以钾长石、石英、方解石、高岭土等为主要原料,采用传统方法制备了耐碱中温日用瓷透明生料釉,探讨了烧成温度与保温时间对釉面效果及热稳定性的影响。采用正交试验法对配方进行了优化,得出了性能良好的最优配方。对样品进行了光泽度、...以钾长石、石英、方解石、高岭土等为主要原料,采用传统方法制备了耐碱中温日用瓷透明生料釉,探讨了烧成温度与保温时间对釉面效果及热稳定性的影响。采用正交试验法对配方进行了优化,得出了性能良好的最优配方。对样品进行了光泽度、热稳定性、热膨胀系数、耐碱性、XRD等测试分析。结果表明:最优配方样品的光泽度为116,热膨胀系数α为7.2×10^(-6)/℃(室温~600℃),抗热震性为170~20℃热交换一次不开裂,耐碱性达到欧盟BS EN 12875-2:2006标准中评价分级的0级;样品的物相组成为玻璃相,没有明显的晶相存在。展开更多
The Marajó Island is the largest island of the Marajō archipelago, located in the north of Brazil. In this region, at the end of 19th century, it was identified an archaeological society named Marajora, which oc...The Marajó Island is the largest island of the Marajō archipelago, located in the north of Brazil. In this region, at the end of 19th century, it was identified an archaeological society named Marajora, which occupied the island from 400 to 1,350 AD. It was characterized by a ceramic style recognized by its beauty and exuberance. Until this moment, the physical and chemical analysis studies in this ceramics are scarce and this kind of studies may help archaeological studies performed in the island. With this purpose, this work presents a preliminary study of the firing temperature in the ceramics. For that, the elementary concentrations of 109 samples from Museu de Archaeology and Ethnology Museum of the University of Sáo Paulo and samples collected in the Marajá Island were studied. The samples were analyzed using instrumental neutron activation analysis in which the elemental concentration of Ce, Co, Cr, Cs, Eu, Fe, Hf, K, La, Lu, Na, Nd, Rb, Sc, Sm, Ta, Tb, Th, U, Yb and Zn were determined. The interpretation of the results was made using multivariate statistical approaches and showed the existence of three chemical groups. Some samples of each cluster were chosen for the determination of their firing temperatures by electron paramagnetic resonance, in order to verify if different firing temperatures was associated with different elemental groups of ceramic samples. The results showed that there are no statistical differences in the firing temperature between the samples from Archaeology and Ethnology Museum and the contemporary samples of the Marajá Island.展开更多
文摘以钾长石、石英、方解石、高岭土等为主要原料,采用传统方法制备了耐碱中温日用瓷透明生料釉,探讨了烧成温度与保温时间对釉面效果及热稳定性的影响。采用正交试验法对配方进行了优化,得出了性能良好的最优配方。对样品进行了光泽度、热稳定性、热膨胀系数、耐碱性、XRD等测试分析。结果表明:最优配方样品的光泽度为116,热膨胀系数α为7.2×10^(-6)/℃(室温~600℃),抗热震性为170~20℃热交换一次不开裂,耐碱性达到欧盟BS EN 12875-2:2006标准中评价分级的0级;样品的物相组成为玻璃相,没有明显的晶相存在。
文摘The Marajó Island is the largest island of the Marajō archipelago, located in the north of Brazil. In this region, at the end of 19th century, it was identified an archaeological society named Marajora, which occupied the island from 400 to 1,350 AD. It was characterized by a ceramic style recognized by its beauty and exuberance. Until this moment, the physical and chemical analysis studies in this ceramics are scarce and this kind of studies may help archaeological studies performed in the island. With this purpose, this work presents a preliminary study of the firing temperature in the ceramics. For that, the elementary concentrations of 109 samples from Museu de Archaeology and Ethnology Museum of the University of Sáo Paulo and samples collected in the Marajá Island were studied. The samples were analyzed using instrumental neutron activation analysis in which the elemental concentration of Ce, Co, Cr, Cs, Eu, Fe, Hf, K, La, Lu, Na, Nd, Rb, Sc, Sm, Ta, Tb, Th, U, Yb and Zn were determined. The interpretation of the results was made using multivariate statistical approaches and showed the existence of three chemical groups. Some samples of each cluster were chosen for the determination of their firing temperatures by electron paramagnetic resonance, in order to verify if different firing temperatures was associated with different elemental groups of ceramic samples. The results showed that there are no statistical differences in the firing temperature between the samples from Archaeology and Ethnology Museum and the contemporary samples of the Marajá Island.
