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二氧化钛/碳纳米管复合催化剂的制备及生物法-光催化处理酒精废水研究
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作者 朱军 李雪莲 +1 位作者 许冬冬 李晓玲 《宿州学院学报》 2015年第12期102-106,共5页
采用溶胶-凝胶法,以钛酸四丁酯为前驱体,通过调节TiO_2/CNTs质量百分比(2%、3%、4%),制备二氧化钛/碳纳米管(TiO_2/CNTs)复合催化剂;在不同焙烧温度下处理复合催化剂,并利用X射线衍射仪(XRD)、红外光谱(FT-IR)、扫描电子显微镜(SEM)对... 采用溶胶-凝胶法,以钛酸四丁酯为前驱体,通过调节TiO_2/CNTs质量百分比(2%、3%、4%),制备二氧化钛/碳纳米管(TiO_2/CNTs)复合催化剂;在不同焙烧温度下处理复合催化剂,并利用X射线衍射仪(XRD)、红外光谱(FT-IR)、扫描电子显微镜(SEM)对复合催化剂进行表征。先用生物法处理酒精废水,然后在可见光照射下,考察复合催化剂在不同条件下对酒精废水降解效果的影响。结果表明:在500℃下,TiO_2/CNTs质量百分比约3%时,复合催化剂锐钛矿相比例最高;在光照时间为50min、pH=4、复合催化剂用量0.6g时,复合催化剂对酒精废水COD降解率最高。 展开更多
关键词 溶胶-凝胶法 二氧化钛/碳纳米管 生物法 光催化 酒精废水
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Photocatalytic Degradation of Phenol over MWCNTs-TiO2 Composite Catalysts with Different Diameters
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作者 李晨 汪文栋 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2009年第4期423-428,448,共7页
Titania-based composite catalysts were prepared through a sol-gel route employing multi-walled carbon nanotubes with different diameters. The materials were characterized using thermogravimetric analysis, nitrogen ads... Titania-based composite catalysts were prepared through a sol-gel route employing multi-walled carbon nanotubes with different diameters. The materials were characterized using thermogravimetric analysis, nitrogen adsorption-desorption isotherm, powder X-ray diffraction, scanning electron microscopy, and diffuse reflectance UV-Vis absorption spectra. The application of the catalysts to photocatalytic degradation of phenol was tested under UV-Vis irradiation. A synergetic effect on phenol removal was observed in case of composite catalysts, which was evaluated in terms of apparent rate constant, total organic carbon removal and photonic efficiency. 展开更多
关键词 Photocatalytic degradation PHENOL Titanium dioxide Multi-walled carbon nanotube Composite catalyst
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