Static corrections using the conventional method are basically conducted in two steps, the weathering correction followed by the correction from the top of the sub-weathering to the unified datum. However, the convent...Static corrections using the conventional method are basically conducted in two steps, the weathering correction followed by the correction from the top of the sub-weathering to the unified datum. However, the conventional method fails to well deal with statics problems in case the top of the sub-weathering is sharply undulated and the lateral velocity of the sub-weathering varies significantly. This brings us to the introduction of a smooth intermediate reference datum （IRD） located under the top of the sub-weathering, which helps to further increase the accuracy of statics based on the weathering corrections, and ensures the imaging quality. Good results based on the IRD technique have been achieved in the complex areas in western China. This paper discusses the IRD functions, its application requirements, and selection of related parameters. Some typical sections for comparison are also given in this paper.展开更多
Using the U.S. National Centers for Environmental Prediction/National Center for Atmospheric Research reanalysis data at 1°× 1° o resolution, analysis is performed on a persistent heavy rainfall event w...Using the U.S. National Centers for Environmental Prediction/National Center for Atmospheric Research reanalysis data at 1°× 1° o resolution, analysis is performed on a persistent heavy rainfall event with two rain bands to the south of the Yangtze River during 17-22 June 2005. The northern rain band was related to the atmospheric mass adjustment of cold front precipitation and the associated ageostrophic feature to the rear right of subtropical westerly jets, while the southern counterpart formed under the joint influence of easterly/westerly jets and the South Asian high （SAH）. The ageostrophic wind field to the rear right of the easterly jet center gives rise to an anti-circulation that favors the genesis of the southern belt. The feature ofdu/dt 〈0 around the SAH ridge line and to the rear right of the easterly jet streak results in a strong v - vg〈O field in the vicinity of the rain region as well as to its south. When westerly jets move southward, an intense v Vg〉0 feature appears to the north of the rain region, i.e., behind the center of the westerly jets. The associated mass adjustment leads to vigorous divergence over the rain region, which is responsible for the strong precipitation from the warm sector of the front. Also, a θe front at the middle level of the southern rain band and the cold front favor the release of instable energy to enhance the rainstorm. The southern and northern fronts approach each other and the two rain belts merge into one.展开更多
Regulating charge transfer to achieve specific transfer path can improve electron utilization and complete efficient photoreduction of CO_(2).Here,we fabricated a S-scheme heterojunction of CN/Fe-MOF by an in-situ ass...Regulating charge transfer to achieve specific transfer path can improve electron utilization and complete efficient photoreduction of CO_(2).Here,we fabricated a S-scheme heterojunction of CN/Fe-MOF by an in-situ assembly strategy.The S-scheme charge transfer mechanism was confirmed by band structure,electron spin resonance(ESR)and work function(Φ)analysis.On the one hand,the response of Fe-MOF in the visible region improved the utilization of light energy,thus increasing the ability of CN/Fe-MOF to generate charge carriers.On the other hand,CN,as the active site,not only had strong adsorption capacity for CO_(2),but also retained photogenerated electrons with high reduction capacity because of S-scheme charge transfer mechanism.Hence,in the absence of any sacrificial agent and cocatalyst,the optimized 50CN/Fe-MOF obtained the highest CO yield(19.17μmol g^(–1))under UV-Vis irradiation,which was almost 10 times higher than that of CN.In situ Fourier transform infrared spectra not only revealed that the photoreduction of CO_(2) occurred at the CN,but also demonstrated that the S-scheme charge transfer mechanism enabled 50CN/Fe-MOF to have a stronger ability to generate HCOO–than CN.展开更多
Electrochemical CO2 reduction is a promising strategy for the utilization of CO2 and intermittent excess electricity.Cu is the only single metal catalyst that can electrochemically convert CO2 into multicarbon product...Electrochemical CO2 reduction is a promising strategy for the utilization of CO2 and intermittent excess electricity.Cu is the only single metal catalyst that can electrochemically convert CO2 into multicarbon products.However,Cu exhibits an unfavorable activity and selectivity for the generation of C2 products because of the insufficient amount of CO*provided for the C‐C coupling.Based on the strong CO2 adsorption and ultrafast reaction kinetics of CO*formation on Pd,an intimate CuPd(100)interface was designed to lower the intermediate reaction barriers and improve the efficiency of C2 product formation.Density functional theory(DFT)calculations showed that the CuPd(100)interface enhanced the CO2 adsorption and decreased the CO2*hydrogenation energy barrier,which was beneficial for the C‐C coupling.The potential‐determining step(PDS)barrier of CO2 to C2 products on the CuPd(100)interface was 0.61 eV,which was lower than that on Cu(100)(0.72 eV).Encouraged by the DFT calculation results,the CuPd(100)interface catalyst was prepared by a facile chemical solution method and characterized by transmission electron microscopy.CO2 temperature‐programmed desorption and gas sensor experiments further confirmed the enhancement of the CO2 adsorption and CO2*hydrogenation ability of the CuPd(100)interface catalyst.Specifically,the obtained CuPd(100)interface catalyst exhibited a C2 Faradaic efficiency of 50.3%±1.2%at‒1.4 VRHE in 0.1 M KHCO3,which was 2.1 times higher than that of the Cu catalyst(23.6%±1.5%).This study provides the basis for the rational design of Cu‐based electrocatalysts for the generation of multicarbon products by fine‐tuning the intermediate reaction barriers.展开更多
The accumulative roll-bonding(ARB)process was applied on the strips of aluminum alloy 1050 in two processing conditions:cold ARB and warm ARB.The results of tensile tests and microhardness measurement show that the wa...The accumulative roll-bonding(ARB)process was applied on the strips of aluminum alloy 1050 in two processing conditions:cold ARB and warm ARB.The results of tensile tests and microhardness measurement show that the warm ARB process exhibits the lower tensile strength and microhardness,more homogeneous distribution of the microhardness,higher elongation,and especially superior planar isotropy of the tensile properties in comparison to the cold ARB,because of the intermediate heat treatment as well as the elevated temperature rolling in the warm ARB process.Furthermore,with increasing the cycles of both processes,the planar isotropy decreases progressively.展开更多
A great number of sensor technologies are applied in the Intemet of Things （loT） currently and more are emerging, which rmkes the loT a heterogeneous network. This paper discusses the convergence and integration pro...A great number of sensor technologies are applied in the Intemet of Things （loT） currently and more are emerging, which rmkes the loT a heterogeneous network. This paper discusses the convergence and integration problem in IoT. A Service-Oriented Middleware for Heterogeneous Environment （SOMHE） in IoT is proposed. The purpose of the middleware is to shield the differ- ence between protocols in the sensor layers such as Radio Frequency Identification （RFID） and Zig-Bee by defining the data conversion and mapping model. A Web service interface is supplied by this middleware, thus the complexity of high level appli-cation development can be reduced greatly. The feasibility and reliability of this middleware is veri-fied by a demonstration systelTL展开更多
Multiple surface cracks and interfacial delamination are the major failure mechanisms in film/substrate systems.The effect of interlayer upon the failure mechanisms of interfacial delamination concomitant to surface c...Multiple surface cracks and interfacial delamination are the major failure mechanisms in film/substrate systems.The effect of interlayer upon the failure mechanisms of interfacial delamination concomitant to surface crack was explored.Finite element model was developed to obtain the stress and energy release rate(ERR),which governs the propagation of interface cracks.The dependences of delamination upon the geometry and constitutive properties of interlayer were examined.The results indicate that the effect of elastic modulus of interlayer on the steady state ERR is insignificant.In cases of different geometrical parameters,however,the steady ERR decreases with the increase of the interlayer thickness.These findings lead to the conclusion that the interlayer constraint has significant effect on the ERR and thus coating life,which can be adopted to modify the ceramic top coat.展开更多
A nano-Li3V2（PO4）3/C powder was successfully prepared by a thermal polymerization method. The particle sizes of the intermediate product powder and the final product Li3V2（PO4）3 are all less than 200 nm. The carbo...A nano-Li3V2（PO4）3/C powder was successfully prepared by a thermal polymerization method. The particle sizes of the intermediate product powder and the final product Li3V2（PO4）3 are all less than 200 nm. The carbon is partially coated on the surface of Li3V2（PO4）3 particles and the rest exists between particles with a total carbon content of 4.6wt%. This nano-Li3V2（PO4）3/C sample shows a discharge capacity of 124 mAh/g with-out capacity fading after 100 cycles at 0.1 C in the voltage rang of 3.0-4.3 V. Excellent rate performance is also achieved with a capacity of 80 mAh/g at 20 C in 3.0-4.3 V and 100 mAh/g at 10 C in 3.0-4.8 V. This study suggests that the thermal polymerization method is suitable to synthesize nano-Li3V2（PO4）3/C materials.展开更多
Long chain alkyl diols have shown important potential for the reconstruction of sea surface temperature,productivities and upwelling conditions in marine or lacustrine environments.However,little is known about the di...Long chain alkyl diols have shown important potential for the reconstruction of sea surface temperature,productivities and upwelling conditions in marine or lacustrine environments.However,little is known about the distribution and sources of the diols in eastern China marginal seas(CMS),which are areas of important organic carbon sink.Here the contents of C_(30) and C_(32)1,15-diols were analyzed in 181 surface sediments from eastern CMS.The similar distribution pattern and strong linear correlation between C_(30) and C_(32) diols indicated that they had similar biological source,with a dominance of C_(30) diol.Their contents ranged from 7-2726 ng g^(-1) for C_(30) diol and 5-669 ng g^(-1) for C_(32) diol,and both showed higher values mainly in the mud area of the Yellow Sea,while the TOC normalized contents showed a more obvious seaward increasing trend.The similar distribution pattern and significant positive correlation between diols and the other marine biomarkers(brassicasterol,dinosterol,C_(37) alkenones) indicated C_(30) and C_(32) diols in eastern CMS were mainly from marine algae.This conclusion was also supported by principal component analysis(PCA).Our results also showed that sediment diol contents were generally related to marine productivity,suggesting that diols could be applied for marine productivity reconstruction in eastern CMS.展开更多
文摘Static corrections using the conventional method are basically conducted in two steps, the weathering correction followed by the correction from the top of the sub-weathering to the unified datum. However, the conventional method fails to well deal with statics problems in case the top of the sub-weathering is sharply undulated and the lateral velocity of the sub-weathering varies significantly. This brings us to the introduction of a smooth intermediate reference datum （IRD） located under the top of the sub-weathering, which helps to further increase the accuracy of statics based on the weathering corrections, and ensures the imaging quality. Good results based on the IRD technique have been achieved in the complex areas in western China. This paper discusses the IRD functions, its application requirements, and selection of related parameters. Some typical sections for comparison are also given in this paper.
基金National Program on Basic Research Project (973 Program) (2009CB421503)Natural Science Foundation of China (40975037)Natural Science Foundation of China (40775033)
文摘Using the U.S. National Centers for Environmental Prediction/National Center for Atmospheric Research reanalysis data at 1°× 1° o resolution, analysis is performed on a persistent heavy rainfall event with two rain bands to the south of the Yangtze River during 17-22 June 2005. The northern rain band was related to the atmospheric mass adjustment of cold front precipitation and the associated ageostrophic feature to the rear right of subtropical westerly jets, while the southern counterpart formed under the joint influence of easterly/westerly jets and the South Asian high （SAH）. The ageostrophic wind field to the rear right of the easterly jet center gives rise to an anti-circulation that favors the genesis of the southern belt. The feature ofdu/dt 〈0 around the SAH ridge line and to the rear right of the easterly jet streak results in a strong v - vg〈O field in the vicinity of the rain region as well as to its south. When westerly jets move southward, an intense v Vg〉0 feature appears to the north of the rain region, i.e., behind the center of the westerly jets. The associated mass adjustment leads to vigorous divergence over the rain region, which is responsible for the strong precipitation from the warm sector of the front. Also, a θe front at the middle level of the southern rain band and the cold front favor the release of instable energy to enhance the rainstorm. The southern and northern fronts approach each other and the two rain belts merge into one.
文摘Regulating charge transfer to achieve specific transfer path can improve electron utilization and complete efficient photoreduction of CO_(2).Here,we fabricated a S-scheme heterojunction of CN/Fe-MOF by an in-situ assembly strategy.The S-scheme charge transfer mechanism was confirmed by band structure,electron spin resonance(ESR)and work function(Φ)analysis.On the one hand,the response of Fe-MOF in the visible region improved the utilization of light energy,thus increasing the ability of CN/Fe-MOF to generate charge carriers.On the other hand,CN,as the active site,not only had strong adsorption capacity for CO_(2),but also retained photogenerated electrons with high reduction capacity because of S-scheme charge transfer mechanism.Hence,in the absence of any sacrificial agent and cocatalyst,the optimized 50CN/Fe-MOF obtained the highest CO yield(19.17μmol g^(–1))under UV-Vis irradiation,which was almost 10 times higher than that of CN.In situ Fourier transform infrared spectra not only revealed that the photoreduction of CO_(2) occurred at the CN,but also demonstrated that the S-scheme charge transfer mechanism enabled 50CN/Fe-MOF to have a stronger ability to generate HCOO–than CN.
文摘Electrochemical CO2 reduction is a promising strategy for the utilization of CO2 and intermittent excess electricity.Cu is the only single metal catalyst that can electrochemically convert CO2 into multicarbon products.However,Cu exhibits an unfavorable activity and selectivity for the generation of C2 products because of the insufficient amount of CO*provided for the C‐C coupling.Based on the strong CO2 adsorption and ultrafast reaction kinetics of CO*formation on Pd,an intimate CuPd(100)interface was designed to lower the intermediate reaction barriers and improve the efficiency of C2 product formation.Density functional theory(DFT)calculations showed that the CuPd(100)interface enhanced the CO2 adsorption and decreased the CO2*hydrogenation energy barrier,which was beneficial for the C‐C coupling.The potential‐determining step(PDS)barrier of CO2 to C2 products on the CuPd(100)interface was 0.61 eV,which was lower than that on Cu(100)(0.72 eV).Encouraged by the DFT calculation results,the CuPd(100)interface catalyst was prepared by a facile chemical solution method and characterized by transmission electron microscopy.CO2 temperature‐programmed desorption and gas sensor experiments further confirmed the enhancement of the CO2 adsorption and CO2*hydrogenation ability of the CuPd(100)interface catalyst.Specifically,the obtained CuPd(100)interface catalyst exhibited a C2 Faradaic efficiency of 50.3%±1.2%at‒1.4 VRHE in 0.1 M KHCO3,which was 2.1 times higher than that of the Cu catalyst(23.6%±1.5%).This study provides the basis for the rational design of Cu‐based electrocatalysts for the generation of multicarbon products by fine‐tuning the intermediate reaction barriers.
文摘The accumulative roll-bonding(ARB)process was applied on the strips of aluminum alloy 1050 in two processing conditions:cold ARB and warm ARB.The results of tensile tests and microhardness measurement show that the warm ARB process exhibits the lower tensile strength and microhardness,more homogeneous distribution of the microhardness,higher elongation,and especially superior planar isotropy of the tensile properties in comparison to the cold ARB,because of the intermediate heat treatment as well as the elevated temperature rolling in the warm ARB process.Furthermore,with increasing the cycles of both processes,the planar isotropy decreases progressively.
基金This paper was supported by the National Natural Science Foundation of China under Crant No. NSFC-61170176 the Na-tional Great Science Specific Project under Grants No. 2010ZX03005-001-03, No2011ZX03005-004-02 the Beijing Munici-pal Con-rnission of Education Build Together Project and Minis-try of Education Infrastructure Construction Project （2-5-2）.
文摘A great number of sensor technologies are applied in the Intemet of Things （loT） currently and more are emerging, which rmkes the loT a heterogeneous network. This paper discusses the convergence and integration problem in IoT. A Service-Oriented Middleware for Heterogeneous Environment （SOMHE） in IoT is proposed. The purpose of the middleware is to shield the differ- ence between protocols in the sensor layers such as Radio Frequency Identification （RFID） and Zig-Bee by defining the data conversion and mapping model. A Web service interface is supplied by this middleware, thus the complexity of high level appli-cation development can be reduced greatly. The feasibility and reliability of this middleware is veri-fied by a demonstration systelTL
基金Project(2013CB035700) supported by the National Basic Research Program of ChinaProjects(11272259,11321062,11002104) supported by the National Natural Science Foundation of China
文摘Multiple surface cracks and interfacial delamination are the major failure mechanisms in film/substrate systems.The effect of interlayer upon the failure mechanisms of interfacial delamination concomitant to surface crack was explored.Finite element model was developed to obtain the stress and energy release rate(ERR),which governs the propagation of interface cracks.The dependences of delamination upon the geometry and constitutive properties of interlayer were examined.The results indicate that the effect of elastic modulus of interlayer on the steady state ERR is insignificant.In cases of different geometrical parameters,however,the steady ERR decreases with the increase of the interlayer thickness.These findings lead to the conclusion that the interlayer constraint has significant effect on the ERR and thus coating life,which can be adopted to modify the ceramic top coat.
文摘A nano-Li3V2（PO4）3/C powder was successfully prepared by a thermal polymerization method. The particle sizes of the intermediate product powder and the final product Li3V2（PO4）3 are all less than 200 nm. The carbon is partially coated on the surface of Li3V2（PO4）3 particles and the rest exists between particles with a total carbon content of 4.6wt%. This nano-Li3V2（PO4）3/C sample shows a discharge capacity of 124 mAh/g with-out capacity fading after 100 cycles at 0.1 C in the voltage rang of 3.0-4.3 V. Excellent rate performance is also achieved with a capacity of 80 mAh/g at 20 C in 3.0-4.3 V and 100 mAh/g at 10 C in 3.0-4.8 V. This study suggests that the thermal polymerization method is suitable to synthesize nano-Li3V2（PO4）3/C materials.
基金supported by the National Natural Science Foundation of China(Nos.41521064 and 41630966)
文摘Long chain alkyl diols have shown important potential for the reconstruction of sea surface temperature,productivities and upwelling conditions in marine or lacustrine environments.However,little is known about the distribution and sources of the diols in eastern China marginal seas(CMS),which are areas of important organic carbon sink.Here the contents of C_(30) and C_(32)1,15-diols were analyzed in 181 surface sediments from eastern CMS.The similar distribution pattern and strong linear correlation between C_(30) and C_(32) diols indicated that they had similar biological source,with a dominance of C_(30) diol.Their contents ranged from 7-2726 ng g^(-1) for C_(30) diol and 5-669 ng g^(-1) for C_(32) diol,and both showed higher values mainly in the mud area of the Yellow Sea,while the TOC normalized contents showed a more obvious seaward increasing trend.The similar distribution pattern and significant positive correlation between diols and the other marine biomarkers(brassicasterol,dinosterol,C_(37) alkenones) indicated C_(30) and C_(32) diols in eastern CMS were mainly from marine algae.This conclusion was also supported by principal component analysis(PCA).Our results also showed that sediment diol contents were generally related to marine productivity,suggesting that diols could be applied for marine productivity reconstruction in eastern CMS.
