二元混合系的端元Sm-Nd模式年龄及在造山带基底研究中的意义

本文提出二元混合体系的端元Sm-Nd模式年龄的计算方法,利用该方法计算二元混合体系两端元的Sm-Nd同位素组成,二端元在混源样品中的重量百分比及地壳残留时间。借助此方法,笔者计算了东秦岭褶皱带基底的Sm-Nd同位素物质组成及形成时代,并讨论了其基底演化过程。研究结果表明,南、北秦岭褶皱带的基底在物质来源和形成时代上存在明显的差别。北秦岭褶皱带基底由 3000Ma和 608Ma两个端元混合组成;而南秦岭褶皱带的基底,则由 1700Ma和 989Ma两个端元混合组成。研究暗示了东秦岭褶皱带存在二次重要的壳幔分异事件,时间分别为989Ma和608Ma。

二元混合物系粘度与密度的推算

以相异组分的摩尔分数及其所含碳原子数描述物系组成与差异,采用遗传程序设计方法构建了运动学粘度和密度的关联模型,以此模型对未受试体系进行了推算并与实验值进行了比较。

熔融NaCaF_3、Na_2CaF_4和Na_3CaF_5的分子动力学模拟

通过分子动力学模拟，研究了熔盐溶液NaCaF3、Na2CaF4和Na4CaF5体系，模拟表明，三种二元混合系的径向分布函数十分接近．由模拟所得到的摩尔混合焓很好地与实验值一致．混合焓与Na＋离子势阱深度之间表现出很好的线性关系．模拟表明，在Na2CaF4体系中，即NaF－CaF2二元系处于低共熔混合组分比NaF：CaF2＝2：1时，Na＋，Ca2＋和F－离子的自扩散系数出现很大的反常．

Hydrolysis of Carbonyl Sulfide in Binary Mixture of Diethylene Glycol Diethyl Ether and Water

The solubility and hydrolysis of carbonyl sulfide in binary mixture of diethylene glycol diethyl ether and water are studied as a function of composition. The use of an aqueous solution of diethylene glycol diethyl ether enhances the solubility and hydrolysis rate of carbonyl sulfide compared with that in pure water. The composition of the mixture with maximum hydrolysis rate varies with temperature. The thermophysical properties including density, viscosity, and surface tension as a function of composition at 20℃ under atmospheric pressure as well as liquid-liquid equilibrium (LLE) data over the temperature range from 28℃ to 90℃ are also measured for the binary mixture.

Dispersion Relations in Binary Gas Mixtures From a Kinetic Theory

Sound propagation and the initial value problems in gas mixtures of two components are investigated. By using the eigen theory of linearized Boltzmann equations, a model equations is formed, with the use of the Fourier-Laplace transform for model equations derived, the dispersion relations for both components are obtained.

Vapor-liquid equilibrium properties for confined binary mixtures involving CO_2,CH_4,and N_2 from Gibbs ensemble Monte Carlo simulations

The effects of solid-fluid interactions on the vapor-liquid phase diagram,coexistence density,relative volatility and vaporization enthalpy have been investigated for confined binary systems of CO 2-CH 4,CO 2-N 2 and CH 4-N 2.The Gibbs ensemble Monte Carlo(GEMC) simulation results indicate that the confinement and the solid-fluid interaction have significant influences on the vapor-liquid equilibrium properties.The confinement and the strength of the solid-fluid interaction make the p-x i phase diagram move to higher pressure regions.They also make the two-phase region become narrower for each binary mixture.The strength of the solid-fluid interactions can cause increases in the coexistence liquid and vapor densities,and cause the decrease of the relative volatility and the vaporization enthalpy for the systems studied.As the pore width is decreased,the two-phase region of the binary mixture becomes narrower.

Characteristic of Local Boiling Heat Transfer of Ammonia and Ammonia/Water Binary Mixture on the Plate Type Evaporator

Power generation using small temperature difference such as ocean thermal energy conversion(OTEC)and discharged thermal energy conversion(DTEC)is expected to be the countermeasures against global warming problem.As ammonia and ammonia/water are used in evaporators for OTEC and DTEC as working fluids,the research of their local boiling heat transfer is important for improvement of the power generation efficiency.Measurements of local boiling heat transfer coefficients were performed for ammonia/water mixture(z=0.9-1)on a vertical flat plate heat exchanger in a range of mass flux(7.5-15 kg/m2s),heat flux(15-23 kW/m 2),and pressure(0.7-0.9 MPa).The result shows that in the case of ammonia/water mixture,the local heat transfer coefficients increase with an increase of mass flux and composition of ammonia,and decrease with an increase of heat flux.