[Objective] The aim was to indentify diseased leaves of broad bean by vibra- tional spectroscopy. [Method] In this paper, broad bean rust, fusarium rhizome rot, broad bean zonate spot, yellow leaf curl virus and norma...[Objective] The aim was to indentify diseased leaves of broad bean by vibra- tional spectroscopy. [Method] In this paper, broad bean rust, fusarium rhizome rot, broad bean zonate spot, yellow leaf curl virus and normal leaves were studied using Fourier transform infrared spectroscopy combined with chemometrics. [Result] The spectra of the samples were similar, only with minor differences in absorption inten- sity of several peaks. Second derivative analyses show that the significant difference of all samples was in the range of 1 200-700 cm2. The data in the range of 1 200- 700 cm' were selected to evaluate correlation coefficients, hierarchical cluster analy- sis (HCA) and principal component analysis (PCA). Results showed that the correla- tion coefficients are larger than 0.928 not only between the healthy leaves, but also between the same diseased leaves. The values between healthy and diseased leaves, and among diseased leaves, are all declined. HCA and PCA yielded about 73.3% and 82.2% accuracy, respectively. [Conclusion] This study demonstrated that FTIR techniques might be used to detect crop diseases.展开更多
In order to distinguish 8 kinds of rhizome crops, the 40 samples were studied by Fourier transform infrared spectroscopy (FTIR) combined with wavelet transform (WT), principal component analysis (PCA) and hieram...In order to distinguish 8 kinds of rhizome crops, the 40 samples were studied by Fourier transform infrared spectroscopy (FTIR) combined with wavelet transform (WT), principal component analysis (PCA) and hieramhical cluster analysis (HCA). The results showed that the infrared spectra were similar on the whole, but there were differences in peak position, peak shape and peak absorption intensity in the range of 1 800-700 cm-1. The infrared spectra in the range of 1 800-700 cm-1 were selected to perform continuous wavelet transform (CWT) and discrete wavelet transform (DWT). The 15th-Ievel decomposition coefficients of CWT and the 5=-level detail coefficients of DWT were classified by PCA and HCA. The cumulative contri- bution rates of the first three principal components of CWT and DWT were 93.12% and 89.78%, respectively. The accurate recognition rates of PCA and HCA were all 100%. It is proved that FTIR combined with WT can be used to distinguish different kinds of rhizome crops.展开更多
In this letter,the new concept of Relative Principle Component (RPC) and method of RPC Analysis (RPCA) are put forward. Meanwhile,the concepts such as Relative Transform (RT),Ro-tundity Scatter (RS) and so on are intr...In this letter,the new concept of Relative Principle Component (RPC) and method of RPC Analysis (RPCA) are put forward. Meanwhile,the concepts such as Relative Transform (RT),Ro-tundity Scatter (RS) and so on are introduced. This new method can overcome some disadvantages of the classical Principle Component Analysis (PCA) when data are rotundity scatter. The RPC selected by RPCA are more representative,and their significance of geometry is more notable,so that the application of the new algorithm will be very extensive. The performance and effectiveness are simply demonstrated by the geometrical interpretation proposed.展开更多
Fourier transform infrared attenuated total reflectance (FTIR-ATR) spectroscopy was employed to characterize rapeseed oils. The spectral features of rapeseed oils were first investigated. Spectral data was processed...Fourier transform infrared attenuated total reflectance (FTIR-ATR) spectroscopy was employed to characterize rapeseed oils. The spectral features of rapeseed oils were first investigated. Spectral data was processed using principal component analysis (PCA) and linear discriminant analysis (LDA) to discriminate the oils from three cultivars of rapeseeds. As a result, 100% discrimination accuracy was obtained by LDA. Furthermore, the applicability of FTIR-ATR spectroscopy to characterize the changes of rapeseed oils caused by thermal treatment was studied. The rapeseed oil at 60 ℃ was regularly subjected to spectral measurement, and the spectral changes induced by thermal treatment were analyzed and discussed. This study had demonstrated the good performance of FTIR-ATR spectroscopy in characterizing rapeseed oils.展开更多
In order to monitor malt quality in the malting industry, despite yearly variations in the barley quality, 394 barley samples were analysed using conventional (moisture, protein and B-glucan content) and mid-infrare...In order to monitor malt quality in the malting industry, despite yearly variations in the barley quality, 394 barley samples were analysed using conventional (moisture, protein and B-glucan content) and mid-infrared Fourier transform spectroscopy FT-IR. The experimental dataset included barley from three harvest years, two barley species, 77 barley varieties, and two-row and six-row barley, from 16 cultivation sites. For each sample, the malt quality indices were also assessed according to European Brewing Convention (EBC) standards. Principal component analysis (PCA) was carried out on mean-centred, normalized and derivative spectra using 200/cm width spectral bands. The most informative spectral bands were observed in the 800-1,000/cm and 1,000-1,200/cm ranges. PCA revealed that barley harvested in 2010 and in 2011 had bands that were very close together, while 2009 harvest clearly displayed a difference in its quality. PCA made it possible to distinguish two species and confirmed that two-row winter barley quality was closer to two-row spring barley quality than to six-row winter barley. Results indicate that mid-infrared spectrometry (MIR) could be a very useful and rapid analytical tool to assess barley qualitative quality.展开更多
基金Supported by National Natural Science Foundation of China(30960179)Natural Science Foundation of Yunnan Province(2007A048M)~~
文摘[Objective] The aim was to indentify diseased leaves of broad bean by vibra- tional spectroscopy. [Method] In this paper, broad bean rust, fusarium rhizome rot, broad bean zonate spot, yellow leaf curl virus and normal leaves were studied using Fourier transform infrared spectroscopy combined with chemometrics. [Result] The spectra of the samples were similar, only with minor differences in absorption inten- sity of several peaks. Second derivative analyses show that the significant difference of all samples was in the range of 1 200-700 cm2. The data in the range of 1 200- 700 cm' were selected to evaluate correlation coefficients, hierarchical cluster analy- sis (HCA) and principal component analysis (PCA). Results showed that the correla- tion coefficients are larger than 0.928 not only between the healthy leaves, but also between the same diseased leaves. The values between healthy and diseased leaves, and among diseased leaves, are all declined. HCA and PCA yielded about 73.3% and 82.2% accuracy, respectively. [Conclusion] This study demonstrated that FTIR techniques might be used to detect crop diseases.
基金Supported by National Natural Science Foundation of China(30960179)Program for Innovative Research Team in Science and Technology in University of Yunnan Province~~
文摘In order to distinguish 8 kinds of rhizome crops, the 40 samples were studied by Fourier transform infrared spectroscopy (FTIR) combined with wavelet transform (WT), principal component analysis (PCA) and hieramhical cluster analysis (HCA). The results showed that the infrared spectra were similar on the whole, but there were differences in peak position, peak shape and peak absorption intensity in the range of 1 800-700 cm-1. The infrared spectra in the range of 1 800-700 cm-1 were selected to perform continuous wavelet transform (CWT) and discrete wavelet transform (DWT). The 15th-Ievel decomposition coefficients of CWT and the 5=-level detail coefficients of DWT were classified by PCA and HCA. The cumulative contri- bution rates of the first three principal components of CWT and DWT were 93.12% and 89.78%, respectively. The accurate recognition rates of PCA and HCA were all 100%. It is proved that FTIR combined with WT can be used to distinguish different kinds of rhizome crops.
基金Supported by the National Natural Science Foundation of China (No.60434020, No.60374020)International Coop-eration Item of Henan Province (No.0446650006)Henan Province Outstanding Youth Science Fund (No.0312001900).
文摘In this letter,the new concept of Relative Principle Component (RPC) and method of RPC Analysis (RPCA) are put forward. Meanwhile,the concepts such as Relative Transform (RT),Ro-tundity Scatter (RS) and so on are introduced. This new method can overcome some disadvantages of the classical Principle Component Analysis (PCA) when data are rotundity scatter. The RPC selected by RPCA are more representative,and their significance of geometry is more notable,so that the application of the new algorithm will be very extensive. The performance and effectiveness are simply demonstrated by the geometrical interpretation proposed.
文摘Fourier transform infrared attenuated total reflectance (FTIR-ATR) spectroscopy was employed to characterize rapeseed oils. The spectral features of rapeseed oils were first investigated. Spectral data was processed using principal component analysis (PCA) and linear discriminant analysis (LDA) to discriminate the oils from three cultivars of rapeseeds. As a result, 100% discrimination accuracy was obtained by LDA. Furthermore, the applicability of FTIR-ATR spectroscopy to characterize the changes of rapeseed oils caused by thermal treatment was studied. The rapeseed oil at 60 ℃ was regularly subjected to spectral measurement, and the spectral changes induced by thermal treatment were analyzed and discussed. This study had demonstrated the good performance of FTIR-ATR spectroscopy in characterizing rapeseed oils.
文摘In order to monitor malt quality in the malting industry, despite yearly variations in the barley quality, 394 barley samples were analysed using conventional (moisture, protein and B-glucan content) and mid-infrared Fourier transform spectroscopy FT-IR. The experimental dataset included barley from three harvest years, two barley species, 77 barley varieties, and two-row and six-row barley, from 16 cultivation sites. For each sample, the malt quality indices were also assessed according to European Brewing Convention (EBC) standards. Principal component analysis (PCA) was carried out on mean-centred, normalized and derivative spectra using 200/cm width spectral bands. The most informative spectral bands were observed in the 800-1,000/cm and 1,000-1,200/cm ranges. PCA revealed that barley harvested in 2010 and in 2011 had bands that were very close together, while 2009 harvest clearly displayed a difference in its quality. PCA made it possible to distinguish two species and confirmed that two-row winter barley quality was closer to two-row spring barley quality than to six-row winter barley. Results indicate that mid-infrared spectrometry (MIR) could be a very useful and rapid analytical tool to assess barley qualitative quality.