We experimentally demonstrate a long-term stable two-dimensional saturable absorption material under ambient conditions—multi-layer antimonene feasible for the mid-infrared spectral region—for the first time to our ...We experimentally demonstrate a long-term stable two-dimensional saturable absorption material under ambient conditions—multi-layer antimonene feasible for the mid-infrared spectral region—for the first time to our knowledge. The multi-layer antimonene material prepared using a liquid-phase exfoliation method was coated on a quartz/Ca F_2 for characterizations and an Au mirror as a reflection-type saturable absorber(SA) device. It has a modulation depth of 10.5%, a saturation peak intensity of 0.26 GW∕cm^2, and a non-saturation loss of 19.1% measured at 2868.0 nm using the typical power-dependent method. By introducing the SA device into a linear-cavity Ho^(3+)∕ Pr^(3+)-codoped fluoride fiber laser at 2865.0 nm, stable Q-switched pulses were obtained. It generated a maximum output power of 112.3 m W and pulse energy of 0.72 μJ, while the shortest pulse duration and largest repetition rate were 1.74 μs and 156.2 k Hz, respectively. The long-term stability of the SA device was also checked using the same laser setup within 28 days. The results indicate that multi-layer antimonene is a type of promising long-term stable SA material under ambient conditions that can be applied in the mid-infrared spectral region.展开更多
A numerical model of two-dimensional soil water movement under surface drip irrigation condition was developed. The physical process of soil water movement is described by 2D Richards equation,and the upper boundary c...A numerical model of two-dimensional soil water movement under surface drip irrigation condition was developed. The physical process of soil water movement is described by 2D Richards equation,and the upper boundary condition is depicted by the improved moving ponded area boundary. The partial differential equation(PDE) is transformed into ordinary differential equations(ODEs) through spatial semi-discretization and numerically solved by an ordinary differential equation solver(CVODE) . The numerical and field experiments indicate the good performance of the model in terms of accuracy and efficiency. The model provides a useful tool for long-term simulation of soil water movement under surface drip irrigation. Also,the model can serve as a general 2D Richards equation solver for variably saturated soil water movement,which is named as TIVS model(Tsinghua Integrated Variably Saturated soil water movement model).展开更多
The saturated hydrocarbon fraction of a heavily biodegraded crude oil from Liaohe oilfield was analyzed by using comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry (GC×...The saturated hydrocarbon fraction of a heavily biodegraded crude oil from Liaohe oilfield was analyzed by using comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry (GC×GC-TOFMS). The "humps", which was termed as unresolved complex mixtures (UCMs) in conventional gas chromatographic analysis, was separated for identification of the individual compound. Main compounds of UCMs were identified according to the combined information of characteristics of GC×GC chromatogram and time-of-flight mass spectra. It's found that UCMs are mainly composed of great number of ring compounds with extremely low concentration. The ring compounds are separated according to their boiling point diversity in the first dimension column, then to their polarity or ring number variety in the second dimension column. In the sample there are two groups of UCMs, i.e., the first group compounds with boiling point lower that of C24 and the second group compounds with boiling point higher than that of C24. The first group of UCMs mainly consists of monocyclic, bicyclic and tricyclic ring compounds. The first group of UCMs is mainly composed of saturated hydrocarbons, in which the percentage of ring compounds with signal-to-noise ratio above 100 is about 75% of the total quantity of saturated hydrocarbon, while its mass is over 80% of the total saturated hydrocarbon. The second group of UCMs is mainly composed of tetracyclic and pentacyclic ring compounds, in which the percentage of UCM compounds with signal-to-noise ratio over 100 is about 17% of the total quantity of saturated hydrocarbon, and its mass is about 0.5% of the total saturated hydrocarbon. The results of this study are helpful for heavy oil developing and genesis mechanism understanding.展开更多
基金National Natural Science Foundation of China(NSFC)(61722503,61435003,61421002)Open Fund of Science and Technology on Solid-State Laser Laboratory+3 种基金Fundamental Research Funds for the Central Universities(ZYGX2016J068)International Scientific Cooperation Project of Sichuan Province(2017HH0046)National Key R&D Program of China(YS2018YFB110012)Natural Science Foundation of Zhejiang Province(LQ18A040004)
文摘We experimentally demonstrate a long-term stable two-dimensional saturable absorption material under ambient conditions—multi-layer antimonene feasible for the mid-infrared spectral region—for the first time to our knowledge. The multi-layer antimonene material prepared using a liquid-phase exfoliation method was coated on a quartz/Ca F_2 for characterizations and an Au mirror as a reflection-type saturable absorber(SA) device. It has a modulation depth of 10.5%, a saturation peak intensity of 0.26 GW∕cm^2, and a non-saturation loss of 19.1% measured at 2868.0 nm using the typical power-dependent method. By introducing the SA device into a linear-cavity Ho^(3+)∕ Pr^(3+)-codoped fluoride fiber laser at 2865.0 nm, stable Q-switched pulses were obtained. It generated a maximum output power of 112.3 m W and pulse energy of 0.72 μJ, while the shortest pulse duration and largest repetition rate were 1.74 μs and 156.2 k Hz, respectively. The long-term stability of the SA device was also checked using the same laser setup within 28 days. The results indicate that multi-layer antimonene is a type of promising long-term stable SA material under ambient conditions that can be applied in the mid-infrared spectral region.
基金supported by the "Eleventh Five-year Plan" Project (Grant No.2007BAD38B01)
文摘A numerical model of two-dimensional soil water movement under surface drip irrigation condition was developed. The physical process of soil water movement is described by 2D Richards equation,and the upper boundary condition is depicted by the improved moving ponded area boundary. The partial differential equation(PDE) is transformed into ordinary differential equations(ODEs) through spatial semi-discretization and numerically solved by an ordinary differential equation solver(CVODE) . The numerical and field experiments indicate the good performance of the model in terms of accuracy and efficiency. The model provides a useful tool for long-term simulation of soil water movement under surface drip irrigation. Also,the model can serve as a general 2D Richards equation solver for variably saturated soil water movement,which is named as TIVS model(Tsinghua Integrated Variably Saturated soil water movement model).
文摘The saturated hydrocarbon fraction of a heavily biodegraded crude oil from Liaohe oilfield was analyzed by using comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry (GC×GC-TOFMS). The "humps", which was termed as unresolved complex mixtures (UCMs) in conventional gas chromatographic analysis, was separated for identification of the individual compound. Main compounds of UCMs were identified according to the combined information of characteristics of GC×GC chromatogram and time-of-flight mass spectra. It's found that UCMs are mainly composed of great number of ring compounds with extremely low concentration. The ring compounds are separated according to their boiling point diversity in the first dimension column, then to their polarity or ring number variety in the second dimension column. In the sample there are two groups of UCMs, i.e., the first group compounds with boiling point lower that of C24 and the second group compounds with boiling point higher than that of C24. The first group of UCMs mainly consists of monocyclic, bicyclic and tricyclic ring compounds. The first group of UCMs is mainly composed of saturated hydrocarbons, in which the percentage of ring compounds with signal-to-noise ratio above 100 is about 75% of the total quantity of saturated hydrocarbon, while its mass is over 80% of the total saturated hydrocarbon. The second group of UCMs is mainly composed of tetracyclic and pentacyclic ring compounds, in which the percentage of UCM compounds with signal-to-noise ratio over 100 is about 17% of the total quantity of saturated hydrocarbon, and its mass is about 0.5% of the total saturated hydrocarbon. The results of this study are helpful for heavy oil developing and genesis mechanism understanding.
