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差压热耦合反应精馏应用于乙酸甲酯水解研究 被引量:3
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作者 李军 王汝军 +2 位作者 王丁丁 马占华 孙兰义 《中国石油大学学报(自然科学版)》 EI CAS CSCD 北大核心 2014年第1期155-160,共6页
结合差压热耦合和反应精馏工艺优势,提出形成差压热耦合反应的精馏工艺方法,将其应用于乙酸甲酯水解过程。在验证UNIQ-HOC模型对模拟该体系适用性的基础上,对影响该工艺的主要影响因素进行考察,得出优化后的主要操作参数,并对比差压热... 结合差压热耦合和反应精馏工艺优势,提出形成差压热耦合反应的精馏工艺方法,将其应用于乙酸甲酯水解过程。在验证UNIQ-HOC模型对模拟该体系适用性的基础上,对影响该工艺的主要影响因素进行考察,得出优化后的主要操作参数,并对比差压热耦合精馏和常规流程的能耗。结果表明,差压热耦合反应精馏增加813.33 kW的功耗,减少7062.3 kW的热量,节能效果显著。 展开更多
关键词 乙酸甲酯水解 差压热耦合 反应精馏 模拟优化 节能
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Study on Hydrolysis of Methyl Acetate in a Catalytic Distillation Column 被引量:3
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作者 王成习 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2001年第4期382-387,共6页
A nonequilibrium stage model was used to simulate countercurrent multicomponent catalytic distillation processes for methyl acetate hydrolysis. Computations of stage efficiencies or height equivalent to a theoretical ... A nonequilibrium stage model was used to simulate countercurrent multicomponent catalytic distillation processes for methyl acetate hydrolysis. Computations of stage efficiencies or height equivalent to a theoretical plate (HETP) were entirely avoided by this model. The consistency of simulated results and experimental data in conversions and concentration of each component along a column indicates that the model predicts the actual process well. The influences of operating parameters on hydrolytic conversions, such as feed molar ratios, feed locations, feed and reflux rates, heights of reactive and stripping sections, were analyzed adequately by simulating calculations. A good operating mode was then obtained, which is helpful to the development of a new process. 展开更多
关键词 methyl acetate HYDROLYSIS catalytic distillation nonequilibrium stage model
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