Vapor-liquid equilibrium (VLE) for a ternary system of methyldichlorosilane + methylvinyldichlorosi-lane + toluene and constituent binary systems were measured at 101.3kPa using a new type of magnetical pump-ebulliome...Vapor-liquid equilibrium (VLE) for a ternary system of methyldichlorosilane + methylvinyldichlorosi-lane + toluene and constituent binary systems were measured at 101.3kPa using a new type of magnetical pump-ebulliometer. The equilibrium compositions of the vapor phase of binary systems were calculated indirectly from the total pressure-temperature-liquid composition (pTx). The experimental data were correlated with the Wilson and NRTL(non-random two liquid) equations. The parameters of the Wilson model were employed to predict the ternary VLE data. The calculated boiling points were in good agreement with the experimental ones.展开更多
Sixteen surface sediment samples were collected and analysed to evaluate the residues of organochlorine pesticides （OCPs） from intertidal fiat in Jiangsu Province. Overall, 22 OCPs were detected with total concentra...Sixteen surface sediment samples were collected and analysed to evaluate the residues of organochlorine pesticides （OCPs） from intertidal fiat in Jiangsu Province. Overall, 22 OCPs were detected with total concentrations of OCPs ranging widely from 0.96 to 12.14 ng/g （dry wt）. Total hexachlorocyclohexane （HCH） and total dichlorodiphenyltrichloroethane （DDT） levels varied from 〈0.01 to 0.67 ng/g and from 0.23 to 4.85 ng/g, respectively. DDTs were the predominant compounds. The dominance of β-HCH indicated a history of HCH pollution. According to the ratios of （p,p＇-DDD＋p,p＇-DDE）/p,p＇DDT and o,p＇-DDT/p,p＇- DDT, new input of DDTs did not occur in most sites, and the main sources were historical usage of technical DDTs. OCPs such as dieldrin, endrin, p,p＇-DDD, and p,p＇-DDT exceeded the effects range low, showing adverse biological effects that would occasionally occur at some sites of the study area.展开更多
基金Supported by the Natural Science Foundation of Jiangxi Province(No.0020019).
文摘Vapor-liquid equilibrium (VLE) for a ternary system of methyldichlorosilane + methylvinyldichlorosi-lane + toluene and constituent binary systems were measured at 101.3kPa using a new type of magnetical pump-ebulliometer. The equilibrium compositions of the vapor phase of binary systems were calculated indirectly from the total pressure-temperature-liquid composition (pTx). The experimental data were correlated with the Wilson and NRTL(non-random two liquid) equations. The parameters of the Wilson model were employed to predict the ternary VLE data. The calculated boiling points were in good agreement with the experimental ones.
基金Supported by the National Natural Science Foundation of China(Nos.40871216,41271466)
文摘Sixteen surface sediment samples were collected and analysed to evaluate the residues of organochlorine pesticides （OCPs） from intertidal fiat in Jiangsu Province. Overall, 22 OCPs were detected with total concentrations of OCPs ranging widely from 0.96 to 12.14 ng/g （dry wt）. Total hexachlorocyclohexane （HCH） and total dichlorodiphenyltrichloroethane （DDT） levels varied from 〈0.01 to 0.67 ng/g and from 0.23 to 4.85 ng/g, respectively. DDTs were the predominant compounds. The dominance of β-HCH indicated a history of HCH pollution. According to the ratios of （p,p＇-DDD＋p,p＇-DDE）/p,p＇DDT and o,p＇-DDT/p,p＇- DDT, new input of DDTs did not occur in most sites, and the main sources were historical usage of technical DDTs. OCPs such as dieldrin, endrin, p,p＇-DDD, and p,p＇-DDT exceeded the effects range low, showing adverse biological effects that would occasionally occur at some sites of the study area.
