Mg-Al-Pb alloy is one of the newly developed materials for the seawater activated batteries. As-cast Mg-6Al-5Pb and Mg-6Al-5Pb-0.5Mn alloys with different additions of Al-15%Mn (mass fraction), Al-30%Mn and Al-50%Mn...Mg-Al-Pb alloy is one of the newly developed materials for the seawater activated batteries. As-cast Mg-6Al-5Pb and Mg-6Al-5Pb-0.5Mn alloys with different additions of Al-15%Mn (mass fraction), Al-30%Mn and Al-50%Mn master alloys were prepared by melting and casting. Their microstructures were observed by optical microscopy and scanning electron microscopy. The electrochemical properties, hydrogen evolution and mass loss of Mg-6Al-5Pb-0.5Mn alloys were studied. The results show that Mg-6Al-5Pb-0.5Mn alloy added with Al-50%Mn master alloy provides more negative corrosion average potential (-1.66 V), smaller corrosion current density (7 μm/cm2) and lower free corrosion rate (0.51 mg·cm-2·h-1) than other alloys. This is probably attributed to the presence of Al11Mn4 phase, which facilitates the self-peeling of corrosion products and enlarges the electrochemical reaction area as well as enhances the electrochemical activity.展开更多
This paper summarizes a set of interpretation technologies for Mesozoic sandstone reservoir prediction in the Longdong loess plateau, such as seismic sequence processing and interpretation based on generalized S trans...This paper summarizes a set of interpretation technologies for Mesozoic sandstone reservoir prediction in the Longdong loess plateau, such as seismic sequence processing and interpretation based on generalized S transform, the eroded paleo-geomorphology interpretation of the top of the Triassic and a variety of lateral reservoir predictions. The effects of employing these technologies are compared and analyzed, as well. The research results show that seismic sequence processing interpretation technology based on generalized S transform can distinguish 3ms (about the thickness of 6 m)sequence interface. Consequently the technology can ascertain the distribution of a sand body of the formation Ch 8 and expand the exploration area of the Xifeng oil field in the Longdong area.展开更多
Fractionation of heavy metals in sediments can help in understanding potential hazards of heavy metals. The present study analyzed total concentrations and fractions of selected heavy metals (Cd, Cr, Cu, Pb, and Zn)...Fractionation of heavy metals in sediments can help in understanding potential hazards of heavy metals. The present study analyzed total concentrations and fractions of selected heavy metals (Cd, Cr, Cu, Pb, and Zn) in surface sediments from Dianchi Lake, Yunnan Province, China, as well as factors that may affect distributions of the various heavy metal fractions. Total concentrations of the heavy metals decreased in the order Zn 〉 Cu 〉 Pb 〉 Cr 〉 Cd. These heavy metals, except Cr, were much higher than their background levels, indicating that Dianchi Lake was polluted by Cd, Zn, Pb, and Cu. Cadmium occurred mainly as the non-residual fraction (sum of the HOAc-soluble, reducible, and oxidizable fractions) (97.6%), and Zn (55.7%) was also predominantly found in the non-residual fraction. In contrast, most of the Cr (88.5%), Pb (81.8%), and Cu (59.2%) occurred in the residual fraction. Correlation analysis showed that total heavy metal concentrations, organic matter and reducible Fe were the main factors affecting the distributions of the various heavy metal fractions. In the Walhai section of Dianchi Lake (comprising 97% of the lake area), the concentrations of Cd, Zn, Pb, and Cu in the non-residual fraction were significantly lower (P ≤ 0.01 or 0.05) than those of the Caohal section (3% of the lake area). This indicated that potential heavy metal hazards in the Caohai section were greater than the Waihai section.展开更多
We studied the effect of pH (pH 5, 6, 7 and 8) on the hatching percentage, survival and reproduction of Artemia strains in Bohai Bay salt ponds. Strains included parthenogenetic Artemia from Bohai Bay (BHB), Artem...We studied the effect of pH (pH 5, 6, 7 and 8) on the hatching percentage, survival and reproduction of Artemia strains in Bohai Bay salt ponds. Strains included parthenogenetic Artemia from Bohai Bay (BHB), Artemiafranciscana from San Francisco Bay, and A. franciscana artificially produced in salt ponds in Vietnam. The latter was included as a potential inoculum for biological management of salt ponds. The hatching percentage of cysts after 24 h and the survival rate of the tested Artemia strains were significantly reduced when exposed to a culture medium at pH 5 for 18 d (P〈0.05). The tolerance of Artemia to 48 h acid exposure varied with developmental stage, increasing in the following order: juvenile, nauplii, pre-adult, with maximum tolerance in adults. All strains of Artemia tested could not reproduce at pH 5. At pH levels from pH 6-8, a higher pH generally resulted in a shorter brood interval and enhanced ovoviviparity. Hence, we suggest that brine acidification has a negative impact on Artemia populations in the Bohai Bay saltworks. Inoculation of Artemia with either local parthenogenetic Artemia or exotic A. franeiscana should be feasible at pH 7-8.展开更多
Coccolith assemblages in two gravity cores(KX21-2 and KX12-1) from the central Western Pacific Warm Pool(WPWP) have been analyzed with SYRACO. The variations of nutricline and primary productivity(PP) have been recons...Coccolith assemblages in two gravity cores(KX21-2 and KX12-1) from the central Western Pacific Warm Pool(WPWP) have been analyzed with SYRACO. The variations of nutricline and primary productivity(PP) have been reconstructed based on these assemblages. The results show that the coccolith assemblages were dominated by Florisphaera profunda, Gephyrocapsa and Emiliania huxleyi over the last 380 kyr. Variations of nutricline and primary productivity can be divided into three intervals. Interval I(about 380–300 kyr): PP was high and nutricline was shallow; Interval II(about 300–160 kyr): PP decreased dramatically for a short time after the acme of G. caribbeanica in Mid-Brunhes while nutricline became deeper; Interval III(about 160 kyr–present): PP fluctuated at low levels and nutricline was deep. Variations of each coccolith taxon and PP were highly correlated in the two cores, which means that the geological environment is similar in the two cores. Spectrum analysis is performed for all coccolith taxons and PP, and the 19-kyr cycle is the most prominent. It means that the production of coccolithophores in the WPWP is mainly controlled by precession.展开更多
The China Seas include the South China Sea, East China Sea, Yellow Sea, and Bohai Sea. Located off the Northwestern Pacific margin, covering 4700000 km^2 from tropical to northern temperate zones, and including a vari...The China Seas include the South China Sea, East China Sea, Yellow Sea, and Bohai Sea. Located off the Northwestern Pacific margin, covering 4700000 km^2 from tropical to northern temperate zones, and including a variety of continental margins/basins and depths, the China Seas provide typical cases for carbon budget studies. The South China Sea being a deep basin and part of the Western Pacific Warm Pool is characterized by oceanic features; the East China Sea with a wide continental shelf, enormous terrestrial discharges and open margins to the West Pacific, is featured by strong cross-shelf materials transport; the Yellow Sea is featured by the confluence of cold and warm waters; and the Bohai Sea is a shallow semiclosed gulf with strong impacts of human activities. Three large rivers, the Yangtze River, Yellow River, and Pearl River, flow into the East China Sea, the Bohai Sea, and the South China Sea, respectively. The Kuroshio Current at the outer margin of the Chinese continental shelf is one of the two major western boundary currents of the world oceans and its strength and position directly affect the regional climate of China. These characteristics make the China Seas a typical case of marginal seas to study carbon storage and fluxes. This paper systematically analyzes the literature data on the carbon pools and fluxes of the Bohai Sea,Yellow Sea, East China Sea, and South China Sea, including different interfaces(land-sea, sea-air, sediment-water, and marginal sea-open ocean) and different ecosystems(mangroves, wetland, seagrass beds, macroalgae mariculture, coral reefs, euphotic zones, and water column). Among the four seas, the Bohai Sea and South China Sea are acting as CO_2 sources, releasing about0.22 and 13.86–33.60 Tg C yr^(-1) into the atmosphere, respectively, whereas the Yellow Sea and East China Sea are acting as carbon sinks, absorbing about 1.15 and 6.92–23.30 Tg C yr^(-1) of atmospheric CO_2, respectively. Overall, if only the CO_2 exchange at the sea-air interface is considered, the Chinese marginal seas appear to be a source of atmospheric CO_2, with a net release of 6.01–9.33 Tg C yr^(-1), mainly from the inputs of rivers and adjacent oceans. The riverine dissolved inorganic carbon (DIC) input into the Bohai Sea and Yellow Sea, East China Sea, and South China Sea are 5.04, 14.60, and 40.14 Tg C yr^(-1),respectively. The DIC input from adjacent oceans is as high as 144.81 Tg C yr^(-1), significantly exceeding the carbon released from the seas to the atmosphere. In terms of output, the depositional fluxes of organic carbon in the Bohai Sea, Yellow Sea, East China Sea, and South China Sea are 2.00, 3.60, 7.40, and 5.92 Tg C yr^(-1), respectively. The fluxes of organic carbon from the East China Sea and South China Sea to the adjacent oceans are 15.25–36.70 and 43.93 Tg C yr^(-1), respectively. The annual carbon storage of mangroves, wetlands, and seagrass in Chinese coastal waters is 0.36–1.75 Tg C yr^(-1), with a dissolved organic carbon(DOC) output from seagrass beds of up to 0.59 Tg C yr^(-1). Removable organic carbon flux by Chinese macroalgae mariculture account for 0.68 Tg C yr^(-1) and the associated POC depositional and DOC releasing fluxes are 0.14 and 0.82 Tg C yr^(-1), respectively. Thus, in total, the annual output of organic carbon, which is mainly DOC, in the China Seas is 81.72–104.56 Tg C yr^(-1). The DOC efflux from the East China Sea to the adjacent oceans is 15.00–35.00 Tg C yr^(-1). The DOC efflux from the South China Sea is 31.39 Tg C yr^(-1). Although the marginal China Seas seem to be a source of atmospheric CO_2 based on the CO_2 flux at the sea-air interface, the combined effects of the riverine input in the area, oceanic input, depositional export,and microbial carbon pump(DOC conversion and output) indicate that the China Seas represent an important carbon storage area.展开更多
Using the 1961–1995 monthly averaged meteorological data from 148 surface stations in the Qinghai-Xizang Plateau (QXP) and its surrounding areas, calculation of the 35-year atmospheric heat source/sink (<Qi>) a...Using the 1961–1995 monthly averaged meteorological data from 148 surface stations in the Qinghai-Xizang Plateau (QXP) and its surrounding areas, calculation of the 35-year atmospheric heat source/sink (<Qi>) and an analysis on its climatic features and relation to rainfall in China have been made. It is found that on the average, the atmospheric heat source over the QXP is the strongest in June (78 W / m2) and cold source is the strongest in December (?72 W/m2). The sensible heat of the surface increases remarkably over the southwest of the QXP, causing the obvious increase of <Qi> there in February and March, which makes a center of the atmospheric heat source appear over the north slope of the Himalayas. Afterwards, this center continues to intensify and experiences noticeable migration westwards twice, separately occurring in April and June. The time when the atmosphere over the east of the QXP becomes heat source and reaches strongest is one month later than that over the southwest of the QXP. In summer, the latent heat of condensation becomes a heating factor as important as the sensible heat and is also a main factor that makes the atmospheric heat source over the east of the QXP continue growing. On the interdecadal time scale, (Q1) of the QXP shows an abrupt change in 1977 and a remarkable increase after 1977. The atmospheric heat source of the spring over the QXP is a good indicator for the subsequent summer rainfall over the valleys of the Changjiang and Huaihe rivers and South China and North China. There is remarkable positive correlation between the QXP heat source of summer and the summer rainfall in the valleys of the Changjiang River.展开更多
基金Project(JPPT-115-168)supported by the National Key Science and Technological Project of ChinaProject(51101171)supported by the National Natural Science Foundation of China
文摘Mg-Al-Pb alloy is one of the newly developed materials for the seawater activated batteries. As-cast Mg-6Al-5Pb and Mg-6Al-5Pb-0.5Mn alloys with different additions of Al-15%Mn (mass fraction), Al-30%Mn and Al-50%Mn master alloys were prepared by melting and casting. Their microstructures were observed by optical microscopy and scanning electron microscopy. The electrochemical properties, hydrogen evolution and mass loss of Mg-6Al-5Pb-0.5Mn alloys were studied. The results show that Mg-6Al-5Pb-0.5Mn alloy added with Al-50%Mn master alloy provides more negative corrosion average potential (-1.66 V), smaller corrosion current density (7 μm/cm2) and lower free corrosion rate (0.51 mg·cm-2·h-1) than other alloys. This is probably attributed to the presence of Al11Mn4 phase, which facilitates the self-peeling of corrosion products and enlarges the electrochemical reaction area as well as enhances the electrochemical activity.
文摘This paper summarizes a set of interpretation technologies for Mesozoic sandstone reservoir prediction in the Longdong loess plateau, such as seismic sequence processing and interpretation based on generalized S transform, the eroded paleo-geomorphology interpretation of the top of the Triassic and a variety of lateral reservoir predictions. The effects of employing these technologies are compared and analyzed, as well. The research results show that seismic sequence processing interpretation technology based on generalized S transform can distinguish 3ms (about the thickness of 6 m)sequence interface. Consequently the technology can ascertain the distribution of a sand body of the formation Ch 8 and expand the exploration area of the Xifeng oil field in the Longdong area.
基金Project supported by the Science and Technology Program for Social Development of Jiangsu Province,China (No.BS2006060)Startup Fund of Nanjing University of Information Science & Technology, the State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering, Hohai University (No. 2005406711)the Jiangsu Key Laboratory of Environmental Change and Ecological Construction, Nanjing Normal University.
文摘Fractionation of heavy metals in sediments can help in understanding potential hazards of heavy metals. The present study analyzed total concentrations and fractions of selected heavy metals (Cd, Cr, Cu, Pb, and Zn) in surface sediments from Dianchi Lake, Yunnan Province, China, as well as factors that may affect distributions of the various heavy metal fractions. Total concentrations of the heavy metals decreased in the order Zn 〉 Cu 〉 Pb 〉 Cr 〉 Cd. These heavy metals, except Cr, were much higher than their background levels, indicating that Dianchi Lake was polluted by Cd, Zn, Pb, and Cu. Cadmium occurred mainly as the non-residual fraction (sum of the HOAc-soluble, reducible, and oxidizable fractions) (97.6%), and Zn (55.7%) was also predominantly found in the non-residual fraction. In contrast, most of the Cr (88.5%), Pb (81.8%), and Cu (59.2%) occurred in the residual fraction. Correlation analysis showed that total heavy metal concentrations, organic matter and reducible Fe were the main factors affecting the distributions of the various heavy metal fractions. In the Walhai section of Dianchi Lake (comprising 97% of the lake area), the concentrations of Cd, Zn, Pb, and Cu in the non-residual fraction were significantly lower (P ≤ 0.01 or 0.05) than those of the Caohal section (3% of the lake area). This indicated that potential heavy metal hazards in the Caohai section were greater than the Waihai section.
基金Supported by the International Cooperation Research Program of the Ministry of Science&Technology of China(No.2010DFA32300)the Pilot Project for International Cooperation"Aquaculture in Hebei and Shandong Provinces"funded by the Province of East-Flanders,Belgiumthe Nature Science Foundation of Tianjin(No.13JCZDJC28700)
文摘We studied the effect of pH (pH 5, 6, 7 and 8) on the hatching percentage, survival and reproduction of Artemia strains in Bohai Bay salt ponds. Strains included parthenogenetic Artemia from Bohai Bay (BHB), Artemiafranciscana from San Francisco Bay, and A. franciscana artificially produced in salt ponds in Vietnam. The latter was included as a potential inoculum for biological management of salt ponds. The hatching percentage of cysts after 24 h and the survival rate of the tested Artemia strains were significantly reduced when exposed to a culture medium at pH 5 for 18 d (P〈0.05). The tolerance of Artemia to 48 h acid exposure varied with developmental stage, increasing in the following order: juvenile, nauplii, pre-adult, with maximum tolerance in adults. All strains of Artemia tested could not reproduce at pH 5. At pH levels from pH 6-8, a higher pH generally resulted in a shorter brood interval and enhanced ovoviviparity. Hence, we suggest that brine acidification has a negative impact on Artemia populations in the Bohai Bay saltworks. Inoculation of Artemia with either local parthenogenetic Artemia or exotic A. franeiscana should be feasible at pH 7-8.
基金supported by the National Natural Science Foundation of China (Nos. 41376047, 91428310, 91228204)
文摘Coccolith assemblages in two gravity cores(KX21-2 and KX12-1) from the central Western Pacific Warm Pool(WPWP) have been analyzed with SYRACO. The variations of nutricline and primary productivity(PP) have been reconstructed based on these assemblages. The results show that the coccolith assemblages were dominated by Florisphaera profunda, Gephyrocapsa and Emiliania huxleyi over the last 380 kyr. Variations of nutricline and primary productivity can be divided into three intervals. Interval I(about 380–300 kyr): PP was high and nutricline was shallow; Interval II(about 300–160 kyr): PP decreased dramatically for a short time after the acme of G. caribbeanica in Mid-Brunhes while nutricline became deeper; Interval III(about 160 kyr–present): PP fluctuated at low levels and nutricline was deep. Variations of each coccolith taxon and PP were highly correlated in the two cores, which means that the geological environment is similar in the two cores. Spectrum analysis is performed for all coccolith taxons and PP, and the 19-kyr cycle is the most prominent. It means that the production of coccolithophores in the WPWP is mainly controlled by precession.
基金supported by the National Key Research and Development Program of China (Grant No. 2016YFA0601400)the National Natural Science Foundation of China (Grant Nos. 91751207, 91428308, 41722603, 41606153 and 41422603)+1 种基金the Fundamental Research Funds for the Central Universities (Grant No. 20720170107)CNOOC Projects (Grant Nos. CNOOC-KJ125FZDXM00TJ001-2014 and CNOOCKJ125FZDXM00ZJ001-2014)
文摘The China Seas include the South China Sea, East China Sea, Yellow Sea, and Bohai Sea. Located off the Northwestern Pacific margin, covering 4700000 km^2 from tropical to northern temperate zones, and including a variety of continental margins/basins and depths, the China Seas provide typical cases for carbon budget studies. The South China Sea being a deep basin and part of the Western Pacific Warm Pool is characterized by oceanic features; the East China Sea with a wide continental shelf, enormous terrestrial discharges and open margins to the West Pacific, is featured by strong cross-shelf materials transport; the Yellow Sea is featured by the confluence of cold and warm waters; and the Bohai Sea is a shallow semiclosed gulf with strong impacts of human activities. Three large rivers, the Yangtze River, Yellow River, and Pearl River, flow into the East China Sea, the Bohai Sea, and the South China Sea, respectively. The Kuroshio Current at the outer margin of the Chinese continental shelf is one of the two major western boundary currents of the world oceans and its strength and position directly affect the regional climate of China. These characteristics make the China Seas a typical case of marginal seas to study carbon storage and fluxes. This paper systematically analyzes the literature data on the carbon pools and fluxes of the Bohai Sea,Yellow Sea, East China Sea, and South China Sea, including different interfaces(land-sea, sea-air, sediment-water, and marginal sea-open ocean) and different ecosystems(mangroves, wetland, seagrass beds, macroalgae mariculture, coral reefs, euphotic zones, and water column). Among the four seas, the Bohai Sea and South China Sea are acting as CO_2 sources, releasing about0.22 and 13.86–33.60 Tg C yr^(-1) into the atmosphere, respectively, whereas the Yellow Sea and East China Sea are acting as carbon sinks, absorbing about 1.15 and 6.92–23.30 Tg C yr^(-1) of atmospheric CO_2, respectively. Overall, if only the CO_2 exchange at the sea-air interface is considered, the Chinese marginal seas appear to be a source of atmospheric CO_2, with a net release of 6.01–9.33 Tg C yr^(-1), mainly from the inputs of rivers and adjacent oceans. The riverine dissolved inorganic carbon (DIC) input into the Bohai Sea and Yellow Sea, East China Sea, and South China Sea are 5.04, 14.60, and 40.14 Tg C yr^(-1),respectively. The DIC input from adjacent oceans is as high as 144.81 Tg C yr^(-1), significantly exceeding the carbon released from the seas to the atmosphere. In terms of output, the depositional fluxes of organic carbon in the Bohai Sea, Yellow Sea, East China Sea, and South China Sea are 2.00, 3.60, 7.40, and 5.92 Tg C yr^(-1), respectively. The fluxes of organic carbon from the East China Sea and South China Sea to the adjacent oceans are 15.25–36.70 and 43.93 Tg C yr^(-1), respectively. The annual carbon storage of mangroves, wetlands, and seagrass in Chinese coastal waters is 0.36–1.75 Tg C yr^(-1), with a dissolved organic carbon(DOC) output from seagrass beds of up to 0.59 Tg C yr^(-1). Removable organic carbon flux by Chinese macroalgae mariculture account for 0.68 Tg C yr^(-1) and the associated POC depositional and DOC releasing fluxes are 0.14 and 0.82 Tg C yr^(-1), respectively. Thus, in total, the annual output of organic carbon, which is mainly DOC, in the China Seas is 81.72–104.56 Tg C yr^(-1). The DOC efflux from the East China Sea to the adjacent oceans is 15.00–35.00 Tg C yr^(-1). The DOC efflux from the South China Sea is 31.39 Tg C yr^(-1). Although the marginal China Seas seem to be a source of atmospheric CO_2 based on the CO_2 flux at the sea-air interface, the combined effects of the riverine input in the area, oceanic input, depositional export,and microbial carbon pump(DOC conversion and output) indicate that the China Seas represent an important carbon storage area.
基金the National Natural Science Foundation of China (Grant No. 40075018).
文摘Using the 1961–1995 monthly averaged meteorological data from 148 surface stations in the Qinghai-Xizang Plateau (QXP) and its surrounding areas, calculation of the 35-year atmospheric heat source/sink (<Qi>) and an analysis on its climatic features and relation to rainfall in China have been made. It is found that on the average, the atmospheric heat source over the QXP is the strongest in June (78 W / m2) and cold source is the strongest in December (?72 W/m2). The sensible heat of the surface increases remarkably over the southwest of the QXP, causing the obvious increase of <Qi> there in February and March, which makes a center of the atmospheric heat source appear over the north slope of the Himalayas. Afterwards, this center continues to intensify and experiences noticeable migration westwards twice, separately occurring in April and June. The time when the atmosphere over the east of the QXP becomes heat source and reaches strongest is one month later than that over the southwest of the QXP. In summer, the latent heat of condensation becomes a heating factor as important as the sensible heat and is also a main factor that makes the atmospheric heat source over the east of the QXP continue growing. On the interdecadal time scale, (Q1) of the QXP shows an abrupt change in 1977 and a remarkable increase after 1977. The atmospheric heat source of the spring over the QXP is a good indicator for the subsequent summer rainfall over the valleys of the Changjiang and Huaihe rivers and South China and North China. There is remarkable positive correlation between the QXP heat source of summer and the summer rainfall in the valleys of the Changjiang River.