Levulinic acid（LA） has been identified as a promising green,biomass derived platform chemical.Response surface analysis（RSA） with a four-factor-five-level central composite design（CCD） was applied to optimize th...Levulinic acid（LA） has been identified as a promising green,biomass derived platform chemical.Response surface analysis（RSA） with a four-factor-five-level central composite design（CCD） was applied to optimize the hydrolysis conditions for the conversion of bamboo（Phyllostachys Praecox f.preveynalis） shoot shell（BSS） to LA catalyzed with ionic liquid [C4mim]HSO4.The effects of four main reaction parameters including temperature,time,C[C4mim]HSO4（initial [C4mim]HSO4 concentration） and XBSS（initial BSS intake） on the hydrolysis reaction for yield of LA were analyzed.A quadratic equation model for yield of LA was established and fitted to the data with an R2 of 0.9868,and effects of main factors and their corresponding relationships were obtained with RSA.Model validation and results of CCD showed good correspondence between actual and predicted values.The analysis of variance（ANOVA） of the results indicated that the yield of LA in the range studied was significantly（P＆lt;0.05） affected by the four factors.The optimized reaction conditions were as follows：temperature of 145 ℃,time of 103.8 min,C[C4mim]HSO4 of 0.9 mol.L-1 and XBSS of 2.04%（by mass）,respectively.A high yield [（71±0.41）%（by mol）,triplicate experiment] was obtained at the optimum conditions of temperature of 145 ℃,time of 104 min,C[C4mim]HSO4 of 0.9 mol.L-1 and XBSS of 2%（by mass）,which obtained from the real experiments,concurred with the model prediction [73.8%（by mol） based on available C6 sugars in BSS or 17.9%（by mass） based on the mass of BSS],indicating that the model was adequate for the hydrolysis process.展开更多
With the rapid development in cloud data centers and cloud service customers,the demand for high quality cloud service has been grown rapidly.To face this reality,this paper focuses on service optimization issues in c...With the rapid development in cloud data centers and cloud service customers,the demand for high quality cloud service has been grown rapidly.To face this reality,this paper focuses on service optimization issues in cloud computing environment.First,a service-oriented architecture is proposed and programmable network facilities are utilized in it to optimize specific cloud services.Then various cloud services are categorized into two subcategories;static services and dynamic services.Furthermore,the concepts of cloud service quality and cloud resource idle rate are defined,and the aforementioned concepts have also been taken into consideration as parameters in the service optimization algorithm to improve the cloud service quality and optimize system workload simultaneously.Numerical simulations are conducted to verify the effectiveness of the proposed algorithm in balancing the workload of all servers.展开更多
基金Supported by the National Natural Science Foundation of China（30940058,31170672）the Natural Science Foundation of Zhejiang Province of China（Y3110025）+1 种基金Key Laboratory for Physical Processing of Agricultural Products（JAPP2010-4）Key Laboratory of Exploitation and Preservation of Coastal Bio-resource（2010F30003）
文摘Levulinic acid（LA） has been identified as a promising green,biomass derived platform chemical.Response surface analysis（RSA） with a four-factor-five-level central composite design（CCD） was applied to optimize the hydrolysis conditions for the conversion of bamboo（Phyllostachys Praecox f.preveynalis） shoot shell（BSS） to LA catalyzed with ionic liquid [C4mim]HSO4.The effects of four main reaction parameters including temperature,time,C[C4mim]HSO4（initial [C4mim]HSO4 concentration） and XBSS（initial BSS intake） on the hydrolysis reaction for yield of LA were analyzed.A quadratic equation model for yield of LA was established and fitted to the data with an R2 of 0.9868,and effects of main factors and their corresponding relationships were obtained with RSA.Model validation and results of CCD showed good correspondence between actual and predicted values.The analysis of variance（ANOVA） of the results indicated that the yield of LA in the range studied was significantly（P＆lt;0.05） affected by the four factors.The optimized reaction conditions were as follows：temperature of 145 ℃,time of 103.8 min,C[C4mim]HSO4 of 0.9 mol.L-1 and XBSS of 2.04%（by mass）,respectively.A high yield [（71±0.41）%（by mol）,triplicate experiment] was obtained at the optimum conditions of temperature of 145 ℃,time of 104 min,C[C4mim]HSO4 of 0.9 mol.L-1 and XBSS of 2%（by mass）,which obtained from the real experiments,concurred with the model prediction [73.8%（by mol） based on available C6 sugars in BSS or 17.9%（by mass） based on the mass of BSS],indicating that the model was adequate for the hydrolysis process.
基金Supported by the National Natural Science Foundation of China(No.61272508,61472033,61202432)
文摘With the rapid development in cloud data centers and cloud service customers,the demand for high quality cloud service has been grown rapidly.To face this reality,this paper focuses on service optimization issues in cloud computing environment.First,a service-oriented architecture is proposed and programmable network facilities are utilized in it to optimize specific cloud services.Then various cloud services are categorized into two subcategories;static services and dynamic services.Furthermore,the concepts of cloud service quality and cloud resource idle rate are defined,and the aforementioned concepts have also been taken into consideration as parameters in the service optimization algorithm to improve the cloud service quality and optimize system workload simultaneously.Numerical simulations are conducted to verify the effectiveness of the proposed algorithm in balancing the workload of all servers.
