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一氧化碳氢化中间物模型的过渡金属-烯酮(亚烯酮基)络合物
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作者 高景星 区泽棠 《天然气化工—C1化学与化工》 CAS CSCD 北大核心 1990年第5期46-53,共8页
有机烯酮的化学已有80年的历史,但过渡金属-烯酮和金属-亚烯酮基络合物的研究才进行几年。由于这类络合物的化学与一碳化学的研究密切相关而引人注目,且迅速发展成为有机金属化学的一个重要分支。本文就过渡金属-烯酮和金属-亚烯酮基络... 有机烯酮的化学已有80年的历史,但过渡金属-烯酮和金属-亚烯酮基络合物的研究才进行几年。由于这类络合物的化学与一碳化学的研究密切相关而引人注目,且迅速发展成为有机金属化学的一个重要分支。本文就过渡金属-烯酮和金属-亚烯酮基络合物的合成、结构、反应性能和作为一氧化碳氢化中间物模型的研究,包括作者过去的研究结果,作简要介绍。 展开更多
关键词 一氧化碳 氢化还原反应 中间物模型
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Effects of coal prices on merchandise prices in China 被引量:4
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作者 Ding Zhihua Zhou Meihua Liu Yan 《Mining Science and Technology》 EI CAS 2011年第5期651-654,共4页
Coal is the principal form of energy used in China. Hence, coal price variations are expected to have some influence on merchandise prices. Monthly data from January, 2002, to October, 2010, were used to construct a v... Coal is the principal form of energy used in China. Hence, coal price variations are expected to have some influence on merchandise prices. Monthly data from January, 2002, to October, 2010, were used to construct a varying-parameter state space model, and an error correction model, to estimate the influence of coat prices on Chinese merchandise prices. The time lag and the dynamic relationship were determined from the data. A long term equilibrium relationship between coal price and the PPI, and the CPI, can be observed. The long term influence of coal price fluctuations on the PPI is 0.263%. The corresponding value for the CPI is 0.157%. The PPI shows an influence from coal price change in the first period of observation: by eight periods the influence is obvious, after which it diminishes. The effect of coal price change on the CPI is rather weak and has no long term memory. Analysis of variance shows a similar situation. The elas- ticity coefficient of coal prices on the CPI, or the PPI, fluctuates over the 2002-2004 period. From 2002 to 2007 the influence elasticity on the CPI declined and subsequently levelled off after 2009. 展开更多
关键词 Coal priceState space modelMerchandise pricePrice fluctuation
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Spatial modeling of the Ulmus pumila growing season in China's temperate zone 被引量:4
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作者 Xu Lin Chen XiaoQiu 《Science China Earth Sciences》 SCIE EI CAS 2012年第4期656-664,共9页
To reveal the ecological mechanism of spatial patterns of plant phenology and spatial sensitivity of plant phenology responses to climate change,we used Ulmus pumila leaf unfolding and leaf fall data at 46 stations of... To reveal the ecological mechanism of spatial patterns of plant phenology and spatial sensitivity of plant phenology responses to climate change,we used Ulmus pumila leaf unfolding and leaf fall data at 46 stations of China's temperate zone during the period 1986-2005 to simulate 20-year mean and yearly spatial patterns of the beginning and end dates of the Ulmus pumila growing season by establishing air temperature-based spatial phenology models,and validate these models by extensive spatial extrapolation.Results show that the spatial patterns of 20-year mean and yearly February-April or September-November temperatures control the spatial patterns of 20-year mean and yearly beginning or end dates of the growing season.Spatial series of mean beginning dates shows a significantly negative correlation with spatial series of mean February-April temperatures at the 46 stations.The mean spring spatial phenology model explained 90% of beginning date variance(p<0.001) with a Root Mean Square Error(RMSE) of 4.7 days.In contrast,spatial series of mean end dates displays a significantly positive correlation with spatial series of mean September-November temperatures at the 46 stations.The mean autumn spatial phenology model explained 79% of end date variance(p<0.001) with a RMSE of 6 days.Similarly,spatial series of yearly beginning dates correlates negatively with spatial series of yearly February-April temperatures and the explained variances of yearly spring spatial phenology models to beginning date are between 72%-87%(p<0.001),whereas spatial series of yearly end dates correlates positively with spatial series of yearly September-November temperatures and the explained variances of yearly autumn spatial phenology models to end date are between 48%-76%(p<0.001).The overall RMSEs of yearly models in simulating beginning and end dates at all modeling stations are 7.3 days and 9 days,respectively.The spatial prediction accuracies of growing season's beginning and end dates based on both 20-year mean and yearly models are close to the spatial simulation accuracies of these models,indicating that the models have a strong spatial extrapolation capability.Further analysis displays that the negative spatial response rate of growing season's beginning date to air temperature was larger in warmer years with higher regional mean February-April temperatures than in colder years with lower regional mean February-April temperatures.This finding implies that climate warming in winter and spring may enhance sensitivity of the spatial response of growing season's beginning date to air temperature. 展开更多
关键词 PHENOLOGY Ulmus pumila air temperature spatial response spatial simulation sensitivity
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