In emulsion system, micro-organisms survive in water phase, thus concentration of preservative in water phase directly reflects to anti-fungi efficacy. As preservative easily migrates into oil phase, it reduces preser...In emulsion system, micro-organisms survive in water phase, thus concentration of preservative in water phase directly reflects to anti-fungi efficacy. As preservative easily migrates into oil phase, it reduces preservative efficacy. A common solution is to increase preservative amount in the whole system. However this way always brings safety issues as preservative is a major allergen. Another effective but safety way is to prohibit preservative migrating into oil phase. In cosmetic research area, phenoxyethanol (PE) and p-Hydroxyacetophenone (p-HAP) pair gradually emerges to be a popular preservative candidate. Thus this new preservative system has been focused as the research object in this work. The relative contents (C) of both PE (CPE) and p-HAP (Cp-HAP) in water phase has been carefully determined. Eight commonly used oils have been further employed to check CPE and Cp-HAP in different oil-water system. The other infuence parameters such as polyols, processing parameters are also investigated. Results shows squalane, petrolatum, silicone oil and hydrogenated polyisobutene might be good oil phase candidates for formulation when using PE and p-HAP preservative system. In these oil systems, PE and p-HAP are mainly located in water phase. Besides, increasing percentage of 1, 3-butylene glycol, shortening homogenization time or adding preservatives at the end of processing under lower temperature could effectively increase effective content preservatives in water phase, either.展开更多
In this article, AHPS (3 - allyloxy- 2 -hydrory- 1 -Propanesulfonate salt) wassynthesized to use in emulsifier-Ne emulsion polymerization of BA/BMa/MMA systemfor high solid content latexes. Storage stability klow beha...In this article, AHPS (3 - allyloxy- 2 -hydrory- 1 -Propanesulfonate salt) wassynthesized to use in emulsifier-Ne emulsion polymerization of BA/BMa/MMA systemfor high solid content latexes. Storage stability klow behavior of the latexes,morphology of the obtained latex particles, dynamic viscoelastic behavior, tensilestrength and water resistance properties of the resulted copolymers were investigated.The experimental results show that with the addition of AHPS, stability of the emulsionis greatly improved that there appears no apparent precipitation dunring thepolymerization and storage at room temperature for 6 months and at -10℃ for fourmonths. Flow of the latexes follows the Bingham body laws, diameter of the latexparticles is about 0.6μn, of which is larger than that of by conventional emulsionpolymerization(0.12μm). In addition, not only water resistance of the copolymersobtained by emulsifier-free emulsion polymerization is greatly improved, but alsotensile strength is obviously enhanced.展开更多
Aiming at deep desulfurization of gasoline,three amphiphilic catalysts [C18H37N(CH3)3]3+x [PMo12-xVxO40](x=1,2,or 3) were prepared and characterized.The amphiphilic vanadium(V)-substituted polyoxometalates were dissol...Aiming at deep desulfurization of gasoline,three amphiphilic catalysts [C18H37N(CH3)3]3+x [PMo12-xVxO40](x=1,2,or 3) were prepared and characterized.The amphiphilic vanadium(V)-substituted polyoxometalates were dissolved in water-immiscible ionic liquid([Bmim]PF6),forming a H2O2-in-[Bmim]PF6 emulsion desulfurization system with 30 m% H2O2 serving as the oxidant.The catalytic oxidation of sulfur-containing model oil has been studied in detail under various reaction conditions using this system.The ionic liquid emulsion system showed high catalytic oxidative activity in the treatment of commodity gasoline.Furthermore,the mechanism of catalytic oxidative desulfurization was also elaborated.展开更多
文摘In emulsion system, micro-organisms survive in water phase, thus concentration of preservative in water phase directly reflects to anti-fungi efficacy. As preservative easily migrates into oil phase, it reduces preservative efficacy. A common solution is to increase preservative amount in the whole system. However this way always brings safety issues as preservative is a major allergen. Another effective but safety way is to prohibit preservative migrating into oil phase. In cosmetic research area, phenoxyethanol (PE) and p-Hydroxyacetophenone (p-HAP) pair gradually emerges to be a popular preservative candidate. Thus this new preservative system has been focused as the research object in this work. The relative contents (C) of both PE (CPE) and p-HAP (Cp-HAP) in water phase has been carefully determined. Eight commonly used oils have been further employed to check CPE and Cp-HAP in different oil-water system. The other infuence parameters such as polyols, processing parameters are also investigated. Results shows squalane, petrolatum, silicone oil and hydrogenated polyisobutene might be good oil phase candidates for formulation when using PE and p-HAP preservative system. In these oil systems, PE and p-HAP are mainly located in water phase. Besides, increasing percentage of 1, 3-butylene glycol, shortening homogenization time or adding preservatives at the end of processing under lower temperature could effectively increase effective content preservatives in water phase, either.
文摘In this article, AHPS (3 - allyloxy- 2 -hydrory- 1 -Propanesulfonate salt) wassynthesized to use in emulsifier-Ne emulsion polymerization of BA/BMa/MMA systemfor high solid content latexes. Storage stability klow behavior of the latexes,morphology of the obtained latex particles, dynamic viscoelastic behavior, tensilestrength and water resistance properties of the resulted copolymers were investigated.The experimental results show that with the addition of AHPS, stability of the emulsionis greatly improved that there appears no apparent precipitation dunring thepolymerization and storage at room temperature for 6 months and at -10℃ for fourmonths. Flow of the latexes follows the Bingham body laws, diameter of the latexparticles is about 0.6μn, of which is larger than that of by conventional emulsionpolymerization(0.12μm). In addition, not only water resistance of the copolymersobtained by emulsifier-free emulsion polymerization is greatly improved, but alsotensile strength is obviously enhanced.
基金the National Nature Science Foundation of China(No.51077013,50873026)Production and Research Prospective Joint Project of Jiangsu Province of China(BY2009153)+2 种基金the Key Program for the Scientific Research Guiding Fund of Basic Scientific Research Operation Expenditure,Southeast University(3207040103)333 High-level Talent Training Project,Jiangsu Province of China (BRA2010033)Student Research Training Program of Southeast University(No.091028644) for financial support
文摘Aiming at deep desulfurization of gasoline,three amphiphilic catalysts [C18H37N(CH3)3]3+x [PMo12-xVxO40](x=1,2,or 3) were prepared and characterized.The amphiphilic vanadium(V)-substituted polyoxometalates were dissolved in water-immiscible ionic liquid([Bmim]PF6),forming a H2O2-in-[Bmim]PF6 emulsion desulfurization system with 30 m% H2O2 serving as the oxidant.The catalytic oxidation of sulfur-containing model oil has been studied in detail under various reaction conditions using this system.The ionic liquid emulsion system showed high catalytic oxidative activity in the treatment of commodity gasoline.Furthermore,the mechanism of catalytic oxidative desulfurization was also elaborated.