工业以太网不断地超越其他的网络。具有竞争性的局域网技术经过修改可适用于传送安全-临界的数据—PROFIsafe、INTERBUS Safety、CAN Open Safety等。然而,压力在于基于以太网的技术将取代它们。目前,标准的以太网协议不能够使用一个标...工业以太网不断地超越其他的网络。具有竞争性的局域网技术经过修改可适用于传送安全-临界的数据—PROFIsafe、INTERBUS Safety、CAN Open Safety等。然而,压力在于基于以太网的技术将取代它们。目前,标准的以太网协议不能够使用一个标准的层来传递安全数据。有一些所有权的解决方案支持公司专用的通信程序如HIMA或者TTTeh-Ethernet。有关的新来者如IDA提供(Interface for Dis-展开更多
Piperine is a member of the lipids family commonly found in peppercorn, ginger and other natural sources and is grouped as an alkaloid. The solubility of piperine has been determined in carbon dioxide at near critical...Piperine is a member of the lipids family commonly found in peppercorn, ginger and other natural sources and is grouped as an alkaloid. The solubility of piperine has been determined in carbon dioxide at near critical and supercritical conditions in a dynamic extraction apparatus. The conditions studied were at pressures ranging from 10 to 20 MPa and temperatures at 293, 300, 313, 323 and 333 K. The results showed that piperine solubility increased with increasing pressure at all temperatures studied. The solubility of plperme in near critical conditions was slightly higher than that at supercritical conditions only at the low-pressure range. Two semi-empirical density dependent correlations, namely the Chrastil model and the Dilute Solution model, were also used to estimate the solubility data. Although both models showed good correlation with the solubility data, the Dilute Solution model performed better prediction than the Chrastil model.展开更多
This paper proposes an estimation method of fracture resistance of oil ＆ gas pipes, based on the results of full scale hydraulic pressure pipe testing with the artificial notch, made by the authors at 2002-2006. It s...This paper proposes an estimation method of fracture resistance of oil ＆ gas pipes, based on the results of full scale hydraulic pressure pipe testing with the artificial notch, made by the authors at 2002-2006. It shows that the fracture process at the stage of stripping （initialization） of crack can be characterized by Critical Fracture Diagram （CFD）. Calculating and experimental way to construct CFD is suggested and discussed. The fracture resistance requirements for oil ＆ gas pipes in terms of fracture mechanics （Kc, Lc） are formulated and proved. The results of full scale hydraulic pressure pipe testing, based on metal testing data of the standard Charpy specimens （KCV） and pipe＇s specification requirements are interrelated. The way to estimate the admissible temperature operation conditions of oil ＆ gas pipes by means of based metal ＂KCV-temperature＂ dependence is proposed.展开更多
In this paper, adsorption and regeneration characteristics of multi-walled carbon nanotubes （MWNTs） used as adsorbent were investigated for the removal of 1,3-beuzenediol （BDO） from water by the supercritieal wat...In this paper, adsorption and regeneration characteristics of multi-walled carbon nanotubes （MWNTs） used as adsorbent were investigated for the removal of 1,3-beuzenediol （BDO） from water by the supercritieal water （SCW） technique. FFIR, XPS, SEM and dispersion stability tests were used to characterize the structure and surface morphology of CNTs. The results showed that CNTs surfaces were slightly activated and strongly etched in supercritieal water system. The adsorption capacity of SCW-treated CNTs was higher than that of raw CNTs. The adsorbed amounts for treated CNTs and raw CNTs samples at the same initial concentration of 60 mg/L were ca. 16.42 and 7.30 mg/g, respectively. The BDO adsorption of treated CNTs was due to the physical adsorption. The experimental data fit Freundlich isotherm model better than Langmuir one. The loaded adsorbent could be efficiently desorbed and regenerated by SCW technique. Therefore, SCW is a promising and environmentally friendly technique for the improvement of adsorption and regeneration of CNTs.展开更多
The critical curves for binary systems of methane combined with nitrogen, carbon monoxide, carbon dioxide, ethane, propane, butane and water at temperatures from 125 K to 650 K and pressures from 3.5 MPa to 250 MPa we...The critical curves for binary systems of methane combined with nitrogen, carbon monoxide, carbon dioxide, ethane, propane, butane and water at temperatures from 125 K to 650 K and pressures from 3.5 MPa to 250 MPa were calculated by using Heilig-Franck equation of state. This equation of state contains a repulsion term and an attraction term for intermolecular interaction. With pairwise combination rules for these potentials, three adjustable parameters are needed. The results showed that the critical curves of the former six binary systems belonged to type I, and CH4＋H2O system belonged to type III. The calculated data were compared with the experimental data,which yielded good results for the pressure-temperature, pressure-composition and temperature-composition behaviors of the seven systems. Moreover, the values of the adjustable parameters were obtained from the calculation of the critical curves. They can also be used for other relevant calculation.展开更多
Vapor-liquid phase equilibrium data including composition,densities,molar volume and equilibrium constant of isobutanol in supercritical carbon dioxide from 313.2K to 353.2K were measured in a variable-volume visual c...Vapor-liquid phase equilibrium data including composition,densities,molar volume and equilibrium constant of isobutanol in supercritical carbon dioxide from 313.2K to 353.2K were measured in a variable-volume visual cell.The properties of critical point were obtained by extrapolation.The results showed that critical temperature,critical pressure and critical compressibility factor of CO2-isobutanol system decreased with the increase of critical CO2 content.The phase equilibrium model was established by Peng-Robinson equation of state and van der Waals-2 mixing regulation,and model parameters were determined by optimization calculation of nonlinear least square method.The correlation between calculated values and the experimental data showed good agreement.展开更多
We solve the equilibrium meanfield equation of state of Ising ferromagnet （obtained from Bragg-Williams theory） by Newton-Raphson method. The number of iterations required to get a convergent solution （within a spe...We solve the equilibrium meanfield equation of state of Ising ferromagnet （obtained from Bragg-Williams theory） by Newton-Raphson method. The number of iterations required to get a convergent solution （within a specified accuracy） of equilibrium magnetisation, at any particular temperature, is observed to diverge in a power law fashion as the temperature approaches the critical value. This is identified as the critical slowing down. The exponent is also estimated. This value of the exponent is compared with that obtained from analytic solution. Besides this, the numerical results are also compared with some experimental results exhibiting satisfactory degree of agreement. It is observed from this study that the information of the invariance of time scale at the critical point is present in the meanfield equilibrium equation of state of Ising ferromagnet.展开更多
The correlation between oxygen concentration and fire temperature when fire was extinguished with water mist was theoretically studied. The Semenov theory was applied to analyze the critical condition when fire was ex...The correlation between oxygen concentration and fire temperature when fire was extinguished with water mist was theoretically studied. The Semenov theory was applied to analyze the critical condition when fire was extin- guished with water mist, from which the correlation could be obtained. The water mist experiments were carded out by varying the fire size, atomizer number, ceiling height, system pressure, and pre-burn time in an enclosed room. The oxygen concentration near the edge of the liquid pool and the fire temperature above the center of the liquid pool were measured. A comparison of the experimental data with the correlation was made under different conditions. The results showed that fire extinguishment was a stochastic process which could be affected by many factors. This theoretical model could predict the correlation between ftre temperature and oxygen concentration when fire was extinguished with water mist in an enclosed room and it can also be treated as a critical condition for fire extinguishment.展开更多
In this study, experiments have been performed for an investigation on heat transfer of water in an inclined downward tube with an inner diameter of 20 mm and an inclined angle of 45° from the horizon, with the r...In this study, experiments have been performed for an investigation on heat transfer of water in an inclined downward tube with an inner diameter of 20 mm and an inclined angle of 45° from the horizon, with the range of pressure from 11.5 to 28 MPa, mass flux from 450 to 1550 kg/(m2 s), and heat flux from 50 to 585 k W/m2. Based on the experimental data, the temperature distribution in the tube wall was derived. The heat transfer characteristics of inclined downward flow were compared with that of vertical downward flow. The effects of heat flux on wall temperature were analyzed and the corresponding empirical correlations were presented. The results show that heat transfer characteristics of water in the inclined downward tube are not uniform along the circumference from the top surface to the bottom surface. An increase in heat flux exacerbates the non-uniformity. At subcritical pressures, both dry-out and departure from nucleate boiling(DNB) occur at the top surface of the inclined downward tube; inversely, only dry-out takes place on the bottom surface of the inclined downward tube and in the vertical downward tube. At near-critical pressures, DNB and dry-out occur in the comparing tubes with greater possibility. At supercritical pressures, heat transfer gets enhanced in the pseudo-critical enthalpy region; in the high enthalpy region, the top surface temperature of the inclined downward tube decreases obviously.展开更多
The leakage research on supercritical carbon dioxide fluid in rolling piston expander was investigated experimentally.Using expander instead of throttle valve is an important way to improve the efficiency of carbon di...The leakage research on supercritical carbon dioxide fluid in rolling piston expander was investigated experimentally.Using expander instead of throttle valve is an important way to improve the efficiency of carbon dioxide refrigeration system.However,the supercritical fluid leakage in expander is serious and is the main factor affecting the expander's efficiency.This paper presented and compared four classic leakage models.The analysis indicated that laminar leakage model is suitable in leakage simulation of expander.A leakage test system,including the leakage test part which has two types of leakage specimens with different gaps ranging from 5 to 15 m,was established.The experimental results indicated that lubricant film played an important role.When the leakage clearance of cylindrical specimen was 5 m,the mass flow rate of leakage was about 0.88 g s-1.The data was 3.638 g s-1 with leakage clearance being 10 m and 7.11g s-1 with leakage clearance being 15 m.A modified leakage model was developed,whose average deviation was within 10% compared with the experimental data.At last,this paper simulated the leakage in rolling piston expander presented by Tian et al.(2010).The leakage between rolling piston and cylinder was the most serious part with the value up to 0.04 kg s-1.展开更多
文摘工业以太网不断地超越其他的网络。具有竞争性的局域网技术经过修改可适用于传送安全-临界的数据—PROFIsafe、INTERBUS Safety、CAN Open Safety等。然而,压力在于基于以太网的技术将取代它们。目前,标准的以太网协议不能够使用一个标准的层来传递安全数据。有一些所有权的解决方案支持公司专用的通信程序如HIMA或者TTTeh-Ethernet。有关的新来者如IDA提供(Interface for Dis-
基金Supported by the IRPA Project of the Ministry of Science,Technology and Innovation,Malaysia (09-02-03-0101-EA0001)Fundamental Research Grant 2009 Directorate General of Higher Education,Ministry of National Education,the Republic of Indonesia
文摘Piperine is a member of the lipids family commonly found in peppercorn, ginger and other natural sources and is grouped as an alkaloid. The solubility of piperine has been determined in carbon dioxide at near critical and supercritical conditions in a dynamic extraction apparatus. The conditions studied were at pressures ranging from 10 to 20 MPa and temperatures at 293, 300, 313, 323 and 333 K. The results showed that piperine solubility increased with increasing pressure at all temperatures studied. The solubility of plperme in near critical conditions was slightly higher than that at supercritical conditions only at the low-pressure range. Two semi-empirical density dependent correlations, namely the Chrastil model and the Dilute Solution model, were also used to estimate the solubility data. Although both models showed good correlation with the solubility data, the Dilute Solution model performed better prediction than the Chrastil model.
文摘This paper proposes an estimation method of fracture resistance of oil ＆ gas pipes, based on the results of full scale hydraulic pressure pipe testing with the artificial notch, made by the authors at 2002-2006. It shows that the fracture process at the stage of stripping （initialization） of crack can be characterized by Critical Fracture Diagram （CFD）. Calculating and experimental way to construct CFD is suggested and discussed. The fracture resistance requirements for oil ＆ gas pipes in terms of fracture mechanics （Kc, Lc） are formulated and proved. The results of full scale hydraulic pressure pipe testing, based on metal testing data of the standard Charpy specimens （KCV） and pipe＇s specification requirements are interrelated. The way to estimate the admissible temperature operation conditions of oil ＆ gas pipes by means of based metal ＂KCV-temperature＂ dependence is proposed.
基金Sponsored by the Project from Natural Scientific Research Innovation Foundation in Harbin Institute of Technology(Grant No. HIT.NSRIF.2008.05)
文摘In this paper, adsorption and regeneration characteristics of multi-walled carbon nanotubes （MWNTs） used as adsorbent were investigated for the removal of 1,3-beuzenediol （BDO） from water by the supercritieal water （SCW） technique. FFIR, XPS, SEM and dispersion stability tests were used to characterize the structure and surface morphology of CNTs. The results showed that CNTs surfaces were slightly activated and strongly etched in supercritieal water system. The adsorption capacity of SCW-treated CNTs was higher than that of raw CNTs. The adsorbed amounts for treated CNTs and raw CNTs samples at the same initial concentration of 60 mg/L were ca. 16.42 and 7.30 mg/g, respectively. The BDO adsorption of treated CNTs was due to the physical adsorption. The experimental data fit Freundlich isotherm model better than Langmuir one. The loaded adsorbent could be efficiently desorbed and regenerated by SCW technique. Therefore, SCW is a promising and environmentally friendly technique for the improvement of adsorption and regeneration of CNTs.
基金Supported by National Natural Science Foundation of China (No 20476071)
文摘The critical curves for binary systems of methane combined with nitrogen, carbon monoxide, carbon dioxide, ethane, propane, butane and water at temperatures from 125 K to 650 K and pressures from 3.5 MPa to 250 MPa were calculated by using Heilig-Franck equation of state. This equation of state contains a repulsion term and an attraction term for intermolecular interaction. With pairwise combination rules for these potentials, three adjustable parameters are needed. The results showed that the critical curves of the former six binary systems belonged to type I, and CH4＋H2O system belonged to type III. The calculated data were compared with the experimental data,which yielded good results for the pressure-temperature, pressure-composition and temperature-composition behaviors of the seven systems. Moreover, the values of the adjustable parameters were obtained from the calculation of the critical curves. They can also be used for other relevant calculation.
文摘Vapor-liquid phase equilibrium data including composition,densities,molar volume and equilibrium constant of isobutanol in supercritical carbon dioxide from 313.2K to 353.2K were measured in a variable-volume visual cell.The properties of critical point were obtained by extrapolation.The results showed that critical temperature,critical pressure and critical compressibility factor of CO2-isobutanol system decreased with the increase of critical CO2 content.The phase equilibrium model was established by Peng-Robinson equation of state and van der Waals-2 mixing regulation,and model parameters were determined by optimization calculation of nonlinear least square method.The correlation between calculated values and the experimental data showed good agreement.
文摘We solve the equilibrium meanfield equation of state of Ising ferromagnet （obtained from Bragg-Williams theory） by Newton-Raphson method. The number of iterations required to get a convergent solution （within a specified accuracy） of equilibrium magnetisation, at any particular temperature, is observed to diverge in a power law fashion as the temperature approaches the critical value. This is identified as the critical slowing down. The exponent is also estimated. This value of the exponent is compared with that obtained from analytic solution. Besides this, the numerical results are also compared with some experimental results exhibiting satisfactory degree of agreement. It is observed from this study that the information of the invariance of time scale at the critical point is present in the meanfield equilibrium equation of state of Ising ferromagnet.
文摘The correlation between oxygen concentration and fire temperature when fire was extinguished with water mist was theoretically studied. The Semenov theory was applied to analyze the critical condition when fire was extin- guished with water mist, from which the correlation could be obtained. The water mist experiments were carded out by varying the fire size, atomizer number, ceiling height, system pressure, and pre-burn time in an enclosed room. The oxygen concentration near the edge of the liquid pool and the fire temperature above the center of the liquid pool were measured. A comparison of the experimental data with the correlation was made under different conditions. The results showed that fire extinguishment was a stochastic process which could be affected by many factors. This theoretical model could predict the correlation between ftre temperature and oxygen concentration when fire was extinguished with water mist in an enclosed room and it can also be treated as a critical condition for fire extinguishment.
基金supported by the "Strategic Priority Research Program" Demonstration of Key Technologies for Clean and Efficient Utilization of Low-rank Coal (Grant No. XDA07030100)
文摘In this study, experiments have been performed for an investigation on heat transfer of water in an inclined downward tube with an inner diameter of 20 mm and an inclined angle of 45° from the horizon, with the range of pressure from 11.5 to 28 MPa, mass flux from 450 to 1550 kg/(m2 s), and heat flux from 50 to 585 k W/m2. Based on the experimental data, the temperature distribution in the tube wall was derived. The heat transfer characteristics of inclined downward flow were compared with that of vertical downward flow. The effects of heat flux on wall temperature were analyzed and the corresponding empirical correlations were presented. The results show that heat transfer characteristics of water in the inclined downward tube are not uniform along the circumference from the top surface to the bottom surface. An increase in heat flux exacerbates the non-uniformity. At subcritical pressures, both dry-out and departure from nucleate boiling(DNB) occur at the top surface of the inclined downward tube; inversely, only dry-out takes place on the bottom surface of the inclined downward tube and in the vertical downward tube. At near-critical pressures, DNB and dry-out occur in the comparing tubes with greater possibility. At supercritical pressures, heat transfer gets enhanced in the pseudo-critical enthalpy region; in the high enthalpy region, the top surface temperature of the inclined downward tube decreases obviously.
基金supported by the National Natural Science Foundation of China (Grant No. 50676064)
文摘The leakage research on supercritical carbon dioxide fluid in rolling piston expander was investigated experimentally.Using expander instead of throttle valve is an important way to improve the efficiency of carbon dioxide refrigeration system.However,the supercritical fluid leakage in expander is serious and is the main factor affecting the expander's efficiency.This paper presented and compared four classic leakage models.The analysis indicated that laminar leakage model is suitable in leakage simulation of expander.A leakage test system,including the leakage test part which has two types of leakage specimens with different gaps ranging from 5 to 15 m,was established.The experimental results indicated that lubricant film played an important role.When the leakage clearance of cylindrical specimen was 5 m,the mass flow rate of leakage was about 0.88 g s-1.The data was 3.638 g s-1 with leakage clearance being 10 m and 7.11g s-1 with leakage clearance being 15 m.A modified leakage model was developed,whose average deviation was within 10% compared with the experimental data.At last,this paper simulated the leakage in rolling piston expander presented by Tian et al.(2010).The leakage between rolling piston and cylinder was the most serious part with the value up to 0.04 kg s-1.
