 北大核心 1997年第3期15-20,共6页
采用XRD、IR、TEM及自动吸附仪分析了常规MCM-41硅铝分子筛的热与水热稳定性差的原因,并采取增加超大孔分子筛孔壁厚度的措施,合成出了结构稳定性良好的MCM-41分子筛,同时考察了影响MCM-41分子筛孔壁厚度... 采用XRD、IR、TEM及自动吸附仪分析了常规MCM-41硅铝分子筛的热与水热稳定性差的原因,并采取增加超大孔分子筛孔壁厚度的措施,合成出了结构稳定性良好的MCM-41分子筛,同时考察了影响MCM-41分子筛孔壁厚度的因素。结果表明,适当降低反应体系的pH值,向体系中加入适量电解质能有效地提高MCM-41分子筛孔壁厚度。壁厚2.7nm的MCM-41分子筛在800℃水蒸汽处理2h后,XRD峰强度保留率为55%,从而使MCM-41分子筛的水热稳定性提高到一个新的高度。 展开更多
关键词 MCM-41沸石 中孔物质 稳定性 分子筛 原油
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Response of coal reservoir porosity to magma intrusion in the Shandong Qiwu Mine,China 被引量:4
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作者 Li Wu Zhu Yanming +1 位作者 Chen Shangbin Wang Hui 《Mining Science and Technology》 EI CAS 2011年第2期185-190,共6页
The Qiwu Mine is located in the Ten Xian coal field of Shandong province.It experienced repeated volcanic activity,after the coal beds formed,where magma intrusion was significant The effect of coal reservoir porosity... The Qiwu Mine is located in the Ten Xian coal field of Shandong province.It experienced repeated volcanic activity,after the coal beds formed,where magma intrusion was significant The effect of coal reservoir porosity after magma intrusion was studied by analysis of regional and mine structure and magmatic activity.Experimental methods including maceral measurement under the microscope and mercury porosimetry were used for testing the pore structure.The authors believe that magma intrusion into low-rank bituminous coal causes reservoir porosity to gradually increase:the closer to the magmatic rock a sample is,the less the porosity.The pore size distribution also changes.In the natural coal bed the pore size is mainly in the transitive and middle pore range.However,the coal changes to anthracite next to the magmatic rock and larger pores dominate.Regional magma thermal evolution caused coal close to magmatic rock to be roasted,which reduced the volatile matter,developed larger holes,and destroyed plant tissue holes.The primary reason for a porosity decrease in the vicinity of magmatic rock is that Bituminite resulting from the roasting fills the holes that were present initially. 展开更多
关键词 Magma intrusion Coal reservoir porosity Low-rank bituminous coal Qiwu Mine
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Sediment consolidation settlement of Chengbei Sea area in the northern Huanghe River subaqueous delta,China
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作者 刘杰 冯秀丽 刘潇 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2017年第3期693-703,共11页
One of the most important factors controlling the morphology of the modem Huanghe (Yellow) River delta is consolidation settlement, which is impacted by fast deposition, high water content, and low density of seaflo... One of the most important factors controlling the morphology of the modem Huanghe (Yellow) River delta is consolidation settlement, which is impacted by fast deposition, high water content, and low density of seafloor sediment. Consolidation settlement of the Huanghe River subaqueous delta was studied based on field data, laboratory experiments on 12 drill holes, and the one-dimensional consolidation theory. Results show that vertical sediment characteristics varied greatly in the rapidly forming sedimentary bodies of the modem Huanghe River subaqueous delta. Sediments in the upper parts of drill holes were coarser than those in the deeper parts, and other physical and mechanical properties changed accordingly. On the basis of the one-dimensional consolidation theory and drilling depth, the final consolidation settlement of drill holes was between 0.6 m and 2.8 m, and the mean settlement of unit depth was at 1.5-3.5 cm/m. It takes about 15-20 years for the consolidation degree to reach 90% and the average sedimentation rate within the overlying 50 m strata was at 5 cm/a to 12 cm/a. This study helps to forecast the final consolidation settlement and settlement rate of the modem Huanghe River subaqueous delta, which provides key geotechnical information for marine engineers. 展开更多
关键词 mechanical properties consolidation settlement drill hole modem Huanghe River subaqueous delta
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