Second-order polarizabilities of BMC and MMONS were determined by solvatocbromic method. The second-order polarizabilities of BMC and MMONS were also calculated by quantum chemical semiempirical CNDO/S-CI method and p...Second-order polarizabilities of BMC and MMONS were determined by solvatocbromic method. The second-order polarizabilities of BMC and MMONS were also calculated by quantum chemical semiempirical CNDO/S-CI method and perturbation theory and second-order nonlinear optical data respectively. Calculated values are in good agreement with experimental results. The effect of molecular and crystal structure on second-order polarizabilities has also been discussed.展开更多
A robust control strategy using the second-order integral sliding mode control(SOISMC)based on the variable speed grey wolf optimization(VGWO)is proposed.The aim is to maximize the wind power extraction of wind turbin...A robust control strategy using the second-order integral sliding mode control(SOISMC)based on the variable speed grey wolf optimization(VGWO)is proposed.The aim is to maximize the wind power extraction of wind turbine.Firstly,according to the uncertainty model of wind turbine,a SOISMC torque controller with fast convergence speed,strong robustness and effective chattering reduction is designed,which ensures that the torque controller can effectively track the reference speed.Secondly,given the strong local search ability of the grey wolf optimization(GWO)and the fast convergence speed and strong global search ability of the particle swarm optimization(PSO),the speed component of PSO is introduced into GWO,and VGWO with fast convergence speed,high solution accuracy and strong global search ability is used to optimize the parameters of wind turbine torque controller.Finally,the simulation is implemented based on Simulink/SimPowerSystem.The results demonstrate the effectiveness of the proposed strategy under both external disturbance and model uncertainty.展开更多
The structural changes of silicate anions in the desilication process with the addition of calcium hydrate alumino-carbonate were studied by measuring Raman spectra, infrared spectra and corresponding second derivativ...The structural changes of silicate anions in the desilication process with the addition of calcium hydrate alumino-carbonate were studied by measuring Raman spectra, infrared spectra and corresponding second derivative spectra. The results show that the desilication ratio in the solution prepared by the addition of sodium silicate(solution-SS) is much greater than that in the solution by the addition of green liquor(solution-GL), and low alumina concentration in the sodium aluminate solutions facilitates the desilication process. It is also shown that alumino-silicate anions in the solution-GL, and Q^3 polymeric silicate anions in solution-SS are predominant, respectively. In addition, increasing the concentration of silica favors respectively the formation of the alumino-silicate or the Q^3 silicate anions in the solution-GL or the solution-SS. Therefore, it can be inferred that the low desilication ratio in the silicate-bearing aluminate solution is mainly attributed to the existence of alumino-silicate anions.展开更多
文摘Second-order polarizabilities of BMC and MMONS were determined by solvatocbromic method. The second-order polarizabilities of BMC and MMONS were also calculated by quantum chemical semiempirical CNDO/S-CI method and perturbation theory and second-order nonlinear optical data respectively. Calculated values are in good agreement with experimental results. The effect of molecular and crystal structure on second-order polarizabilities has also been discussed.
基金This work was supported by the National Natural Science Foundation of China(No.51876089)the Fundamental Research Funds for the Central Universities(No.kfjj20190205).
文摘A robust control strategy using the second-order integral sliding mode control(SOISMC)based on the variable speed grey wolf optimization(VGWO)is proposed.The aim is to maximize the wind power extraction of wind turbine.Firstly,according to the uncertainty model of wind turbine,a SOISMC torque controller with fast convergence speed,strong robustness and effective chattering reduction is designed,which ensures that the torque controller can effectively track the reference speed.Secondly,given the strong local search ability of the grey wolf optimization(GWO)and the fast convergence speed and strong global search ability of the particle swarm optimization(PSO),the speed component of PSO is introduced into GWO,and VGWO with fast convergence speed,high solution accuracy and strong global search ability is used to optimize the parameters of wind turbine torque controller.Finally,the simulation is implemented based on Simulink/SimPowerSystem.The results demonstrate the effectiveness of the proposed strategy under both external disturbance and model uncertainty.
基金Project(51274242)supported by the National Natural Science Foundation of ChinaProject(2015CX001)supported by the Innovation-driven Plan in Central South University,China
文摘The structural changes of silicate anions in the desilication process with the addition of calcium hydrate alumino-carbonate were studied by measuring Raman spectra, infrared spectra and corresponding second derivative spectra. The results show that the desilication ratio in the solution prepared by the addition of sodium silicate(solution-SS) is much greater than that in the solution by the addition of green liquor(solution-GL), and low alumina concentration in the sodium aluminate solutions facilitates the desilication process. It is also shown that alumino-silicate anions in the solution-GL, and Q^3 polymeric silicate anions in solution-SS are predominant, respectively. In addition, increasing the concentration of silica favors respectively the formation of the alumino-silicate or the Q^3 silicate anions in the solution-GL or the solution-SS. Therefore, it can be inferred that the low desilication ratio in the silicate-bearing aluminate solution is mainly attributed to the existence of alumino-silicate anions.
