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甲基丙烯酸/丙烯酰胺双单体共聚反蛋白石光子晶体的制备 被引量:2
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作者 傅小勤 郭明 +1 位作者 武嘉 战胜鑫 《化学学报》 SCIE CAS CSCD 北大核心 2012年第5期611-616,共6页
以烧结后的二氧化硅光子晶体为模板,采用溶胶凝胶法向模板间隙填充以甲基丙烯酸(MAA)和丙烯酰胺(AM)为双功能单体,N,N'-亚甲基双丙烯酰胺(BIS)为交联剂的聚合物前驱液,制备了甲基丙烯酸/丙烯酰胺共聚(PMAM)双单体反蛋白石凝胶光子晶... 以烧结后的二氧化硅光子晶体为模板,采用溶胶凝胶法向模板间隙填充以甲基丙烯酸(MAA)和丙烯酰胺(AM)为双功能单体,N,N'-亚甲基双丙烯酰胺(BIS)为交联剂的聚合物前驱液,制备了甲基丙烯酸/丙烯酰胺共聚(PMAM)双单体反蛋白石凝胶光子晶体.通过紫外可见光谱分析表明,反蛋白石结构的凝胶膜对pH响应范围在4.0~7.0之间.由于其不受离子强度的影响,除了可以作为pH传感器外,还可以作为金属离子及生物小分子等分子印迹光子晶体传感器的基体膜. 展开更多
关键词 二氧化硅光子晶体 反蛋白石光子晶体 垂直沉积 烧结
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High-quality SiO_2 Colloidal Crystal Fabricated by Controllable Vertical Deposition Method
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作者 CAI Xiao-mei CHEN Fu-yi JIE Wan-qi 《Semiconductor Photonics and Technology》 CAS 2006年第2期95-99,共5页
Monodispersed silica microspheres with diameter of 353nm were assembled into photonic crystal in ethanol colloidal suspensions of varied silica volume fraction at different temperature and humidity by means of control... Monodispersed silica microspheres with diameter of 353nm were assembled into photonic crystal in ethanol colloidal suspensions of varied silica volume fraction at different temperature and humidity by means of controllable vertical deposition method. The surface morphology and optical properties were studied by SEM and UV-Vis-NIR. It was found that the high-quality silica colloidal photonic crystals were obtained from ethanol solutions with environment temperature between 45℃ and 55℃, humidity between 66% and 76%, the volume fraction of microspheres is between 0.8% and 1.5%. The ordered close-packed photonic crystal fabricated by controllable vertical deposition method had the two photonic bandgaps in the visible light band and near infrared band. 展开更多
关键词 Photonic crystals Silica colloidal crystals Controllable vertical deposition Photonic bandgap
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