The shear-induced migration of neutrally-buoyant non-colloidal circular particles in a two-dimensional circular Couette flow is investigated numerically with a distributed Lagrange multiplier based fictitious domain m...The shear-induced migration of neutrally-buoyant non-colloidal circular particles in a two-dimensional circular Couette flow is investigated numerically with a distributed Lagrange multiplier based fictitious domain method.The effects of inertia and volume fraction on the particle migration are examined.The results indicate that inertia has a negative effect on the particle migration.In consistence with the experimental observations,the rapid migration of particles near the inner cylinder at the early stage is observed in the simulation,which is believed to be related to the chain-like clustering of particles.The migration of circular particles in a plane Poiseuille flow is also examined in order to further confirm the effect of such clustering on the particle migration at early stage.There is tendency for the particles in the vicinity of outer cylinder in the Couette device to pack into concentric rings at late stage in case of high particle concentration.展开更多
A practical approach of measurement calibration is presented for obtaining the true area of the photographed objects projected in the 2-D image scene. The calibration is performed using three circular samples with giv...A practical approach of measurement calibration is presented for obtaining the true area of the photographed objects projected in the 2-D image scene. The calibration is performed using three circular samples with given diameters. The process is first to obtain the ratio mm/pixel in two orthogonal directions, and then use the obtained ratios with the total number of pixels scanned within projected area of the object of interest to compute the desired area. Compared the optically measured areas with their corresponding true areas, the results show that the proposed method is quite encouraging and the relevant application also proves the approach adequately accurate.展开更多
The signals of 1H NMR and 13 C NMR for benzodiheteropine 1 and its cycloaddtion products 2～5 were assigned by two dimensional NMR techniques. The characteristics of their structures were analyzed and ...The signals of 1H NMR and 13 C NMR for benzodiheteropine 1 and its cycloaddtion products 2～5 were assigned by two dimensional NMR techniques. The characteristics of their structures were analyzed and discussed. The boat conformation of the seven membered heteroatomic ring in these structures was interpreted on the basis of the spectrum of NOESY as well. The coupling constants of relative protons were in accord with above results.展开更多
During range-based self-localization of Wireless Sensor Network (WSN) nodes, the number and placement methods of beacon nodes have a great influence on the accuracy of localization. This paper proves a theorem which d...During range-based self-localization of Wireless Sensor Network (WSN) nodes, the number and placement methods of beacon nodes have a great influence on the accuracy of localization. This paper proves a theorem which describes the relationship between the placement of beacon nodes and whether the node can be located in 3D indoor environment. In fact, as the highest locating accuracy can be acquired when the beacon nodes form one or more equilateral triangles in 2D plane, we generalizes this conclusion to 3D space, and proposes a beacon nodes selection algorithm based on the minimum condition number to get the higher locating accuracy, which can minimize the influence of distance measurement error. Simulation results show that the algorithm is effective and feasible.展开更多
Equilibrium photoproduct of 7r-cyclopentadienyliron dicarbonyl dimer [CpFe（CO）2]2 in non- polar solvent carbon tetrachloride （CC14） is investigated using time-resolved 2D IR spec- troscopy. One of the several poss...Equilibrium photoproduct of 7r-cyclopentadienyliron dicarbonyl dimer [CpFe（CO）2]2 in non- polar solvent carbon tetrachloride （CC14） is investigated using time-resolved 2D IR spec- troscopy. One of the several possible visible-light-driven photoreaction pathways is confirmed and the product is found to contain a di-carbonyl group that exhibits quantum beating be- tween two equivalent transitions in time-resolved 2D IR spectra, which turns out to be the anti-symmetric and symmetric stretching of the terminal carbonyl stretching modes of CpFe（CO）2C1. This is the main product and its reaction pathway involves radical formation, followed by chloride addition. Quantum-chemistry computations support these experimental results. Our results indicate that 2D IR method can be used to identify in situ structures and dynamics of chemical species involved in condensed-phase chemical reactions.展开更多
A two dimensional model approach for the photodetachment dynamics of closed shell an-ionic systems in presence of external light field have been proposed in the context of polar environmental media. The effects of str...A two dimensional model approach for the photodetachment dynamics of closed shell an-ionic systems in presence of external light field have been proposed in the context of polar environmental media. The effects of strong coupling between the solvent polarization and the extra charge in the system were studied by a simple model. The electronic states of con-cerned halide ions are represented by a two dimensional model Hamiltonian with a potential V（x,y）=-V0e^-σ（x^2＋y^2）. The time dependent Fourier grid Hamiltonian method have been used to follow the detachment process with fairly high intensities of light. The environmental effects on the dynamics are sought to be modeled by two different ways. The first one was the presence of polar solvents which perturb the energy levels of anionic systems by changing the effective potential surface and the second one was allowing the fluctuation of the well depth randomly to mimic the system in a more realistic view point. The average detachment rate constant is calculated as a function of important parameters of the used light field to explain the effects of solvent field on the dynamical behavior of dipole bound anionic system at least in a qualitative way.展开更多
基金Supported by the National Natural Science Foundation of China （No. 10472104）.
文摘The shear-induced migration of neutrally-buoyant non-colloidal circular particles in a two-dimensional circular Couette flow is investigated numerically with a distributed Lagrange multiplier based fictitious domain method.The effects of inertia and volume fraction on the particle migration are examined.The results indicate that inertia has a negative effect on the particle migration.In consistence with the experimental observations,the rapid migration of particles near the inner cylinder at the early stage is observed in the simulation,which is believed to be related to the chain-like clustering of particles.The migration of circular particles in a plane Poiseuille flow is also examined in order to further confirm the effect of such clustering on the particle migration at early stage.There is tendency for the particles in the vicinity of outer cylinder in the Couette device to pack into concentric rings at late stage in case of high particle concentration.
基金Supported by the National Natural Science Foundation of China (No.60472100).
文摘A practical approach of measurement calibration is presented for obtaining the true area of the photographed objects projected in the 2-D image scene. The calibration is performed using three circular samples with given diameters. The process is first to obtain the ratio mm/pixel in two orthogonal directions, and then use the obtained ratios with the total number of pixels scanned within projected area of the object of interest to compute the desired area. Compared the optically measured areas with their corresponding true areas, the results show that the proposed method is quite encouraging and the relevant application also proves the approach adequately accurate.
文摘The signals of 1H NMR and 13 C NMR for benzodiheteropine 1 and its cycloaddtion products 2～5 were assigned by two dimensional NMR techniques. The characteristics of their structures were analyzed and discussed. The boat conformation of the seven membered heteroatomic ring in these structures was interpreted on the basis of the spectrum of NOESY as well. The coupling constants of relative protons were in accord with above results.
基金Supported by the National Natural Science Foundation of China (No.61003236 61171053)+2 种基金the Doctoral Fund of Ministry of Education of China (No.20113223110002)the Natural Science Major Program for Colleges and Universities in Jiangsu Province (No.11KJA520001)Science & Technology Innovation Fund for higher education institutions of Jiangsu Province (CXZZ12_0481)
文摘During range-based self-localization of Wireless Sensor Network (WSN) nodes, the number and placement methods of beacon nodes have a great influence on the accuracy of localization. This paper proves a theorem which describes the relationship between the placement of beacon nodes and whether the node can be located in 3D indoor environment. In fact, as the highest locating accuracy can be acquired when the beacon nodes form one or more equilateral triangles in 2D plane, we generalizes this conclusion to 3D space, and proposes a beacon nodes selection algorithm based on the minimum condition number to get the higher locating accuracy, which can minimize the influence of distance measurement error. Simulation results show that the algorithm is effective and feasible.
文摘Equilibrium photoproduct of 7r-cyclopentadienyliron dicarbonyl dimer [CpFe（CO）2]2 in non- polar solvent carbon tetrachloride （CC14） is investigated using time-resolved 2D IR spec- troscopy. One of the several possible visible-light-driven photoreaction pathways is confirmed and the product is found to contain a di-carbonyl group that exhibits quantum beating be- tween two equivalent transitions in time-resolved 2D IR spectra, which turns out to be the anti-symmetric and symmetric stretching of the terminal carbonyl stretching modes of CpFe（CO）2C1. This is the main product and its reaction pathway involves radical formation, followed by chloride addition. Quantum-chemistry computations support these experimental results. Our results indicate that 2D IR method can be used to identify in situ structures and dynamics of chemical species involved in condensed-phase chemical reactions.
文摘A two dimensional model approach for the photodetachment dynamics of closed shell an-ionic systems in presence of external light field have been proposed in the context of polar environmental media. The effects of strong coupling between the solvent polarization and the extra charge in the system were studied by a simple model. The electronic states of con-cerned halide ions are represented by a two dimensional model Hamiltonian with a potential V（x,y）=-V0e^-σ（x^2＋y^2）. The time dependent Fourier grid Hamiltonian method have been used to follow the detachment process with fairly high intensities of light. The environmental effects on the dynamics are sought to be modeled by two different ways. The first one was the presence of polar solvents which perturb the energy levels of anionic systems by changing the effective potential surface and the second one was allowing the fluctuation of the well depth randomly to mimic the system in a more realistic view point. The average detachment rate constant is calculated as a function of important parameters of the used light field to explain the effects of solvent field on the dynamical behavior of dipole bound anionic system at least in a qualitative way.
