Efficient charge separation and rapid interfacial reaction kinetics are crucial factors that determine the efficiency of photocatalytic hydrogen evolution.Herein,a fascinating 2D heterojunction photocatalyst with supe...Efficient charge separation and rapid interfacial reaction kinetics are crucial factors that determine the efficiency of photocatalytic hydrogen evolution.Herein,a fascinating 2D heterojunction photocatalyst with superior photocatalytic hydrogen evolution performance–holey C_(3)N_(4)nanosheets nested with TiO_(2)nanocrystals(denoted as HCN/TiO_(2))–is designed and fabricated via an in situ exfoliation and conversion strategy.The HCN/TiO_(2)is found to exhibit an ultrathin 2D heteroarchitecture with intimate interfacial contact,highly porous structures and ultrasmall TiO_(2)nanocrystals,leading to drastically improved charge carrier separation,maximized active sites and the promotion of mass transport for photocatalysis.Consequently,the HCN/TiO_(2)delivers an impressive hydrogen production rate of 282.3 lmol h^(-1)per10 mg under AM 1.5 illumination and an apparent quantum efficiency of 13.4%at a wavelength of 420 nm due to the synergetic enhancement of surface reactions and charge separation.The present work provides a promising strategy for developing high-performance 2D heterojunctions for clean energy applications.展开更多
With the development of the global economy, interaction among different economic entities from one region is intensifying, which makes it significant to consider such interaction when constructing composite index for ...With the development of the global economy, interaction among different economic entities from one region is intensifying, which makes it significant to consider such interaction when constructing composite index for each country from one region. Recent advances in signal extraction and time series analysis have made such consideration feasible and practical. Singular spectrum analysis （SSA） is a well-developed technique for time series analysis and proven to be a powerful tool for signal extraction. The present study aims to introduce the usage of the SSA technique for multi-country business cycle analysis. The multivariate SSA （MSSA） is employed to construct a model-based composite index and the two dimensional SSA （2D-SSA） is employed to establish the multi-country composite index. Empirical results performed on Chinese economy demonstrate the accuracy and stability of MSSA-based composite index, and the 2D-SSA based composite indices for Asian countries confirm the efficiency of the technique in capturing the interaction among different countries.展开更多
A novel extended traction boundary element-free method is proposed to analyze the crack problems of two-dimensional infinite magnetoelectroelastic solid.An extended traction boundary integral equation only involving C...A novel extended traction boundary element-free method is proposed to analyze the crack problems of two-dimensional infinite magnetoelectroelastic solid.An extended traction boundary integral equation only involving Cauchy singularity is firstly derived.Then,the extended dislocation densities on the crack surface are expressed as the combination of a characteristic term and unknown weight functions,and the radial point interpolation method is adopted to approximate the unknown weight functions.The numerical scheme of the extended traction boundary element-free method is further established,and an effective numerical procedure is used to evaluate the Cauchy singular integrals.Finally,the stress intensity factor,electric displacement intensity factor and magnetic induction intensity factor are computed for some selected crack problems that contain straight,curved and branched cracks,and good numerical results are obtained.At the same time,the fracture properties of these crack problems are discussed.展开更多
基金the National Key R&D Program of China(2018YFE0201704 and 2018YFE0201701)the National Natural Science Foundation of China(21673256,21533011,2163100,and 21603036)Shanghai Rising-Star Program.
文摘Efficient charge separation and rapid interfacial reaction kinetics are crucial factors that determine the efficiency of photocatalytic hydrogen evolution.Herein,a fascinating 2D heterojunction photocatalyst with superior photocatalytic hydrogen evolution performance–holey C_(3)N_(4)nanosheets nested with TiO_(2)nanocrystals(denoted as HCN/TiO_(2))–is designed and fabricated via an in situ exfoliation and conversion strategy.The HCN/TiO_(2)is found to exhibit an ultrathin 2D heteroarchitecture with intimate interfacial contact,highly porous structures and ultrasmall TiO_(2)nanocrystals,leading to drastically improved charge carrier separation,maximized active sites and the promotion of mass transport for photocatalysis.Consequently,the HCN/TiO_(2)delivers an impressive hydrogen production rate of 282.3 lmol h^(-1)per10 mg under AM 1.5 illumination and an apparent quantum efficiency of 13.4%at a wavelength of 420 nm due to the synergetic enhancement of surface reactions and charge separation.The present work provides a promising strategy for developing high-performance 2D heterojunctions for clean energy applications.
基金supported by the National Science Foundation of China under Grant No.71101142Presidential Award of Chinese Academy of Sciences
文摘With the development of the global economy, interaction among different economic entities from one region is intensifying, which makes it significant to consider such interaction when constructing composite index for each country from one region. Recent advances in signal extraction and time series analysis have made such consideration feasible and practical. Singular spectrum analysis （SSA） is a well-developed technique for time series analysis and proven to be a powerful tool for signal extraction. The present study aims to introduce the usage of the SSA technique for multi-country business cycle analysis. The multivariate SSA （MSSA） is employed to construct a model-based composite index and the two dimensional SSA （2D-SSA） is employed to establish the multi-country composite index. Empirical results performed on Chinese economy demonstrate the accuracy and stability of MSSA-based composite index, and the 2D-SSA based composite indices for Asian countries confirm the efficiency of the technique in capturing the interaction among different countries.
基金supported by the National Natural Science Foundation of China (10772123,11072160)Natural Science Foundation for Outstanding Young People of Hebei Province (A2009001624),China
文摘A novel extended traction boundary element-free method is proposed to analyze the crack problems of two-dimensional infinite magnetoelectroelastic solid.An extended traction boundary integral equation only involving Cauchy singularity is firstly derived.Then,the extended dislocation densities on the crack surface are expressed as the combination of a characteristic term and unknown weight functions,and the radial point interpolation method is adopted to approximate the unknown weight functions.The numerical scheme of the extended traction boundary element-free method is further established,and an effective numerical procedure is used to evaluate the Cauchy singular integrals.Finally,the stress intensity factor,electric displacement intensity factor and magnetic induction intensity factor are computed for some selected crack problems that contain straight,curved and branched cracks,and good numerical results are obtained.At the same time,the fracture properties of these crack problems are discussed.
