期刊文献+
共找到5篇文章
< 1 >
每页显示 20 50 100
基于迁移学习与TrAdaBoost-SVM方法的XRF中药重金属超标研究
1
作者 马骞 杨婉琪 +2 位作者 李福生 程惠珠 赵彦春 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2023年第9期2729-2733,共5页
中药材重金属超标问题日趋严重,将阻碍中药产业的未来高质量发展,因此研究高效、准确、便捷的超标鉴定方法对于了解中药的安全性具有重要意义。X射线荧光(XRF)光谱分析具有无损检测、快速准确、样品制备方便等优势,在元素分析领域获得... 中药材重金属超标问题日趋严重,将阻碍中药产业的未来高质量发展,因此研究高效、准确、便捷的超标鉴定方法对于了解中药的安全性具有重要意义。X射线荧光(XRF)光谱分析具有无损检测、快速准确、样品制备方便等优势,在元素分析领域获得广泛应用。由于中药材重金属超标阈值低(如中国药典2020年版规定铅超标为5 mg·kg-1),中药的种类繁多,基体复杂,国家标准样本匮乏,常规的分类算法难以准确鉴定超标问题。将迁移学习与多分类支持向量机(TrAdaBoost-SVM)方法结合,以金银花为例,采用与金银花相似的国家土壤标准样品的光谱特征信息用于数据增强,将土壤标准样品和少量中药样本混合建立迁移学习和支持向量机分类模型。通过实验验证,迁移学习和TrAdaBoost-SVM结合的分类优化方法,与传统SVM、AdaBoost分类算法相比,鉴定重金属元素铅(Pb)的超标准确率有显著提高。通过测试数据集的预测验证,TrAdaBoost-SVM模型的预测准确率为96.7%,高于传统SVM及AdaBoost分类模型的准确率。所提出的迁移学习与TrAdaBoost-SVM结合的方法,可在小样本条件下建立分类模型,并对中药的重金属超标准确预测,具有一定的理论意义和应用价值。 展开更多
关键词 X荧光光谱分析技术 迁移学习 支持向量机 中药重金属超标分类
下载PDF
超临界CO_2配合萃取技术去除中药中重金属研究进展 被引量:6
2
作者 张楠楠 季巧遇 +1 位作者 杨凌宇 李琼 《亚太传统医药》 2011年第1期147-149,共3页
重金属是中药的重要污染物之一,超临界CO2配合萃取技术已作为一种新型技术广泛应用于去除中药中重金属的研究。对超临界CO2配合萃取重金属离子的原理、方法、影响因素及其应用进行综述,着重介绍该方法在去除中药中重金属方面的应用,并... 重金属是中药的重要污染物之一,超临界CO2配合萃取技术已作为一种新型技术广泛应用于去除中药中重金属的研究。对超临界CO2配合萃取重金属离子的原理、方法、影响因素及其应用进行综述,着重介绍该方法在去除中药中重金属方面的应用,并对其发展方向进行展望。 展开更多
关键词 中药重金属 超临界CO2 萃取技术 原理 影响因素
下载PDF
Investigation of Heavy Metal Contents in Traditional Chinese Herbal Medicine Peristrophe roxburghiana Collected from Northwest of Guangxi 被引量:2
3
作者 刘旭辉 李容 +2 位作者 郭俊 罗志勇 覃勇荣 《Agricultural Science & Technology》 CAS 2016年第12期2751-2756,2762,共7页
Objective] This study was conducted to evaluate the product quality and safety of Peristrophe roxburghiana_ col ected from different places in Hechi City, northwest of Gunagxi, so as to provide basic data for further ... Objective] This study was conducted to evaluate the product quality and safety of Peristrophe roxburghiana_ col ected from different places in Hechi City, northwest of Gunagxi, so as to provide basic data for further development and uti-lization of the characteristic plant resource P. roxburghiana. [Method] Contents of 9 kinds of heavy metals including Cd, Mn, Pb, Zn and Cu in the herb were deter-mined by the method of wet digestion-flame atomic absorption spectrophotometry and atomic fluorescence spectrometry, respectively. [Results] Heavy metal contents of Cd, Mn, Pb, Fe, Cu, Zn, As, Hg and Se were 1.62-17.25, 8.93-142.53, 4.37-18.43, 103.7-242.81, 2.55-5.35, 85.40-146.30, 0.07-0.54, 0.00-0.08 and 0.00-0.47 mg/kg, respectively. According to the national food safety standards and Green Trade Standards of lmporting &amp; Exporting Medicinal plants &amp; Preparations, the heavy metal contents of the P. roxburghiana_samples col ected from different coun-ties in Hechi City exceeded standards or at the critical values. Among which, Cd, Pb and Zn contents of the samples are seriously higher than the standards. [Con-clusion] Therefore, the impact of soil heavy metal pol ution on the safety of edible plants in the northwest of Guangxi should be highly concerned. 展开更多
关键词 Northwest of Guangxi Traditional Chinese herbal medicine Peristro-pheroxburghiana Product quality and safety Heavy metal content
下载PDF
化学原子化-原子吸收光谱法测定金银花中镉含量的方法研究 被引量:9
4
作者 刘利敏 罗亚虹 +1 位作者 李琦 龚治湘 《药物分析杂志》 CAS CSCD 北大核心 2013年第2期278-280,共3页
目的:采用化学原子化-原子吸收光谱法,建立金银花中重金属镉的测定方法。方法:采用PE-AA400原子吸收分光光度计,MCA-201微型化学原子化器,波长228.8 nm,狭缝2.7 mm/1.35 mm,灯电流4 mA,氩气流量为1.2 L.min-1。结果:镉浓度在0.1~8.0μg... 目的:采用化学原子化-原子吸收光谱法,建立金银花中重金属镉的测定方法。方法:采用PE-AA400原子吸收分光光度计,MCA-201微型化学原子化器,波长228.8 nm,狭缝2.7 mm/1.35 mm,灯电流4 mA,氩气流量为1.2 L.min-1。结果:镉浓度在0.1~8.0μg.L-1范围内,具有良好的线性关系,校准方程为A=0.1356C+0.0117(r=0.9998);方法回收率(n=9)为95.5%。结论:化学原子化-原子吸收光谱法测定金银花中痕量镉,灵敏度高,无背景影响,操作简单快速,成本低廉。 展开更多
关键词 化学原子化-原子吸收光谱法 原子吸收光谱仪 化学原子化器 石墨炉法 金银花 中药重金属及有害元素 安全监测
原文传递
Microbial and heavy metal contamination in commonly consumed traditional Chinese herbal medicines 被引量:12
5
作者 Adelinesuyien Ting Yiingyng Chow Weishang Tan 《Journal of Traditional Chinese Medicine》 SCIE CAS CSCD 2013年第1期119-124,共6页
OBJECTIVE: The increasing popularity and widespread use of traditional Chinese herbs as alterna- tive medicine have sparked an interest in understanding their biosafety, especially in decoctions that are consumed. Th... OBJECTIVE: The increasing popularity and widespread use of traditional Chinese herbs as alterna- tive medicine have sparked an interest in understanding their biosafety, especially in decoctions that are consumed. This study aimed to assess the level of microbial and heavy metal contamination in commonly consumed herbal medicine in Malay- sia and the effects of boiling on these contamination levels. METHODS: Four commonly consumed Chinese herbal medicine in Malaysia-"Eight Treasure Herbal Tea", "Herbal Tea", Xiyangshen (Radix Panacis Quin- quefolii) and Dangshen (Radix Codonopsis) were evaluated in this study. Herbal medicines were pre- pared as boiled and non-boiled decoctions, and their microbial enumeration and heavy metal detection were conducted with plate assay and atom- ic absorption spectroscopy, respectively. RESULTS: Findings revealed that herbal medicines generally had 6 Iogl0cfu/mL microbial cells and that boiling had significantly reduced microbial contaminants, where no Bacillus spp., Staphylococcus spp. and Clostridium spp. were recovered. Heavy metals such as Mn, Cu, Cd, Pb, Fe and Zn were also detect- ed from all the samples, generally in low concentra- tions (〈1 mg/L) except for Mn (18.545 mg/L). All de- coctions (after boiling) have reduced concentra- tions of Cu, while others were not significantly dif- ferent. Comparisons between samples with single and multi-herbs suggest level of microbial and metal contamination is not influenced by number of herbs in sample. CONCLUSION: Herbal medicines generally have microbial and heavy metal contaminants. However, the boiling process to generate decoctions was able to successfully reduce the number of microbes and Cu, ensuring safety of herbal medicines for consumption. 展开更多
关键词 Decoction processing Drug contamination Heavy metal poisoning nervous system Microbial consortia Drugs Chinese herbal
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部