This paper analyzes the defaults of traditional method according to the resource management method of grid computing based on virtual organization. It supports the concept to ameliorate the resource management with mo...This paper analyzes the defaults of traditional method according to the resource management method of grid computing based on virtual organization. It supports the concept to ameliorate the resource management with mobile agent and gives the ameliorated resource management model. Also pointed out is the methodology of ameliorating resource management and the way to realize in reality.展开更多
Massive information flows are gen- erated from interactive processing and visua- lizations. To efficiently support information transmission over the Interact, information cen- tric architecture has been recently propo...Massive information flows are gen- erated from interactive processing and visua- lizations. To efficiently support information transmission over the Interact, information cen- tric architecture has been recently proposed. In this paper, we consider an information centric architecture, called the data centric networking architecture to provide communication servi- ces to big data, where a service identifier is used to name the data objects. We propose dif- ferent approaches for the dissemination of data objects in a large-scale data centric network. In particular, we propose various approaches to link the data dissemination approach with the topology of the Internet. Further, we eva- luate the proposed approaches with respect to data delivery efficiency, round-trip time imp- rovement, and deployment cost. Based on the results obtained from this study, it can be sh- own that by disseminating data objects to small ISPs, the data delivery efficiency can be significantly improved within an acceptable deployment cost.展开更多
The pyrolysis of zeolitic imidazolate frameworks(ZIFs) is becoming a popular approach for the synthesis of catalysts comprising porphyrin-like metal single atom catalysts(SACs) on N-doped carbons(M-N-C).Understanding ...The pyrolysis of zeolitic imidazolate frameworks(ZIFs) is becoming a popular approach for the synthesis of catalysts comprising porphyrin-like metal single atom catalysts(SACs) on N-doped carbons(M-N-C).Understanding the structural evolution of M-N-C as a function of ZIF pyrolysis temperature is important for realizing high performance catalysts.Herein,we report a detailed investigation of the evolution of Zn single atom catalyst sites during the pyrolysis of ZIF-8 at temperatures ranging from 500 to 900℃.Results from Zn L-edge and Zn K-edge X-ray absorption spectroscopy studies reveal that tetrahedral ZnN4 centers in ZIF-8 transform to porphyrin-like ZnN4 centers supported on N-doped carbon at temperatures as low as 600℃.As the pyrolysis temperature increased in the range 600-900℃,the Zn atoms moved closer to the N4 coordination plane.This subtle geometry change in the ZnN4 sites alters the electron density on the Zn atoms(formally Zn2+),strongly impacting the catalytic performance for the peroxidase-like decomposition of H2 O2.The catalyst obtained at 800℃(Zn-N-C-800) offered the best performance for H2 O2 decomposition.This work provides valuable new insights about the evolution of porphyrin-like single metal sites on N-doped carbons from ZIF precursors and the factors influencing SAC activity.展开更多
基金Sponsored by the National Natural Science Foundation of China (No.60573141& No.70271050), National 863 High Technology Research Program of China (No.2005AA775050), the Natural Science Foundation of Jiangsu Province (No.BK2005146), High Technology Research Programme of Jiangsu Province (No.BG2004004, No.BG2005038, No.BG2006001), High Technology Research Programme of Nanjing (No.2006RZ105), and key Laboratory of Information Technology Processing of Jiangsu Province (kjs05001), Jiangsu Provincial Research Scheme of Natural Science for Higher Education Institutions (05KJB520092).
文摘This paper analyzes the defaults of traditional method according to the resource management method of grid computing based on virtual organization. It supports the concept to ameliorate the resource management with mobile agent and gives the ameliorated resource management model. Also pointed out is the methodology of ameliorating resource management and the way to realize in reality.
基金supported by the National Science and Technology Major Projects of the Ministry of Science and Technology of China under Grant No.2012ZX03005003the State Key Program of National Natural Science of China under Grant No.61232017+3 种基金the National Basic Research Program of China(973 Program)under Grant No.2013CB329101the National Natural Science Foundation of China under Grants No.61102049,No.61271202the Beijing Natural Science Foundation underGrants No.4132053,No.4122060the Scientific Research Foundation of the Returned Overseas Chinese Scholars of State Education Ministry under Grant No.W13C300010
文摘Massive information flows are gen- erated from interactive processing and visua- lizations. To efficiently support information transmission over the Interact, information cen- tric architecture has been recently proposed. In this paper, we consider an information centric architecture, called the data centric networking architecture to provide communication servi- ces to big data, where a service identifier is used to name the data objects. We propose dif- ferent approaches for the dissemination of data objects in a large-scale data centric network. In particular, we propose various approaches to link the data dissemination approach with the topology of the Internet. Further, we eva- luate the proposed approaches with respect to data delivery efficiency, round-trip time imp- rovement, and deployment cost. Based on the results obtained from this study, it can be sh- own that by disseminating data objects to small ISPs, the data delivery efficiency can be significantly improved within an acceptable deployment cost.
基金supported by the Ministry of Business, Innovation and Employment Catalyst Fund (MAUX 1609)the University of Auckland Faculty Research Development Fund+1 种基金the MacDiarmid Institute for Advanced Materials and Nanotechnologya generous philanthropic donation from Greg and Kathryn Trounson。
文摘The pyrolysis of zeolitic imidazolate frameworks(ZIFs) is becoming a popular approach for the synthesis of catalysts comprising porphyrin-like metal single atom catalysts(SACs) on N-doped carbons(M-N-C).Understanding the structural evolution of M-N-C as a function of ZIF pyrolysis temperature is important for realizing high performance catalysts.Herein,we report a detailed investigation of the evolution of Zn single atom catalyst sites during the pyrolysis of ZIF-8 at temperatures ranging from 500 to 900℃.Results from Zn L-edge and Zn K-edge X-ray absorption spectroscopy studies reveal that tetrahedral ZnN4 centers in ZIF-8 transform to porphyrin-like ZnN4 centers supported on N-doped carbon at temperatures as low as 600℃.As the pyrolysis temperature increased in the range 600-900℃,the Zn atoms moved closer to the N4 coordination plane.This subtle geometry change in the ZnN4 sites alters the electron density on the Zn atoms(formally Zn2+),strongly impacting the catalytic performance for the peroxidase-like decomposition of H2 O2.The catalyst obtained at 800℃(Zn-N-C-800) offered the best performance for H2 O2 decomposition.This work provides valuable new insights about the evolution of porphyrin-like single metal sites on N-doped carbons from ZIF precursors and the factors influencing SAC activity.
