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苯酚+乙腈二元系固液相平衡
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作者 欧阳兴旺 车冠全 《广东教育学院学报》 2000年第3期84-86,93,共4页
全浓度范围内测定了 x C6H5OH+(1 -x) CH3CN二元系固液平衡相图 ,此体系形成了摩尔比 1∶ 3的不稳定化合物 CH3CN· (C6H5OH) 3,其转熔温度为 2 80 .55K,体系低共熔点组成和温度分别为 x=0 .1 47,T=2 2 1 .2 8K.转熔点位置在 (0 .72... 全浓度范围内测定了 x C6H5OH+(1 -x) CH3CN二元系固液平衡相图 ,此体系形成了摩尔比 1∶ 3的不稳定化合物 CH3CN· (C6H5OH) 3,其转熔温度为 2 80 .55K,体系低共熔点组成和温度分别为 x=0 .1 47,T=2 2 1 .2 8K.转熔点位置在 (0 .72 8,2 80 .55K) . 展开更多
关键词 相图 平衡 苯酚 乙腈 二元系固液相平衡 氢键
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Solid-Liquid Equilibria of trans-1,2-Cyclohexanediol+Butyl Acetate+ Water Ternary System 被引量:4
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作者 周彩荣 石晓华 +2 位作者 王海峰 高玉国 蒋登高 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2007年第3期449-452,共4页
Using a laser observation technique,the solubilities of trans-1,2-cyclohexanediol in butyl acetate+wa- ter were measured at the temperature range from 298.15K to 323.15K by a synthetic method at atmospheric pres- sure... Using a laser observation technique,the solubilities of trans-1,2-cyclohexanediol in butyl acetate+wa- ter were measured at the temperature range from 298.15K to 323.15K by a synthetic method at atmospheric pres- sure.It is shown that the solubilities of trans-1,2-cyclohexanediol in butyl acetate+water were affected greatly by the proportion of butyl acetate and water,and presented maximum value at given temperature.The UNIFAC model was used to correlate the experimental data.The average relative deviation(ARD)between experimental and calculated values is 3.03%. 展开更多
关键词 trans-1 2-cyclohexanediol solid-liquid equilibria laser monitoring technique SOLUBILITY UNIFAC
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