[目的]随着新能源的大规模应用,新能源发电并网面临的挑战不断突显,储能系统的重要性日益上升。二氧化碳储能(Carbon Dioxide Energy Storage,CES)技术是近年来兴起的一种压缩气体储能技术,具有储能密度大、寿命长、系统设计灵活等优势...[目的]随着新能源的大规模应用,新能源发电并网面临的挑战不断突显,储能系统的重要性日益上升。二氧化碳储能(Carbon Dioxide Energy Storage,CES)技术是近年来兴起的一种压缩气体储能技术,具有储能密度大、寿命长、系统设计灵活等优势。其中液态二氧化碳储能(Liquid Carbon Dioxide Energy Storage,LCES)技术在系统高压侧和低压侧均采用液相存储二氧化碳,储能密度高、运行稳定性强。[方法]文章首先介绍了LCES系统的运行原理和关键技术指标,指出二氧化碳液化的重要性和常见工艺。然后介绍了针对LCES系统低压侧CO_(2)液化的研究现状,包括采用混合储能工质、自冷凝、利用LNG冷能、采用蓄冷器,详细分析了各种方式的特点。[结果]研究表明,采用蓄冷器是最具优势的方式。进一步分析蓄冷液化面临的技术挑战及发展前景具有必要性。[结论]研究为LCES系统CO_(2)液化技术的进一步发展提供了指导。展开更多
Permeabilities and selectivities of gases such as carbon dioxide （CO2）, sulfur dioxide （SO2）, nitrogen （N2） and methane （CH4） in six imidazolium-based ionic liquids （[emim][BF4], [bmim][BF4], [bmim][PF6], [ba...Permeabilities and selectivities of gases such as carbon dioxide （CO2）, sulfur dioxide （SO2）, nitrogen （N2） and methane （CH4） in six imidazolium-based ionic liquids （[emim][BF4], [bmim][BF4], [bmim][PF6], [banim][BF4], [bmim][Tf2N] and [emim][CF3SO3]） supported on polyethersulfone microfiltration membranes are investigated in a single gas feed system using nitrogen as the environment and reference component at temperature from 25 to 45℃ and pressure of N2 from 100 to 400 kPa. It is found that SO2 has the highest permeability in the tested supported ionic liquid membranes, being an order of magnitude higher than that of CO2, and about 2 to 3 orders of magnitude larger than those of N2 and CH4. The observed selectivity of SO2 over the two ordinary gas components is also striking. It is shown experimentally that the dissolution and transport of gas components in the supported ionic liquid membranes, as well as the nature of ionic liquids play important roles in the gas permeation. A nonlinear increase of permeation rate with temperature and operation pressure is also observed for all sample gases. By considering the factors that influence the permeabilities and selectivities of CO2 and SO2, it is expected to develop an optimal supported ionic liquid membrane technology for the isolation of acidic gases in the near future.展开更多
Utilization of carbon dioxide(CO_(2))has become a crucial and anticipated solution to address environmental and ecological issues.Enzymes such as carbonic anhydrase(CA)can efficiently convert CO_(2) into various platf...Utilization of carbon dioxide(CO_(2))has become a crucial and anticipated solution to address environmental and ecological issues.Enzymes such as carbonic anhydrase(CA)can efficiently convert CO_(2) into various platform chemicals under ambient conditions,which offers a promising way for CO_(2) utilization.Herein,we constructed a Pickering interfacial biocatalytic system(PIBS)stabilized by CA‐embedded MOFs(ZIF‐8 and ZIF‐L)for CO_(2) mineralization.Through structure engineering of MOFs and incorporation of Pickering emulsion,the internal and external diffusion processes of CO_(2) during the enzymatic mineralization were greatly intensified.When CO_(2) was ventilated at a flow rate of 50 mL min^(–1) for 1 h,the pH value of PIBS dropped from~8.00 to~6.50,while the average pH value of free system only dropped to~7.15,indicating that the initial reaction rate of CO_(2) mineralization of PIBS is nearly twice that of the free system.After the 8^(th) cycle reaction,PIBS can still produce more than 9.8 mg of CaCO_(3) in 5 min,realizing efficient and continuous mineralization of CO_(2).展开更多
文摘[目的]随着新能源的大规模应用,新能源发电并网面临的挑战不断突显,储能系统的重要性日益上升。二氧化碳储能(Carbon Dioxide Energy Storage,CES)技术是近年来兴起的一种压缩气体储能技术,具有储能密度大、寿命长、系统设计灵活等优势。其中液态二氧化碳储能(Liquid Carbon Dioxide Energy Storage,LCES)技术在系统高压侧和低压侧均采用液相存储二氧化碳,储能密度高、运行稳定性强。[方法]文章首先介绍了LCES系统的运行原理和关键技术指标,指出二氧化碳液化的重要性和常见工艺。然后介绍了针对LCES系统低压侧CO_(2)液化的研究现状,包括采用混合储能工质、自冷凝、利用LNG冷能、采用蓄冷器,详细分析了各种方式的特点。[结果]研究表明,采用蓄冷器是最具优势的方式。进一步分析蓄冷液化面临的技术挑战及发展前景具有必要性。[结论]研究为LCES系统CO_(2)液化技术的进一步发展提供了指导。
基金Supported by the National Natural Science Foundation of China （20776065）, the Natural Science Foundation of Jiangsu Province （BK2008023）, and the National Found for Fostering Talents of Basic Science 00630425）.
文摘Permeabilities and selectivities of gases such as carbon dioxide （CO2）, sulfur dioxide （SO2）, nitrogen （N2） and methane （CH4） in six imidazolium-based ionic liquids （[emim][BF4], [bmim][BF4], [bmim][PF6], [banim][BF4], [bmim][Tf2N] and [emim][CF3SO3]） supported on polyethersulfone microfiltration membranes are investigated in a single gas feed system using nitrogen as the environment and reference component at temperature from 25 to 45℃ and pressure of N2 from 100 to 400 kPa. It is found that SO2 has the highest permeability in the tested supported ionic liquid membranes, being an order of magnitude higher than that of CO2, and about 2 to 3 orders of magnitude larger than those of N2 and CH4. The observed selectivity of SO2 over the two ordinary gas components is also striking. It is shown experimentally that the dissolution and transport of gas components in the supported ionic liquid membranes, as well as the nature of ionic liquids play important roles in the gas permeation. A nonlinear increase of permeation rate with temperature and operation pressure is also observed for all sample gases. By considering the factors that influence the permeabilities and selectivities of CO2 and SO2, it is expected to develop an optimal supported ionic liquid membrane technology for the isolation of acidic gases in the near future.
文摘Utilization of carbon dioxide(CO_(2))has become a crucial and anticipated solution to address environmental and ecological issues.Enzymes such as carbonic anhydrase(CA)can efficiently convert CO_(2) into various platform chemicals under ambient conditions,which offers a promising way for CO_(2) utilization.Herein,we constructed a Pickering interfacial biocatalytic system(PIBS)stabilized by CA‐embedded MOFs(ZIF‐8 and ZIF‐L)for CO_(2) mineralization.Through structure engineering of MOFs and incorporation of Pickering emulsion,the internal and external diffusion processes of CO_(2) during the enzymatic mineralization were greatly intensified.When CO_(2) was ventilated at a flow rate of 50 mL min^(–1) for 1 h,the pH value of PIBS dropped from~8.00 to~6.50,while the average pH value of free system only dropped to~7.15,indicating that the initial reaction rate of CO_(2) mineralization of PIBS is nearly twice that of the free system.After the 8^(th) cycle reaction,PIBS can still produce more than 9.8 mg of CaCO_(3) in 5 min,realizing efficient and continuous mineralization of CO_(2).
