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二乙二醇丙酸甲酯的合成与结构表征
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作者 施立钦 邱从平 《化学分析计量》 CAS 2016年第2期41-43,68,共4页
采用二乙二醇和丙酸甲酯为主要原料,以钾为催化剂,在通N2 气保护的条件下合成二乙二醇丙酸甲酯,用离子排阻高效液相色谱法对合成的二乙二醇丙酸甲酯进行定量分析.最佳合成条件二乙二醇与丙酸甲酯的物质的量比为1∶2,催化剂的质量为反应... 采用二乙二醇和丙酸甲酯为主要原料,以钾为催化剂,在通N2 气保护的条件下合成二乙二醇丙酸甲酯,用离子排阻高效液相色谱法对合成的二乙二醇丙酸甲酯进行定量分析.最佳合成条件二乙二醇与丙酸甲酯的物质的量比为1∶2,催化剂的质量为反应物二乙二醇质量的1.5%,于25℃条件下反应24 h,产物经硅胶柱分离、乙酸乙酯梯度洗脱,然后干燥,制得二乙二醇丙酸甲酯成品,收率为61.5%,纯度达99.5%.用FT-IR,1 H–NMR,GC–MS 法对二乙二醇丙酸甲酯的分子结构进行了确证. 展开更多
关键词 二乙二醇丙酸甲酯 离子排阻柱 PEG修饰剂 核磁共振
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Properties of Surface Cyclic Oligomers Present on Polyester Fiber
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作者 郑敏 宋心远 《Journal of Donghua University(English Edition)》 EI CAS 2003年第1期22-26,共5页
The effects of different treatments, such as dry heat,wet heat, solvent vapor and ultrasonic, on propertiesof the cyclic oligomers on the surface of polyester fiberare studied. The components of surface oligomers area... The effects of different treatments, such as dry heat,wet heat, solvent vapor and ultrasonic, on propertiesof the cyclic oligomers on the surface of polyester fiberare studied. The components of surface oligomers areanalyzed through Thin-Layer Chromatograph. Theresult shows that: all of the treatment, especially solvent vapor treatment,call significantly increase the content of surface cyclic oligomers.The content of cyclic triIner is increased more considerably than other oligomers. Moreover,the morphology and thedistribution of surface cyclic oligomers are also different from different treatments:Dry heat and wet heat cause larger polygonal solids distributed evenly on the surface of fiber;solvent vapor nlakes fiber surface exhibit irregular rodlike crystal shapes randomly;ultrasonic treatment induces some obscureand smaller deposi^on the surface of fiber. 展开更多
关键词 heat treatment solvent vapor ULTRASONIC cyclic oligomers thin—layer chromatograph
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