The flammability characterization and thermal composition of polymers flame retarded by decabromodiphenylethane (DBDPE) and antimony trioxide (Sb2O3) were studied by cone calorimeter and thermogravimetry (TG). The res...The flammability characterization and thermal composition of polymers flame retarded by decabromodiphenylethane (DBDPE) and antimony trioxide (Sb2O3) were studied by cone calorimeter and thermogravimetry (TG). The results show that ABS/DBDPE/Sb2O3 has the similar flammability parameters and thermal composition curves to ABS/DBDPO/Sb2O3. It suggests that DBDPE/Sb2O3 has the similar flame retardant behavior to DBDPO/Sb2O3. The heat release rate (HRR) and the effect heat combustion (EHC) curves of polymers flame retarded by DBDPE/Sb2O3 all decrease, but the mass loss rate (MLR) curve slightly increase. It shows that the decrease of HRR is not due to the increase of char formation ratio but the generation of incombustible gases. The major flame retardant mechanism of DBDPE/Sb2O3 is gas phase flame retardant mechanism. Increasing content of Sb2O3 in DBDPE/Sb2O3 can improve the flame retardant property and thermal stability of acrylonitrile butadiene styrene. Sb2O3 has a good synergistic effect with DBDPE.展开更多
Five Shenfu char samples were prepared from Shenfu raw coal at different temperatures (950, 1100, 1200, 1300 and 1400℃) using a muffle furnace. Demineralization of the char samples was performed by treating them wi...Five Shenfu char samples were prepared from Shenfu raw coal at different temperatures (950, 1100, 1200, 1300 and 1400℃) using a muffle furnace. Demineralization of the char samples was performed by treating them with 10% nitric acid for 10 min in a CEM Discover microwave reactor. The gasification of the chars, and corresponding demineralized chars, in a carbon dioxide (CO2) atmosphere was conducted in a Netzsch STA 409Cl31F tempera- ture-programmed thermogravimetry apparatus. The effects of charring temperature and demineralization on the gasification reactivity of chars were systematically investigated. The results show that a char formed at a lower temperature is more reactive except for demineralized char formed at 1100℃, which is less reactive than char formed at 1200℃. Demineralization decreases the char reactivities toward gasification with CO2 to a small extent.展开更多
Detection of a periodic signal hidden in noise is the goal of Superconducting Gravimeter (SG) data analysis. Due to spikes, gaps, datum shrifts (offsets) and other disturbances, the traditional FFT method shows inhere...Detection of a periodic signal hidden in noise is the goal of Superconducting Gravimeter (SG) data analysis. Due to spikes, gaps, datum shrifts (offsets) and other disturbances, the traditional FFT method shows inherent limitations. Instead, the least squares spectral analysis (LSSA) has showed itself more suitable than Fourier analysis of gappy, unequally spaced and unequally weighted data series in a variety of applications in geodesy and geophysics. This paper reviews the principle of LSSA and gives a possible strategy for the analysis of time series obtained from the Canadian Superconducting Gravimeter Installation (CGSI), with gaps, offsets, unequal sampling decimation of the data and unequally weighted data points.展开更多
It has been generally unclear over the mechanism of inhibitory influence of silicate on structural rearrangement or solely physical adsorption onto manganese dioxide (MnO2) about the decomposition of hydrogen peroxi...It has been generally unclear over the mechanism of inhibitory influence of silicate on structural rearrangement or solely physical adsorption onto manganese dioxide (MnO2) about the decomposition of hydrogen peroxide (H2O2). Consequently, several experiments were carried out by using MnO2 as a catalyst for the decomposition of H2O2 in a concentration series under certain concentrations of silicates. The silicates were analyzed by using a molybdenum blue colorimetric method. The results showed that the determination of silicates was inhibited by H2O2, whose inhibitory effect was greatly increased by increasing its concentration, but not limited by pH. SEM-EDX (scanning electron microscopy-energy dispersive x-ray spectrometry) results showed that the adsorption of silicates onto the surface of MnO2 was not purely via a structural rearrangement, with increasing Mn atoms protruding on the outer surface by covering oxygen and silicon atoms. XRD (X-ray diffraction) and FTIR (Fourier transform infrared) spectra results further revealed no significant total crystal structural changes in MnO2 after the adsorption of silicates, but only a small shift of 0.21° at 2e from 56.36° to 56.15° , and a FTIR vibration showed at around 1 050 cm-1. The results, therefore, showed that silicate adsorption onto MnO2 took place via both surface adsorption and structural rearrangement by interfacial reaction.展开更多
A kind of modified epoxy resins was obtained by condensation of epoxy resin with silicic acid tetraethyl ester(TEOS) and nano-SiO2. The reactions were performed with hydrochloric acid as a catalyst at 63 ℃. The str...A kind of modified epoxy resins was obtained by condensation of epoxy resin with silicic acid tetraethyl ester(TEOS) and nano-SiO2. The reactions were performed with hydrochloric acid as a catalyst at 63 ℃. The structure, thermal stability and morphological characteristics of the modified epoxy resins were studied through infrared spectra(FT-IR) analysis, thermogravimetric(TG) analysis and scanning electron microscopy respectively. It has been found from the IR and TG study that modified epoxy resins have greater thermal stability than epoxy resins, and its thermal stability has been improved by the formation of inter-crosslinked network structure. The modified epoxy resins exhibit heterogeneous morphology and heterogeneity increases with more TEOS feeding, which in turn confirms the formation of inter-crosslinked network structure in modified epoxy resins.展开更多
An experimental and theoretical study of steam reforming of dimethyl ether was carried out in a processor for fuel cell vehicles to explore the effect of temperature gradient and hydrogen content of the processor.A st...An experimental and theoretical study of steam reforming of dimethyl ether was carried out in a processor for fuel cell vehicles to explore the effect of temperature gradient and hydrogen content of the processor.A steady-state,laminar,two-dimensional axi-symmetric model was proposed to investigate the fluid flow,heat transfer and chemical reactions in the dimethyl ether steam reforming processor using porous medium approach.The numerical model was established with Star-CD program using SIMPLE algorithm and finite volume method.Experimental verification of the two-dimensional mathematical model was conducted.The numerical results coincided well with the experimental data.The effects of the parameters on the temperature gradient and hydrogen content of the processor were studied using the numerical model.展开更多
We propose a decision method -double scale method to derive the priority vector of finite alternatives with respect to a single criterion based on competition model. Compared with the attribute hierarchical model, the...We propose a decision method -double scale method to derive the priority vector of finite alternatives with respect to a single criterion based on competition model. Compared with the attribute hierarchical model, the double scale method is reasonable and practical.展开更多
基金Project(20574020) supported by the National Natural Science Foundation of China
文摘The flammability characterization and thermal composition of polymers flame retarded by decabromodiphenylethane (DBDPE) and antimony trioxide (Sb2O3) were studied by cone calorimeter and thermogravimetry (TG). The results show that ABS/DBDPE/Sb2O3 has the similar flammability parameters and thermal composition curves to ABS/DBDPO/Sb2O3. It suggests that DBDPE/Sb2O3 has the similar flame retardant behavior to DBDPO/Sb2O3. The heat release rate (HRR) and the effect heat combustion (EHC) curves of polymers flame retarded by DBDPE/Sb2O3 all decrease, but the mass loss rate (MLR) curve slightly increase. It shows that the decrease of HRR is not due to the increase of char formation ratio but the generation of incombustible gases. The major flame retardant mechanism of DBDPE/Sb2O3 is gas phase flame retardant mechanism. Increasing content of Sb2O3 in DBDPE/Sb2O3 can improve the flame retardant property and thermal stability of acrylonitrile butadiene styrene. Sb2O3 has a good synergistic effect with DBDPE.
基金Projects 2004CB217704 supported by the Special Fund for Major State Basic Research Project, 104031 by the Key Project of Chinese Ministry of Education JHB05-33 by the Program of the Universities in Jiangsu Province for Development of High-Tech Industries
文摘Five Shenfu char samples were prepared from Shenfu raw coal at different temperatures (950, 1100, 1200, 1300 and 1400℃) using a muffle furnace. Demineralization of the char samples was performed by treating them with 10% nitric acid for 10 min in a CEM Discover microwave reactor. The gasification of the chars, and corresponding demineralized chars, in a carbon dioxide (CO2) atmosphere was conducted in a Netzsch STA 409Cl31F tempera- ture-programmed thermogravimetry apparatus. The effects of charring temperature and demineralization on the gasification reactivity of chars were systematically investigated. The results show that a char formed at a lower temperature is more reactive except for demineralized char formed at 1100℃, which is less reactive than char formed at 1200℃. Demineralization decreases the char reactivities toward gasification with CO2 to a small extent.
文摘Detection of a periodic signal hidden in noise is the goal of Superconducting Gravimeter (SG) data analysis. Due to spikes, gaps, datum shrifts (offsets) and other disturbances, the traditional FFT method shows inherent limitations. Instead, the least squares spectral analysis (LSSA) has showed itself more suitable than Fourier analysis of gappy, unequally spaced and unequally weighted data series in a variety of applications in geodesy and geophysics. This paper reviews the principle of LSSA and gives a possible strategy for the analysis of time series obtained from the Canadian Superconducting Gravimeter Installation (CGSI), with gaps, offsets, unequal sampling decimation of the data and unequally weighted data points.
基金Supported by the Provincial Basic Research Program of Hebei Education Department(ZD2015110)the National Special Project on Key Technologies and Demonstration of Wetland Ecological Restoration in the Haihe River Basin(2014ZX07203008)
文摘It has been generally unclear over the mechanism of inhibitory influence of silicate on structural rearrangement or solely physical adsorption onto manganese dioxide (MnO2) about the decomposition of hydrogen peroxide (H2O2). Consequently, several experiments were carried out by using MnO2 as a catalyst for the decomposition of H2O2 in a concentration series under certain concentrations of silicates. The silicates were analyzed by using a molybdenum blue colorimetric method. The results showed that the determination of silicates was inhibited by H2O2, whose inhibitory effect was greatly increased by increasing its concentration, but not limited by pH. SEM-EDX (scanning electron microscopy-energy dispersive x-ray spectrometry) results showed that the adsorption of silicates onto the surface of MnO2 was not purely via a structural rearrangement, with increasing Mn atoms protruding on the outer surface by covering oxygen and silicon atoms. XRD (X-ray diffraction) and FTIR (Fourier transform infrared) spectra results further revealed no significant total crystal structural changes in MnO2 after the adsorption of silicates, but only a small shift of 0.21° at 2e from 56.36° to 56.15° , and a FTIR vibration showed at around 1 050 cm-1. The results, therefore, showed that silicate adsorption onto MnO2 took place via both surface adsorption and structural rearrangement by interfacial reaction.
文摘A kind of modified epoxy resins was obtained by condensation of epoxy resin with silicic acid tetraethyl ester(TEOS) and nano-SiO2. The reactions were performed with hydrochloric acid as a catalyst at 63 ℃. The structure, thermal stability and morphological characteristics of the modified epoxy resins were studied through infrared spectra(FT-IR) analysis, thermogravimetric(TG) analysis and scanning electron microscopy respectively. It has been found from the IR and TG study that modified epoxy resins have greater thermal stability than epoxy resins, and its thermal stability has been improved by the formation of inter-crosslinked network structure. The modified epoxy resins exhibit heterogeneous morphology and heterogeneity increases with more TEOS feeding, which in turn confirms the formation of inter-crosslinked network structure in modified epoxy resins.
基金supported by the National Natural Science Foundation of China (50975169)Shanghai Science Technology Committee (620210029)
文摘An experimental and theoretical study of steam reforming of dimethyl ether was carried out in a processor for fuel cell vehicles to explore the effect of temperature gradient and hydrogen content of the processor.A steady-state,laminar,two-dimensional axi-symmetric model was proposed to investigate the fluid flow,heat transfer and chemical reactions in the dimethyl ether steam reforming processor using porous medium approach.The numerical model was established with Star-CD program using SIMPLE algorithm and finite volume method.Experimental verification of the two-dimensional mathematical model was conducted.The numerical results coincided well with the experimental data.The effects of the parameters on the temperature gradient and hydrogen content of the processor were studied using the numerical model.
基金This research is supported by National Natural Science foundation of China(10671108) and the Natural Science Foundation of Shandong province(Y2005A04)
文摘We propose a decision method -double scale method to derive the priority vector of finite alternatives with respect to a single criterion based on competition model. Compared with the attribute hierarchical model, the double scale method is reasonable and practical.