The total internal partition sums （TIPS） are calculated at the temperature up to 6000 K for 12 C16 02. Using the calculated partition functions, we produce the line intensities of v3 band of 12C1602 at several high ...The total internal partition sums （TIPS） are calculated at the temperature up to 6000 K for 12 C16 02. Using the calculated partition functions, we produce the line intensities of v3 band of 12C1602 at several high temperatures. The results show that the calculated line intensities are in very good agreement with those of HITRAN database at the temperature up to 3000 K, which provides a strong support for the calculations of TIPS and line intensities at high temperature. Then the calculation is extended to further high temperature, and the simulated spectra of u3 band of 12C1602 at 5000 and 6000 K are reported.展开更多
Three pillar-layered metal-organic frameworks（MOFs） based on M（HBTC）（4,4＇-bipy）.3DMF（M =Ni, Co, and Zn; HBTC = 1,3,5-benzenetricarboxylic acid, 4,4＇-bipy = 4,4′-bipyridine） were synthesized using a solvothe...Three pillar-layered metal-organic frameworks（MOFs） based on M（HBTC）（4,4＇-bipy）.3DMF（M =Ni, Co, and Zn; HBTC = 1,3,5-benzenetricarboxylic acid, 4,4＇-bipy = 4,4′-bipyridine） were synthesized using a solvothermal method. Zn（HBTC）（4,4＇-bipy）.3DMF was synthesized for the first time using both a solvothermal and microwave method, and subsequently characterized by various physicochemical methods. The structure of M（HBTC）（4,4＇-bipy）.3DMF consisted of honeycomb grid layers of M2＋ ions and BTC units, which were further linked by the 4,4＇-bipy pillars to form a three-dimensional highly porous framework. All the MOFs displayed excellent synergistic catalytic properties with alkyl ammonium halides（TBAX） in the solventless fixation of CO_2 with epoxides to produce cyclic carbonates. The catalytic activities of these MOFs followed the trend Zn Co Ni,which was explained by the acid-base bifunctional properties. The microwave-synthesized Zn（HBTC）（4,4＇-bipy）.3DMF material exhibited physical, chemical, and catalytic properties that were similar to those of the catalyst obtained using a conventional solvothermal synthesis. The scope of various parameters, including recyclability, was studied, and a plausible reaction mechanism was suggested.展开更多
Theoretical analyses have been performed to describe the coupling losses for a plane mirror in rectangular waveguide resonator for an arbitrary waveguide mode as a function of the Fresnel number for several values of ...Theoretical analyses have been performed to describe the coupling losses for a plane mirror in rectangular waveguide resonator for an arbitrary waveguide mode as a function of the Fresnel number for several values of the aspect ratio by using Fresnel approximation.展开更多
Carbon dioxide （CO2） capture and geological storage （CCS） is one of promising technologies for greenhouse gas effect mitigation. Many geotechnical challenges remain during carbon dioxide storage field practices, a...Carbon dioxide （CO2） capture and geological storage （CCS） is one of promising technologies for greenhouse gas effect mitigation. Many geotechnical challenges remain during carbon dioxide storage field practices, among which effectively detecting CO2 from deep underground is one of engineering problems. This paper reviews monitoring techniques currently used during CO2 injection and storage. A method developed based on measuring seismic microtremors is of main interest. This method was first successfully used to characterize a site in this paper. To explore its feasibility in C02 storage monitoring, numerical simulations were conducted to investigate detectable changes in elastic wave signatures due to injection and geological storage of CO2. It is found that, although it is effective for shallow earth profile estimation, the surface wave velocity is not sensitive to the CO2 layer physical parameter variations,especially for a thin CO2 geological storage layer in a deep underground reservoir.展开更多
How would typhoon activity over the western North Pacific change for various scenarios of future global warming?Using the model projections of the Coupled Model Intercomparison Project phase 3(CMIP 3)under the SRES A1...How would typhoon activity over the western North Pacific change for various scenarios of future global warming?Using the model projections of the Coupled Model Intercomparison Project phase 3(CMIP 3)under the SRES A1B scenario,we generated summer(September)ice-free Arctic conditions,also referred to as Blue Arctic conditions,and then used the corresponding monthly sea surface temperature(SST)and a set of CO2concentrations to drive an AGCM model to simulate the resulting changes in background conditions affecting typhoon activity over the western North Pacific.Our results show that,during typhoon season(June to October),atmospheric and ocean circulations over the western North Pacific would be significantly different from the present circulations.Changes in the vertical shear of zonal wind and outgoing longwave radiation(OLR)in the western North Pacific are favorable for westward and northward shift,respectively,of the location of typhoon genesis.Moreover,changes in the above fields over the key area may be conducive to less frequent typhoons.In addition,the tropical cyclone genesis potential index(GPI)over the western North Pacific would decrease(increase)east(west)of 150°E(140°E).展开更多
基金The project supported by National Natural Science Foundation of China under Grant No. 10676025, and the Research Fund for the Doctoral Program of High Education of China under Grant No. 20050610010
文摘The total internal partition sums （TIPS） are calculated at the temperature up to 6000 K for 12 C16 02. Using the calculated partition functions, we produce the line intensities of v3 band of 12C1602 at several high temperatures. The results show that the calculated line intensities are in very good agreement with those of HITRAN database at the temperature up to 3000 K, which provides a strong support for the calculations of TIPS and line intensities at high temperature. Then the calculation is extended to further high temperature, and the simulated spectra of u3 band of 12C1602 at 5000 and 6000 K are reported.
文摘Three pillar-layered metal-organic frameworks（MOFs） based on M（HBTC）（4,4＇-bipy）.3DMF（M =Ni, Co, and Zn; HBTC = 1,3,5-benzenetricarboxylic acid, 4,4＇-bipy = 4,4′-bipyridine） were synthesized using a solvothermal method. Zn（HBTC）（4,4＇-bipy）.3DMF was synthesized for the first time using both a solvothermal and microwave method, and subsequently characterized by various physicochemical methods. The structure of M（HBTC）（4,4＇-bipy）.3DMF consisted of honeycomb grid layers of M2＋ ions and BTC units, which were further linked by the 4,4＇-bipy pillars to form a three-dimensional highly porous framework. All the MOFs displayed excellent synergistic catalytic properties with alkyl ammonium halides（TBAX） in the solventless fixation of CO_2 with epoxides to produce cyclic carbonates. The catalytic activities of these MOFs followed the trend Zn Co Ni,which was explained by the acid-base bifunctional properties. The microwave-synthesized Zn（HBTC）（4,4＇-bipy）.3DMF material exhibited physical, chemical, and catalytic properties that were similar to those of the catalyst obtained using a conventional solvothermal synthesis. The scope of various parameters, including recyclability, was studied, and a plausible reaction mechanism was suggested.
文摘Theoretical analyses have been performed to describe the coupling losses for a plane mirror in rectangular waveguide resonator for an arbitrary waveguide mode as a function of the Fresnel number for several values of the aspect ratio by using Fresnel approximation.
基金the financial supports from the State Key Laboratory for Geomechanics & Deep Underground Engineering, China University of Mining and Technology (No. SKLGDUEK1002)the Fundamental Research Funds for the Central Government Supported Universities of Tongji University, China (No. 0270219037)
文摘Carbon dioxide （CO2） capture and geological storage （CCS） is one of promising technologies for greenhouse gas effect mitigation. Many geotechnical challenges remain during carbon dioxide storage field practices, among which effectively detecting CO2 from deep underground is one of engineering problems. This paper reviews monitoring techniques currently used during CO2 injection and storage. A method developed based on measuring seismic microtremors is of main interest. This method was first successfully used to characterize a site in this paper. To explore its feasibility in C02 storage monitoring, numerical simulations were conducted to investigate detectable changes in elastic wave signatures due to injection and geological storage of CO2. It is found that, although it is effective for shallow earth profile estimation, the surface wave velocity is not sensitive to the CO2 layer physical parameter variations,especially for a thin CO2 geological storage layer in a deep underground reservoir.
基金supported by the National Basic Research Program of China (Grant No. 2012CB955401)the National Natural Science Foundation of China (Grant No. 41130103)Norwegian Research Council project "East-Asia DecCen"
文摘How would typhoon activity over the western North Pacific change for various scenarios of future global warming?Using the model projections of the Coupled Model Intercomparison Project phase 3(CMIP 3)under the SRES A1B scenario,we generated summer(September)ice-free Arctic conditions,also referred to as Blue Arctic conditions,and then used the corresponding monthly sea surface temperature(SST)and a set of CO2concentrations to drive an AGCM model to simulate the resulting changes in background conditions affecting typhoon activity over the western North Pacific.Our results show that,during typhoon season(June to October),atmospheric and ocean circulations over the western North Pacific would be significantly different from the present circulations.Changes in the vertical shear of zonal wind and outgoing longwave radiation(OLR)in the western North Pacific are favorable for westward and northward shift,respectively,of the location of typhoon genesis.Moreover,changes in the above fields over the key area may be conducive to less frequent typhoons.In addition,the tropical cyclone genesis potential index(GPI)over the western North Pacific would decrease(increase)east(west)of 150°E(140°E).
