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表面增强拉曼光谱结合乘子效应模型对血浆和药片中甲巯咪唑的定量检测 被引量:3
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作者 胡敏 陈增萍 +2 位作者 陈瑶 石彩霞 俞汝勤 《分析化学》 SCIE EI CAS CSCD 北大核心 2015年第5期759-764,共6页
将表面增强拉曼散射(Surface-enhanced raman scattering,SERS)技术与乘子效应模型结合,采用2-巯基异烟酸作为内标,以银纳米颗粒为SERS增强基底,对血浆和药片样本中甲巯咪唑的进行准确的定量分析。实验结果表明,本方法对血浆样本中甲... 将表面增强拉曼散射(Surface-enhanced raman scattering,SERS)技术与乘子效应模型结合,采用2-巯基异烟酸作为内标,以银纳米颗粒为SERS增强基底,对血浆和药片样本中甲巯咪唑的进行准确的定量分析。实验结果表明,本方法对血浆样本中甲巯咪唑的平均相对预测误差为5.1%,检出限为32 nmol/L;对药片中甲巯咪唑的定量结果与LC-MS/MS方法基本一致,其加标回收率在93.3%~110.9%之间。 展开更多
关键词 表面增强拉曼光谱 甲巯咪唑 2-巯基异烟酸 乘子效应模型 定量分析
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两阶段DEA超效率对博物馆文化服务效率评价
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作者 高颖 翟丹妮 《管理科学与研究(中英文版)》 2023年第6期1-11,共11页
博物馆是地区公共文化服务体系的重要组成部分。本研究基于两阶段DEA模型,在规模收益改变(VRS)的条件下,考虑了各省份间的竞争关系。将两阶段加性模型与超效率模型相结合,减少了各省文化服务效率相同的排序,增加了区分度。同时,利用乘... 博物馆是地区公共文化服务体系的重要组成部分。本研究基于两阶段DEA模型,在规模收益改变(VRS)的条件下,考虑了各省份间的竞争关系。将两阶段加性模型与超效率模型相结合,减少了各省文化服务效率相同的排序,增加了区分度。同时,利用乘子模型与包络模型在两阶段网络结构中等价关系对2020年中国博物馆文化服务效率进行研究分析;得出西部地区博物馆文化服务效率较高,并且博物馆文化服务效率与经济发展水平无直接关联。同将模型结果与博物馆领域现有评级结果进行对比,得出部分地区存在较大差异。对于低效率的省份通过投影值对其投入产出指标进行调整,根据调整量分析出地方文化财务支出冗余是省份无效的主要原因。 展开更多
关键词 博物馆文化服务效率 两阶段DEA模型 加性超效率 乘子模型 包络模型
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表面增强拉曼散射光谱定量分析技术的研究进展 被引量:18
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作者 左奇 陈瑶 +1 位作者 石彩霞 陈增萍 《分析化学》 SCIE EI CAS CSCD 北大核心 2015年第11期1656-1663,共8页
表面增强拉曼散射(SERS)光谱具有灵敏度高、光谱特征强、受光漂白影响小等特点,在环境、食品和药品、以及生物分析等领域有着广阔的应用前景。目前,SERS光谱技术仅属于定性或半定量分析技术,尚未发展成为一项成熟的定量分析检测技术。... 表面增强拉曼散射(SERS)光谱具有灵敏度高、光谱特征强、受光漂白影响小等特点,在环境、食品和药品、以及生物分析等领域有着广阔的应用前景。目前,SERS光谱技术仅属于定性或半定量分析技术,尚未发展成为一项成熟的定量分析检测技术。本文综述了现有文献中用于提高SERS定量结果准确度的方法以及它们的优缺点,并在此基础上展望了SERS技术在复杂体系中定量分析的发展方向。 展开更多
关键词 表面增强拉曼散射光谱 乘子效应模型 定量分析 评述
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A Note on Shor’s Quantum Algorithm 被引量:1
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作者 曹正军 刘丽华 《Journal of Shanghai Jiaotong university(Science)》 EI 2006年第3期368-370,共3页
Shor proposed a polynomial time algorithm for computing the order of one element in a multiplicative group using a quantum computer. Based on Miller’s randomization, he then gave a factorization algorithm. But the al... Shor proposed a polynomial time algorithm for computing the order of one element in a multiplicative group using a quantum computer. Based on Miller’s randomization, he then gave a factorization algorithm. But the algorithm has two shortcomings, the order must be even and the output might be a trivial factor. Actually, these drawbacks can be overcome if the number is an RSA modulus. Applying the special structure of the RSA modulus, an algorithm is presented to overcome the two shortcomings. The new algorithm improves Shor’s algorithm for factoring RSA modulus. The cost of the factorization algorithm almost depends on the calculation of the order of 2 in the multiplication group. 展开更多
关键词 Shor's quantum algorithm RSA modulus order
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Optimization Model on Quadratic Programming Problem with Fuzzy
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作者 Sugiyarto Surono Yosza Dasril Mohd Ismail 《Journal of Mathematics and System Science》 2012年第7期464-468,共5页
In this paper, the authors propose a computational procedure by using fuzzy approach to fred the optimal solution of quadratic programming problems. The authors divide the calculation of the optimal solution into two ... In this paper, the authors propose a computational procedure by using fuzzy approach to fred the optimal solution of quadratic programming problems. The authors divide the calculation of the optimal solution into two stages. In the first stage the authors determine the unconstrained minimization and check its feasibility. The second stage, the authors explore the feasible region from initial point to another point until the authors get the optimal point by using Lagrange multiplier. A numerical example is included to support as illustration of the paper. 展开更多
关键词 Fuzzy optimal solution triangular fuzzy number feasible set quadratic programming positive definite.
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Non-deterministic fatigue life analysis using convex set models 被引量:5
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作者 SUN WenCai YANG ZiChun LI KunFeng 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2013年第4期765-774,共10页
The non-probabilistic approach to fatigue life analysis was studied using the convex models-interval, ellipsoidal and multiconvex models. The lower and upper bounds of the fatigue life were obtained by using the secon... The non-probabilistic approach to fatigue life analysis was studied using the convex models-interval, ellipsoidal and multiconvex models. The lower and upper bounds of the fatigue life were obtained by using the second-order Taylor series and Lagrange multiplier method. The solving process for derivatives of the implicit life function was presented. Moreover, a median ellipsoidal model was proposed which can take into account the sample blind zone and almost impossibility of concurrence of some small probability events. The Monte Carlo method for multi-convex model was presented, an important alternative when the analytical method does not work. A project example was given. The feasibility and rationality of the presented approach were verified. It is also revealed that the proposed method is conservative compared to the traditional probabilistic method, but it is a useful complement when it is difficult to obtain the accurate probability densities of parameters. 展开更多
关键词 non-deterministic fatigue life convex set model NON-PROBABILISTIC Taylor expansion Monte Carlo
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