A novel zinc-rich pigment based on P(St-BA-MAA-SPAA) nano-latex was obtained, which is suitable for the use in hot alkali liquid medium. The nano-latex was synthesized by active emulsifier latex polymerization method ...A novel zinc-rich pigment based on P(St-BA-MAA-SPAA) nano-latex was obtained, which is suitable for the use in hot alkali liquid medium. The nano-latex was synthesized by active emulsifier latex polymerization method with monomers of styrene (St), butylacrylate (BA), methylacrylic acid(MAA) in the presence of active emulsifier 3-sulfopropylacrylate(SPAA). The synthesis condition and properties of the latex were investigated. And the anti-corrosive property of the resultant zinc-rich coating was studied. The results show that the nano-latex is self-stabilized and has a narrow particle diameter distribution, the average diameter of the latex particles is 71 nm. Zinc powders can be evenly dispersed in the nano-latex, which indicates that the P(St-BA-MAA-SPAA) nano latex can be used as the binder of zinc-rich coating. The resultant zinc-rich coating is able to resist the invasion of hot alkali solution(the temperature is 95 ℃ and the pH value is 14) for 480 h and the exposure time in salt spray is 1 200 h. Moreover, the coating shows good thermal conductivity and static electricity properties, its thermal conductivity and electric resistivity are 21-37 W/(m·K) and 6.7×105-3.5×106 Ω·cm, respectively.展开更多
The centralized processing of high-sulfur and high-acidity crude has contributed to improvement of the overall economic benefits of the oil refining enterprise, but has also resulted in crude emulsification, severe co...The centralized processing of high-sulfur and high-acidity crude has contributed to improvement of the overall economic benefits of the oil refining enterprise, but has also resulted in crude emulsification, severe corrosion of process units and environmental protection issues. The long-cycle, safe and smooth operation of process units were guaranteed after selection of optimal processing routes and adoption of a series of technical measures.展开更多
In emulsion system, micro-organisms survive in water phase, thus concentration of preservative in water phase directly reflects to anti-fungi efficacy. As preservative easily migrates into oil phase, it reduces preser...In emulsion system, micro-organisms survive in water phase, thus concentration of preservative in water phase directly reflects to anti-fungi efficacy. As preservative easily migrates into oil phase, it reduces preservative efficacy. A common solution is to increase preservative amount in the whole system. However this way always brings safety issues as preservative is a major allergen. Another effective but safety way is to prohibit preservative migrating into oil phase. In cosmetic research area, phenoxyethanol （PE） and p-Hydroxyacetophenone （p-HAP） pair gradually emerges to be a popular preservative candidate. Thus this new preservative system has been focused as the research object in this work. The relative contents （C） of both PE （CPE） and p-HAP （Cp-HAP） in water phase has been carefully determined. Eight commonly used oils have been further employed to check CPE and Cp-HAP in different oil-water system. The other infuence parameters such as polyols, processing parameters are also investigated. Results shows squalane, petrolatum, silicone oil and hydrogenated polyisobutene might be good oil phase candidates for formulation when using PE and p-HAP preservative system. In these oil systems, PE and p-HAP are mainly located in water phase. Besides, increasing percentage of 1, 3-butylene glycol, shortening homogenization time or adding preservatives at the end of processing under lower temperature could effectively increase effective content preservatives in water phase, either.展开更多
Fermented whey （a by-product from tofu industry） has been used as a coagulant in tofu manufactures in Indonesia. This research aimed to study effects of fermented whey on coagulation efficiency and physicochemical c...Fermented whey （a by-product from tofu industry） has been used as a coagulant in tofu manufactures in Indonesia. This research aimed to study effects of fermented whey on coagulation efficiency and physicochemical characteristics of tofu, compared to other acid coagulants （acetic acid and glucono-delta-lactone （GDL）） and salt coagulants （calcium sulfate and natural gypsum）. A randomized block design with a single factor was used in this research. Fermented whey could be used as coagulant in tofu manufacturing. Physicochemical characteristics of tofu from fermented whey were not significantly difference compared to tofu from calcium salt and acid coagulants. Coagulation efficiencies （CF, TSIL TPR and TB~） of fermented whey are lower than that from calcium salt coagulants （calcium sulphate and natural gypsum）. Fermented whey showed no significant differences in tofu properties and parameters of coagulation process, compared to GDL and acetic acid.展开更多
文摘A novel zinc-rich pigment based on P(St-BA-MAA-SPAA) nano-latex was obtained, which is suitable for the use in hot alkali liquid medium. The nano-latex was synthesized by active emulsifier latex polymerization method with monomers of styrene (St), butylacrylate (BA), methylacrylic acid(MAA) in the presence of active emulsifier 3-sulfopropylacrylate(SPAA). The synthesis condition and properties of the latex were investigated. And the anti-corrosive property of the resultant zinc-rich coating was studied. The results show that the nano-latex is self-stabilized and has a narrow particle diameter distribution, the average diameter of the latex particles is 71 nm. Zinc powders can be evenly dispersed in the nano-latex, which indicates that the P(St-BA-MAA-SPAA) nano latex can be used as the binder of zinc-rich coating. The resultant zinc-rich coating is able to resist the invasion of hot alkali solution(the temperature is 95 ℃ and the pH value is 14) for 480 h and the exposure time in salt spray is 1 200 h. Moreover, the coating shows good thermal conductivity and static electricity properties, its thermal conductivity and electric resistivity are 21-37 W/(m·K) and 6.7×105-3.5×106 Ω·cm, respectively.
文摘The centralized processing of high-sulfur and high-acidity crude has contributed to improvement of the overall economic benefits of the oil refining enterprise, but has also resulted in crude emulsification, severe corrosion of process units and environmental protection issues. The long-cycle, safe and smooth operation of process units were guaranteed after selection of optimal processing routes and adoption of a series of technical measures.
文摘In emulsion system, micro-organisms survive in water phase, thus concentration of preservative in water phase directly reflects to anti-fungi efficacy. As preservative easily migrates into oil phase, it reduces preservative efficacy. A common solution is to increase preservative amount in the whole system. However this way always brings safety issues as preservative is a major allergen. Another effective but safety way is to prohibit preservative migrating into oil phase. In cosmetic research area, phenoxyethanol （PE） and p-Hydroxyacetophenone （p-HAP） pair gradually emerges to be a popular preservative candidate. Thus this new preservative system has been focused as the research object in this work. The relative contents （C） of both PE （CPE） and p-HAP （Cp-HAP） in water phase has been carefully determined. Eight commonly used oils have been further employed to check CPE and Cp-HAP in different oil-water system. The other infuence parameters such as polyols, processing parameters are also investigated. Results shows squalane, petrolatum, silicone oil and hydrogenated polyisobutene might be good oil phase candidates for formulation when using PE and p-HAP preservative system. In these oil systems, PE and p-HAP are mainly located in water phase. Besides, increasing percentage of 1, 3-butylene glycol, shortening homogenization time or adding preservatives at the end of processing under lower temperature could effectively increase effective content preservatives in water phase, either.
文摘Fermented whey （a by-product from tofu industry） has been used as a coagulant in tofu manufactures in Indonesia. This research aimed to study effects of fermented whey on coagulation efficiency and physicochemical characteristics of tofu, compared to other acid coagulants （acetic acid and glucono-delta-lactone （GDL）） and salt coagulants （calcium sulfate and natural gypsum）. A randomized block design with a single factor was used in this research. Fermented whey could be used as coagulant in tofu manufacturing. Physicochemical characteristics of tofu from fermented whey were not significantly difference compared to tofu from calcium salt and acid coagulants. Coagulation efficiencies （CF, TSIL TPR and TB~） of fermented whey are lower than that from calcium salt coagulants （calcium sulphate and natural gypsum）. Fermented whey showed no significant differences in tofu properties and parameters of coagulation process, compared to GDL and acetic acid.
