The flammability characterization and thermal composition of polymers flame retarded by decabromodiphenylethane (DBDPE) and antimony trioxide (Sb2O3) were studied by cone calorimeter and thermogravimetry (TG). The res...The flammability characterization and thermal composition of polymers flame retarded by decabromodiphenylethane (DBDPE) and antimony trioxide (Sb2O3) were studied by cone calorimeter and thermogravimetry (TG). The results show that ABS/DBDPE/Sb2O3 has the similar flammability parameters and thermal composition curves to ABS/DBDPO/Sb2O3. It suggests that DBDPE/Sb2O3 has the similar flame retardant behavior to DBDPO/Sb2O3. The heat release rate (HRR) and the effect heat combustion (EHC) curves of polymers flame retarded by DBDPE/Sb2O3 all decrease, but the mass loss rate (MLR) curve slightly increase. It shows that the decrease of HRR is not due to the increase of char formation ratio but the generation of incombustible gases. The major flame retardant mechanism of DBDPE/Sb2O3 is gas phase flame retardant mechanism. Increasing content of Sb2O3 in DBDPE/Sb2O3 can improve the flame retardant property and thermal stability of acrylonitrile butadiene styrene. Sb2O3 has a good synergistic effect with DBDPE.展开更多
Five Shenfu char samples were prepared from Shenfu raw coal at different temperatures （950, 1100, 1200, 1300 and 1400℃） using a muffle furnace. Demineralization of the char samples was performed by treating them wi...Five Shenfu char samples were prepared from Shenfu raw coal at different temperatures （950, 1100, 1200, 1300 and 1400℃） using a muffle furnace. Demineralization of the char samples was performed by treating them with 10% nitric acid for 10 min in a CEM Discover microwave reactor. The gasification of the chars, and corresponding demineralized chars, in a carbon dioxide （CO2） atmosphere was conducted in a Netzsch STA 409Cl31F tempera- ture-programmed thermogravimetry apparatus. The effects of charring temperature and demineralization on the gasification reactivity of chars were systematically investigated. The results show that a char formed at a lower temperature is more reactive except for demineralized char formed at 1100℃, which is less reactive than char formed at 1200℃. Demineralization decreases the char reactivities toward gasification with CO2 to a small extent.展开更多
Detection of a periodic signal hidden in noise is the goal of Superconducting Gravimeter (SG) data analysis. Due to spikes, gaps, datum shrifts (offsets) and other disturbances, the traditional FFT method shows inhere...Detection of a periodic signal hidden in noise is the goal of Superconducting Gravimeter (SG) data analysis. Due to spikes, gaps, datum shrifts (offsets) and other disturbances, the traditional FFT method shows inherent limitations. Instead, the least squares spectral analysis (LSSA) has showed itself more suitable than Fourier analysis of gappy, unequally spaced and unequally weighted data series in a variety of applications in geodesy and geophysics. This paper reviews the principle of LSSA and gives a possible strategy for the analysis of time series obtained from the Canadian Superconducting Gravimeter Installation (CGSI), with gaps, offsets, unequal sampling decimation of the data and unequally weighted data points.展开更多
We propose a decision method -double scale method to derive the priority vector of finite alternatives with respect to a single criterion based on competition model. Compared with the attribute hierarchical model, the...We propose a decision method -double scale method to derive the priority vector of finite alternatives with respect to a single criterion based on competition model. Compared with the attribute hierarchical model, the double scale method is reasonable and practical.展开更多
基金Project(20574020) supported by the National Natural Science Foundation of China
文摘The flammability characterization and thermal composition of polymers flame retarded by decabromodiphenylethane (DBDPE) and antimony trioxide (Sb2O3) were studied by cone calorimeter and thermogravimetry (TG). The results show that ABS/DBDPE/Sb2O3 has the similar flammability parameters and thermal composition curves to ABS/DBDPO/Sb2O3. It suggests that DBDPE/Sb2O3 has the similar flame retardant behavior to DBDPO/Sb2O3. The heat release rate (HRR) and the effect heat combustion (EHC) curves of polymers flame retarded by DBDPE/Sb2O3 all decrease, but the mass loss rate (MLR) curve slightly increase. It shows that the decrease of HRR is not due to the increase of char formation ratio but the generation of incombustible gases. The major flame retardant mechanism of DBDPE/Sb2O3 is gas phase flame retardant mechanism. Increasing content of Sb2O3 in DBDPE/Sb2O3 can improve the flame retardant property and thermal stability of acrylonitrile butadiene styrene. Sb2O3 has a good synergistic effect with DBDPE.
基金Projects 2004CB217704 supported by the Special Fund for Major State Basic Research Project, 104031 by the Key Project of Chinese Ministry of Education JHB05-33 by the Program of the Universities in Jiangsu Province for Development of High-Tech Industries
文摘Five Shenfu char samples were prepared from Shenfu raw coal at different temperatures （950, 1100, 1200, 1300 and 1400℃） using a muffle furnace. Demineralization of the char samples was performed by treating them with 10% nitric acid for 10 min in a CEM Discover microwave reactor. The gasification of the chars, and corresponding demineralized chars, in a carbon dioxide （CO2） atmosphere was conducted in a Netzsch STA 409Cl31F tempera- ture-programmed thermogravimetry apparatus. The effects of charring temperature and demineralization on the gasification reactivity of chars were systematically investigated. The results show that a char formed at a lower temperature is more reactive except for demineralized char formed at 1100℃, which is less reactive than char formed at 1200℃. Demineralization decreases the char reactivities toward gasification with CO2 to a small extent.
文摘Detection of a periodic signal hidden in noise is the goal of Superconducting Gravimeter (SG) data analysis. Due to spikes, gaps, datum shrifts (offsets) and other disturbances, the traditional FFT method shows inherent limitations. Instead, the least squares spectral analysis (LSSA) has showed itself more suitable than Fourier analysis of gappy, unequally spaced and unequally weighted data series in a variety of applications in geodesy and geophysics. This paper reviews the principle of LSSA and gives a possible strategy for the analysis of time series obtained from the Canadian Superconducting Gravimeter Installation (CGSI), with gaps, offsets, unequal sampling decimation of the data and unequally weighted data points.
基金This research is supported by National Natural Science foundation of China（10671108） and the Natural Science Foundation of Shandong province（Y2005A04）
文摘We propose a decision method -double scale method to derive the priority vector of finite alternatives with respect to a single criterion based on competition model. Compared with the attribute hierarchical model, the double scale method is reasonable and practical.
