The process of aluminothermic reduction of a mixture of calcined dolomite and calcined magnesite had been developed. The mechanism of the process was studied by SEM and EDS. The reduction process was divided into thre...The process of aluminothermic reduction of a mixture of calcined dolomite and calcined magnesite had been developed. The mechanism of the process was studied by SEM and EDS. The reduction process was divided into three stages:0≤ηt/ηf≤0.43±0.06, 0.43±0.06≤ηt/ηf≤0.9±0.02 and 0.9±0.02≤ηt/ηf<1, whereηt andηf are the reduction ratio at time t and the final reduction ratio obtained in the experiment at temperature T, respectively. The first stage included the direct reaction between calcined dolomite or calcined magnesite and Al with 12CaO·7Al2O3 and MgO·Al2O3 as products. The reaction rate depended on the chemical reaction. The CA phase was mainly produced in the second stage and the overall reaction rate was determined by both the diffusion of Ca2+ with molten Al and the chemical reaction. The CA2 phase was mainly produced in the third stage and the reaction process was controlled by the diffusion of Ca2+.展开更多
The vacuum aluminothermic reduction of the mixture of calcined magnesite and calcined dolomite was studied. An isothermal reduction method satisfying the vacuum aluminothermic reduction was proposed. The experiments w...The vacuum aluminothermic reduction of the mixture of calcined magnesite and calcined dolomite was studied. An isothermal reduction method satisfying the vacuum aluminothermic reduction was proposed. The experiments were carried out at 4 Pa. The results indicate that the reduction rate is increased with increasing temperature, content of aluminum and pellet forming pressure. The XRD patterns of pellets at different reduction stages confirm that the reduction process can be roughly classified into three stages:the formation of MgAl2O4, and Ca12Al14O33 phases;the phase transformation from MgAl2O4 and C12A7 to CaAl2O4;the formation of CaAl4O7 phase. The experimental data were divided into three parts according to the kinetic models. The apparent activation energies of the three parts were determined to be 98.2, 133.0 and 223.3 kJ/mol, respectively.展开更多
Yunmai52, developed by crossing with common wheat-Haynaldia villosa6AL/6VS translocation line 92R149 as a resistant parent in 1992, was a common wheat cultivar approved and released in 2007 in Yunnan Province, China, ...Yunmai52, developed by crossing with common wheat-Haynaldia villosa6AL/6VS translocation line 92R149 as a resistant parent in 1992, was a common wheat cultivar approved and released in 2007 in Yunnan Province, China, which is characterized by high resistance to powdery mildew and stripe rust. In this study,an F_2 population derived from a cross K78S/Yunmai52 was constructed to investigate the resistance genes, where K78 S is a wheat male sterile line susceptible to powdery mildew and stripe rust. Phenotypic identification of the parents, F_1 and F_2 populations and chi-square analyses showed that F_1 population was immune to stripe rust and powdery mildew; the segregation ratio of resistance and susceptibility to powdery mildew(χ~2=1.10χ~2_(1,0.05)=3.84) and stripe rust(χ~2=0.15χ~2_(1,0.05)=3.84) fit to a 3:1 ratio in F_2 population, indicating that Yunmai52 harbors a dominant stripe rust resistance gene and a dominant powdery mildew resistance gene. The individuals were further detected with a marker co-segregated with Pm21(SCAR_(1400)) and two markers closely linked with Yr26(XWe173 and Xbarc181). The results showed that polymorphic bands could be amplified between the parents and between resistance and susceptibility gene pools at the same locus. Randomly 96 individuals of F_2 population were selected for verification. The results showed that the phenotype was significantly correlated with the genotype. The detection accuracy of markers SCAR_(1400), XWe173 and Xbarc181 was 100%, 97.91% and 92.70%, respectively.Yunmai52 harbored powdery mildew resistance gene Pm21 and stripe rust resistance gene Yr26, which were both derived from 6AL/6VS translocation line 92R149.In addition, the results also demonstrate that Pm21 and Yr26 are two genes conferring durable resistance to powdery mildew and stripe rust in wheat.展开更多
The shortage and inefficiency of public cultural services are common problems in China, especially in the western regions. Baiyun District has made use- ful exploration to the construction of rural public cultural ser...The shortage and inefficiency of public cultural services are common problems in China, especially in the western regions. Baiyun District has made use- ful exploration to the construction of rural public cultural service system, network system, resource system, management system and service system.展开更多
To understand the mineral elements in different varieties of tea ( Camellia sinensis), 17 mineral elements in eight tea varieties including Yunnan Dayezhong, No. 43 Longjing and No. 6 Zaobaijian, were measured. The ...To understand the mineral elements in different varieties of tea ( Camellia sinensis), 17 mineral elements in eight tea varieties including Yunnan Dayezhong, No. 43 Longjing and No. 6 Zaobaijian, were measured. The results showed that nine elements, such as P, K, Ba, Mn, Cu, were significantly different among varieties, others did not. Black tea varieties usually contain high contents of Cu and K. As a conclusion, mineral elements should be extensively considered in breeding tea varieties.展开更多
A novel mixed collector (BHOA) was prepared by mixing benzohydroxamic acid (BHA) and sodium oleate (NaOL) and applied to the flotation separation of smithsonite from dolomite. Flotation results showed that NaOL alone ...A novel mixed collector (BHOA) was prepared by mixing benzohydroxamic acid (BHA) and sodium oleate (NaOL) and applied to the flotation separation of smithsonite from dolomite. Flotation results showed that NaOL alone had good collecting performance on smithsonite and common gangue mineral dolomite but had poor selectivity. By using a BHA/NaOL mixed system with a molar ratio of 2:1, the recoveries of smithsonite and dolomite reached approximately 90% and 5%, respectively. Surface tension analysis showed that the surface activity of BHOA was a little higher than that of a single NaOL because of synergistic effects. Zeta potential and X-ray photoelectron spectroscopy measurements indicated that surfactants BHA and NaOL co-absorbed on the smithsonite surface and only NaOL was present on the dolomite surface in the presence of BHOA.展开更多
The present study aims at the recovery of potassium from muscovite mica(which contains K_(2)O;~10 wt%)using NaCl-roasting coupled with H_(2)SO_(4)-leaching process.The preliminary acid leaching studies applying differ...The present study aims at the recovery of potassium from muscovite mica(which contains K_(2)O;~10 wt%)using NaCl-roasting coupled with H_(2)SO_(4)-leaching process.The preliminary acid leaching studies applying different mineral acids resulted in a potassium recovery of 8%−18%.The optimum leaching conditions for the maximum recovery were 4 mol/L H_(2)SO_(4),60 min leaching time and liquid-solid ratio 4 mL/g at 90℃.However,the roasting of muscovite with additive NaCl(muscovite:NaCl mass ratio of 1:1.00,900℃,45 min)followed by H_(2)SO_(4)-leaching(95℃,60 min)extracted potassium to the tune of 98%.Under similar roasting conditions,the H_(2)O-leaching process extracted only 60%of potassium.The effects of various roasting and leaching parameters such as temperature,time,NaCl concentration,acid concentration,liquid-solid ratio on potassium extraction were evaluated.The appearance of the sylvite(KCl)mineral phase in the NaCl-roasted muscovite and its disappearance in the acid/water leached residue confirmed the physical and chemical distortions of the muscovite crystal structure.The possible mechanism of potassium release from the complex muscovite structure was elucidated based on available literature substantiated by characterizations using X-ray diffraction(XRD)and scanning electron microscopy with energy dispersive X-rays spectroscopy(SEM-EDX).展开更多
The Zhuxi W(Cu)skarn deposit,the world’s largest tungsten deposit is newly discovered in Jingdezhen city,northeastern Jiangxi province,China.It mainly occurs near the contact zone between the Yanshanian granites and ...The Zhuxi W(Cu)skarn deposit,the world’s largest tungsten deposit is newly discovered in Jingdezhen city,northeastern Jiangxi province,China.It mainly occurs near the contact zone between the Yanshanian granites and the Late Paleozoic carbonate rocks.Three types of mineralization including skarn type,altered granite type and quartz vein veinlet type orebodies have been observed.In this study,the 40Ar 39Ar age of hydrothermal muscovite coexisting with copper mineralization in the altered granite type orebody formed near the unconformity interface is determined by step-heating technology using CO2 laser.The plateau age,isochron age,and inverse isochron age of muscovite are(147.39±0.94)Ma,(147.2±1.5)Ma,and(147.1±1.5)Ma,respectively.These ages are almost identical to the ages of ore-related granite and other mineralization types in the Zhuxi W(Cu)deposit,indicating that the Cu mineralizations occurred at the shallow depth and near the unconformity interface are contemporaneous during the Late Jurassic.This further suggested that the acompanied W and Cu mineralization in the Zhuxi W(Cu)deposit which may be controlled by the magma source is enriched in both W and Cu.展开更多
Matrix porosity calculations of fractured and vuggy reservoirs, such as volcanics and weathered dolomite, are one of the problems urgently needed to solve in well-log evaluation. In this paper, we first compare the an...Matrix porosity calculations of fractured and vuggy reservoirs, such as volcanics and weathered dolomite, are one of the problems urgently needed to solve in well-log evaluation. In this paper, we first compare the an empirical formula for porosity calculation from full diameter rhyolite core experiments with the matrix porosity formulas commonly used. We discuss the applicability of the empirical formula in fractured and vuggy reservoirs, such as intermediate-basic volcanics and weathered dolomite. Based on core analysis data, the error distribution of the calculated porosity of our empirical formula and the other porosity formulas in these reservoirs are given. The statistical error analysis indicates that the our empirical formula provides a higher precision than the other porosity formulas. When the porosity is between 1.5% and 15%, the acoustic experiment formula can be used not only for acidic volcanics but also in other fractured and vuggy reservoirs, such as intermediate-basic volcanics and weathered dolomite. Moreover, the formula can reduce the effects of borehole enlargement and rock alteration on porosity computation.展开更多
The origin and migration of natural gas and the accumulation of gas hydrates within the Pearl River Mouth Basin of the northern South China Sea are poorly understood. Based on high-resolution 2D/3D seismic data, three...The origin and migration of natural gas and the accumulation of gas hydrates within the Pearl River Mouth Basin of the northern South China Sea are poorly understood. Based on high-resolution 2D/3D seismic data, three environments of focused fluid flow: gas chimneys, mud diapirs and active faults have been identified. Widespread gas chimneys that act as important conduits for fluid flow are located below bottom simulating reflections and above basal uplifts. The occurrence and evolution of gas chimneys can be divided into a violent eruptive stage and a quiet seepage stage. For most gas chimneys, the strong eruptions are deduced to have happened during the Dongsha Movement in the latest Miocene, which are observed below Pliocene strata and few active faults develop above the top of the Miocene. The formation pressures of the Baiyun Sag currently are considered to be normal, based on these terms: 1) Borehole pressure tests with pressure coefficients of 1.043-l.047; 2) The distribution of gas chimneys is limited to strata older than the Pliocene; 3) Disseminated methane hydrates, rather than fractured hydrates, are found in the hydrate samples; 4) The gas hydrate is mainly charged with biogenic gas rather than thermogenic gas based on the chemical tests from gas hydrates cores. However, periods of quiet focused fluid flow also enable the establishment of good conduits for the migration of abundant biogenic gas and lesser volumes ofthermogenic gas. A geological model goveming fluid flow has been proposed to interpret the release of overpressure, the migration of fluids and the formation of gas hydrates, in an integrated manner. This model suggests that gas chimneys positioned above basal uplifts were caused by the Dongsha Movement at about 5.5 Ma. Biogenic gas occupies the strata above the base of the middle Miocene and migrates slowly into the gas chimney columns. Some of the biogenic gas and small volumes ofthermogenic gas eventually contribute to the formation of the gas hydrates.展开更多
This paper analyzes the samples of rainwater from January to October 1999 at three monitoring sites of Baiyun Mountain and of aerosol composition in near-surface layer in January and June 1999 at two sites. The result...This paper analyzes the samples of rainwater from January to October 1999 at three monitoring sites of Baiyun Mountain and of aerosol composition in near-surface layer in January and June 1999 at two sites. The results suggest that (1) The pH value of rainwater is between 3.13 and 7.18, and the frequency of acid rain is more than 58 %. With the ascent of the monitoring sites, the pH value of rainwater decreases, and the frequency of acid rain increases. (2) In January, the chemical aerosol compositions at different altitudes are similar, but in June the acidity of aerosol rises at the higher site because of the increase of SO42-. (3) In rainwater, the proportion is such that SO42- is the most significant anion and Ca2+ is the most important cation, but both of them decrease as the altitude ascends. The proportion of NO3- and NH4+ rise at the higher site and have more contribution to the acidity of rainwater. (4) As the impact of automobile emissions around Baiyun Mountain, the proportion of NO3-/SO42-molecular concentration reaches 0.40, and NO3- is relatively more important to the rain acidity at the higher site.展开更多
This study presents bulk chemical compositions of the Tongmuling soil profile, which developed on dolostone, and the overlying strata covering the bedrock in the central Guizhou province(southern China). The chemical ...This study presents bulk chemical compositions of the Tongmuling soil profile, which developed on dolostone, and the overlying strata covering the bedrock in the central Guizhou province(southern China). The chemical weathering characteristics of the studied profile were investigated and the inheritance relationships between the terra rossa and overlying strata were discussed. The results show that there is no remarkable variation in the major elements and weathering indices from the rock–soil interface to the topsoil, indicating that the studied profile was not typical for in situ crustal chemical weathering. The terra rossa were mainly composed of Si O_2, Al_2O_3 and Fe_2O_3. Compared with the insoluble residues and overlying strata, the terra rossa are characterized by an enrichment of Y and Cs and depletion of Ba and Sr. The subsoil shows a notable Ce negative anomaly, characterized by heavy rare earth element enrichment(L/H = 1.55–3.74), whereas the topsoil shows a positive Ce anomaly with light rare earth element enrichment(L/H = 5.93–9.14). According to Laterite-forming capacity estimates, the terra rossa could not have only been formed from acid-insoluble residues from the bedrock; Al_2O_3 versus Fe_2O_3and Nb plotted against Ta show significant positive correlations between the terra rossa and overlying strata. The Eu/Eu* versusGd_N/Yb_Nand ternary diagrams for Sc, Th, Zr, and Ta suggest that the overlying strata could also provide parent materials for the genesis of terra rossa.展开更多
A series of marine natural gas fields were recently discovered in oolitic dolomites of the Lower Triassic Feixianguan formation, northeastern Sichuan Basin, southwest China. The mechanism forming these reservoir dolom...A series of marine natural gas fields were recently discovered in oolitic dolomites of the Lower Triassic Feixianguan formation, northeastern Sichuan Basin, southwest China. The mechanism forming these reservoir dolomites is debatable, limiting the ability to characterize these reservoir successfully. Based on the investigation of the representative Dukouhe, Luojiazhai, and Puguang areas, this issue was addressed by examining the distribution, petrology, and geochemistry of the dolomites, the most comprehensive study to date was provided. Dolomitization occurred at a very early stage of diagenesis, as shown by the petrological features of the rock fabric. Vadose silt, which is composed primarily of dolomitic clasts, is found in the primary and secondary pores of the oolitic dolomite. This indicates that the overlying strata were subjected to dolomitization when the Feixianguan formation was located in the vadose zone. Therefore, it may be inferred that the dolomitization which occurred before the formation was exposed to meteoric conditions. The spatial distribution and geochemical characteristics of the dolomite indicate that dolomitization occurred as a result of seepage reflux. The degree of dolomitization decreases with increasing distance from the evaporative lagoon. Furthermore, the type and porosity of the dolomite vary in different zones of the upward-shoaling sequence, with the porosity gradually decreasing from the highest layer to the lowest layer. This reflects a close relationship between dolomitization and seawater evaporation during the formation of the dolomite. Geochemical analysis provided further evidence for the relationship between the dolomitization fluid and the coeval seawater. The 87Sr/86Sr and 813C isotopes, as well as the abundances of trace elements, Fe and Mn, indicate that seawater concentrated by evaporation acted as the dolomitization fluid. These results also show that dolomitization most likely occurred in a semi-closed diagenetic environment. Therefore, the main mechanism of oolitic dolomite formation is seepage reflux, which occurred at an early stage of diagenesis.展开更多
基金Project(MYF2011-34)supported by High-tech R&D Projects of Liaoning Province Magnesia Materials Industry,ChinaProject(2011221002)supported by Industrial Research Projects of Liaoning Province,ChinaProject(N100302009)supported by the Fundamental Research Funds for the Central Universities,China
文摘The process of aluminothermic reduction of a mixture of calcined dolomite and calcined magnesite had been developed. The mechanism of the process was studied by SEM and EDS. The reduction process was divided into three stages:0≤ηt/ηf≤0.43±0.06, 0.43±0.06≤ηt/ηf≤0.9±0.02 and 0.9±0.02≤ηt/ηf<1, whereηt andηf are the reduction ratio at time t and the final reduction ratio obtained in the experiment at temperature T, respectively. The first stage included the direct reaction between calcined dolomite or calcined magnesite and Al with 12CaO·7Al2O3 and MgO·Al2O3 as products. The reaction rate depended on the chemical reaction. The CA phase was mainly produced in the second stage and the overall reaction rate was determined by both the diffusion of Ca2+ with molten Al and the chemical reaction. The CA2 phase was mainly produced in the third stage and the reaction process was controlled by the diffusion of Ca2+.
基金Project(MYF2011-34)supported by High-tech R&D Plan of Liaoning Province,ChinaProject(2011221002)supported by Industrial Research Projects of Liaoning Province,ChinaProject(N100302009)supported by the Fundamental Research Funds for the Central Universities,China
文摘The vacuum aluminothermic reduction of the mixture of calcined magnesite and calcined dolomite was studied. An isothermal reduction method satisfying the vacuum aluminothermic reduction was proposed. The experiments were carried out at 4 Pa. The results indicate that the reduction rate is increased with increasing temperature, content of aluminum and pellet forming pressure. The XRD patterns of pellets at different reduction stages confirm that the reduction process can be roughly classified into three stages:the formation of MgAl2O4, and Ca12Al14O33 phases;the phase transformation from MgAl2O4 and C12A7 to CaAl2O4;the formation of CaAl4O7 phase. The experimental data were divided into three parts according to the kinetic models. The apparent activation energies of the three parts were determined to be 98.2, 133.0 and 223.3 kJ/mol, respectively.
基金Supported by National 863 Program of China(2011AA10A106)Director Fund of the Institute of Food Crops+1 种基金Yunnan Academy of Agricultural Sciences(2013LZS003)Program for Science and Technology Innovation Talents of Yunnan Province(2012HC008)~~
文摘Yunmai52, developed by crossing with common wheat-Haynaldia villosa6AL/6VS translocation line 92R149 as a resistant parent in 1992, was a common wheat cultivar approved and released in 2007 in Yunnan Province, China, which is characterized by high resistance to powdery mildew and stripe rust. In this study,an F_2 population derived from a cross K78S/Yunmai52 was constructed to investigate the resistance genes, where K78 S is a wheat male sterile line susceptible to powdery mildew and stripe rust. Phenotypic identification of the parents, F_1 and F_2 populations and chi-square analyses showed that F_1 population was immune to stripe rust and powdery mildew; the segregation ratio of resistance and susceptibility to powdery mildew(χ~2=1.10χ~2_(1,0.05)=3.84) and stripe rust(χ~2=0.15χ~2_(1,0.05)=3.84) fit to a 3:1 ratio in F_2 population, indicating that Yunmai52 harbors a dominant stripe rust resistance gene and a dominant powdery mildew resistance gene. The individuals were further detected with a marker co-segregated with Pm21(SCAR_(1400)) and two markers closely linked with Yr26(XWe173 and Xbarc181). The results showed that polymorphic bands could be amplified between the parents and between resistance and susceptibility gene pools at the same locus. Randomly 96 individuals of F_2 population were selected for verification. The results showed that the phenotype was significantly correlated with the genotype. The detection accuracy of markers SCAR_(1400), XWe173 and Xbarc181 was 100%, 97.91% and 92.70%, respectively.Yunmai52 harbored powdery mildew resistance gene Pm21 and stripe rust resistance gene Yr26, which were both derived from 6AL/6VS translocation line 92R149.In addition, the results also demonstrate that Pm21 and Yr26 are two genes conferring durable resistance to powdery mildew and stripe rust in wheat.
文摘The shortage and inefficiency of public cultural services are common problems in China, especially in the western regions. Baiyun District has made use- ful exploration to the construction of rural public cultural service system, network system, resource system, management system and service system.
基金Supported by Applied Basic Research Development Program of Si-chuanKey Scientific and Technological Project of Tea Breeding Pro-ject in Sichuan Province during Eleventh Five-year Plan~~
文摘To understand the mineral elements in different varieties of tea ( Camellia sinensis), 17 mineral elements in eight tea varieties including Yunnan Dayezhong, No. 43 Longjing and No. 6 Zaobaijian, were measured. The results showed that nine elements, such as P, K, Ba, Mn, Cu, were significantly different among varieties, others did not. Black tea varieties usually contain high contents of Cu and K. As a conclusion, mineral elements should be extensively considered in breeding tea varieties.
基金Project(51704329) supported by the National Natural Science Foundation of ChinaProject(2018YFC1901901) supported by the National Key Scientific Research Project of China
文摘A novel mixed collector (BHOA) was prepared by mixing benzohydroxamic acid (BHA) and sodium oleate (NaOL) and applied to the flotation separation of smithsonite from dolomite. Flotation results showed that NaOL alone had good collecting performance on smithsonite and common gangue mineral dolomite but had poor selectivity. By using a BHA/NaOL mixed system with a molar ratio of 2:1, the recoveries of smithsonite and dolomite reached approximately 90% and 5%, respectively. Surface tension analysis showed that the surface activity of BHOA was a little higher than that of a single NaOL because of synergistic effects. Zeta potential and X-ray photoelectron spectroscopy measurements indicated that surfactants BHA and NaOL co-absorbed on the smithsonite surface and only NaOL was present on the dolomite surface in the presence of BHOA.
文摘The present study aims at the recovery of potassium from muscovite mica(which contains K_(2)O;~10 wt%)using NaCl-roasting coupled with H_(2)SO_(4)-leaching process.The preliminary acid leaching studies applying different mineral acids resulted in a potassium recovery of 8%−18%.The optimum leaching conditions for the maximum recovery were 4 mol/L H_(2)SO_(4),60 min leaching time and liquid-solid ratio 4 mL/g at 90℃.However,the roasting of muscovite with additive NaCl(muscovite:NaCl mass ratio of 1:1.00,900℃,45 min)followed by H_(2)SO_(4)-leaching(95℃,60 min)extracted potassium to the tune of 98%.Under similar roasting conditions,the H_(2)O-leaching process extracted only 60%of potassium.The effects of various roasting and leaching parameters such as temperature,time,NaCl concentration,acid concentration,liquid-solid ratio on potassium extraction were evaluated.The appearance of the sylvite(KCl)mineral phase in the NaCl-roasted muscovite and its disappearance in the acid/water leached residue confirmed the physical and chemical distortions of the muscovite crystal structure.The possible mechanism of potassium release from the complex muscovite structure was elucidated based on available literature substantiated by characterizations using X-ray diffraction(XRD)and scanning electron microscopy with energy dispersive X-rays spectroscopy(SEM-EDX).
基金Project(41873059)supported by the National Natural Science Foundation of ChinaProject(JGMEDB [2017]78)supported by the Jiangxi Geological and Mineral Exploration and Development Bureau Foundation,China+2 种基金Project(2011BAB04B02)supported by the National Science and Technology Support Plan Project,ChinaProject(201411035)supported by the Welfare Research Program of Ministry of Land and Resources,ChinaProject(20150013)supported by Jiangxi Provincial Geological Exploration Fund Management Center,China
文摘The Zhuxi W(Cu)skarn deposit,the world’s largest tungsten deposit is newly discovered in Jingdezhen city,northeastern Jiangxi province,China.It mainly occurs near the contact zone between the Yanshanian granites and the Late Paleozoic carbonate rocks.Three types of mineralization including skarn type,altered granite type and quartz vein veinlet type orebodies have been observed.In this study,the 40Ar 39Ar age of hydrothermal muscovite coexisting with copper mineralization in the altered granite type orebody formed near the unconformity interface is determined by step-heating technology using CO2 laser.The plateau age,isochron age,and inverse isochron age of muscovite are(147.39±0.94)Ma,(147.2±1.5)Ma,and(147.1±1.5)Ma,respectively.These ages are almost identical to the ages of ore-related granite and other mineralization types in the Zhuxi W(Cu)deposit,indicating that the Cu mineralizations occurred at the shallow depth and near the unconformity interface are contemporaneous during the Late Jurassic.This further suggested that the acompanied W and Cu mineralization in the Zhuxi W(Cu)deposit which may be controlled by the magma source is enriched in both W and Cu.
基金sponsored by the Science Research and Technology Development Project of Petrochina Company Limited "Well Logging Interpretation and Integrative Evaluation of the Complex Lithology"(Grant No.2008A-2705)
文摘Matrix porosity calculations of fractured and vuggy reservoirs, such as volcanics and weathered dolomite, are one of the problems urgently needed to solve in well-log evaluation. In this paper, we first compare the an empirical formula for porosity calculation from full diameter rhyolite core experiments with the matrix porosity formulas commonly used. We discuss the applicability of the empirical formula in fractured and vuggy reservoirs, such as intermediate-basic volcanics and weathered dolomite. Based on core analysis data, the error distribution of the calculated porosity of our empirical formula and the other porosity formulas in these reservoirs are given. The statistical error analysis indicates that the our empirical formula provides a higher precision than the other porosity formulas. When the porosity is between 1.5% and 15%, the acoustic experiment formula can be used not only for acidic volcanics but also in other fractured and vuggy reservoirs, such as intermediate-basic volcanics and weathered dolomite. Moreover, the formula can reduce the effects of borehole enlargement and rock alteration on porosity computation.
基金Supported by the National Natural Science Foundation of China (Nos.40930845 and 41006031)the International Science & Technology Cooperation Program of China (No. 2010DFA21740)the National Science and Technology Major Project (No. 2011ZX05026-004-06)
文摘The origin and migration of natural gas and the accumulation of gas hydrates within the Pearl River Mouth Basin of the northern South China Sea are poorly understood. Based on high-resolution 2D/3D seismic data, three environments of focused fluid flow: gas chimneys, mud diapirs and active faults have been identified. Widespread gas chimneys that act as important conduits for fluid flow are located below bottom simulating reflections and above basal uplifts. The occurrence and evolution of gas chimneys can be divided into a violent eruptive stage and a quiet seepage stage. For most gas chimneys, the strong eruptions are deduced to have happened during the Dongsha Movement in the latest Miocene, which are observed below Pliocene strata and few active faults develop above the top of the Miocene. The formation pressures of the Baiyun Sag currently are considered to be normal, based on these terms: 1) Borehole pressure tests with pressure coefficients of 1.043-l.047; 2) The distribution of gas chimneys is limited to strata older than the Pliocene; 3) Disseminated methane hydrates, rather than fractured hydrates, are found in the hydrate samples; 4) The gas hydrate is mainly charged with biogenic gas rather than thermogenic gas based on the chemical tests from gas hydrates cores. However, periods of quiet focused fluid flow also enable the establishment of good conduits for the migration of abundant biogenic gas and lesser volumes ofthermogenic gas. A geological model goveming fluid flow has been proposed to interpret the release of overpressure, the migration of fluids and the formation of gas hydrates, in an integrated manner. This model suggests that gas chimneys positioned above basal uplifts were caused by the Dongsha Movement at about 5.5 Ma. Biogenic gas occupies the strata above the base of the middle Miocene and migrates slowly into the gas chimney columns. Some of the biogenic gas and small volumes ofthermogenic gas eventually contribute to the formation of the gas hydrates.
基金Research on ecosystem environment and development of natural environmental resources in the scenic resort of Baiyun Mountain a key scientific project of Guangzhou (98-2-044-02)
文摘This paper analyzes the samples of rainwater from January to October 1999 at three monitoring sites of Baiyun Mountain and of aerosol composition in near-surface layer in January and June 1999 at two sites. The results suggest that (1) The pH value of rainwater is between 3.13 and 7.18, and the frequency of acid rain is more than 58 %. With the ascent of the monitoring sites, the pH value of rainwater decreases, and the frequency of acid rain increases. (2) In January, the chemical aerosol compositions at different altitudes are similar, but in June the acidity of aerosol rises at the higher site because of the increase of SO42-. (3) In rainwater, the proportion is such that SO42- is the most significant anion and Ca2+ is the most important cation, but both of them decrease as the altitude ascends. The proportion of NO3- and NH4+ rise at the higher site and have more contribution to the acidity of rainwater. (4) As the impact of automobile emissions around Baiyun Mountain, the proportion of NO3-/SO42-molecular concentration reaches 0.40, and NO3- is relatively more important to the rain acidity at the higher site.
基金financially supported by the National Basic Research Program of China(Grants No.2006CB403202)
文摘This study presents bulk chemical compositions of the Tongmuling soil profile, which developed on dolostone, and the overlying strata covering the bedrock in the central Guizhou province(southern China). The chemical weathering characteristics of the studied profile were investigated and the inheritance relationships between the terra rossa and overlying strata were discussed. The results show that there is no remarkable variation in the major elements and weathering indices from the rock–soil interface to the topsoil, indicating that the studied profile was not typical for in situ crustal chemical weathering. The terra rossa were mainly composed of Si O_2, Al_2O_3 and Fe_2O_3. Compared with the insoluble residues and overlying strata, the terra rossa are characterized by an enrichment of Y and Cs and depletion of Ba and Sr. The subsoil shows a notable Ce negative anomaly, characterized by heavy rare earth element enrichment(L/H = 1.55–3.74), whereas the topsoil shows a positive Ce anomaly with light rare earth element enrichment(L/H = 5.93–9.14). According to Laterite-forming capacity estimates, the terra rossa could not have only been formed from acid-insoluble residues from the bedrock; Al_2O_3 versus Fe_2O_3and Nb plotted against Ta show significant positive correlations between the terra rossa and overlying strata. The Eu/Eu* versusGd_N/Yb_Nand ternary diagrams for Sc, Th, Zr, and Ta suggest that the overlying strata could also provide parent materials for the genesis of terra rossa.
基金Project(2012CB214803)supported by the Major State Basic Research Development Program,ChinaProject(2011ZX5017-001-HZO2)supported by the National Science & Technology Special Project,China+1 种基金Project(2011D-5006-0105)supported by the PetroChina Research Fund,ChinaProject(SZD0414)supported by the Key Subject Construction Project of Sichuan Province,China
文摘A series of marine natural gas fields were recently discovered in oolitic dolomites of the Lower Triassic Feixianguan formation, northeastern Sichuan Basin, southwest China. The mechanism forming these reservoir dolomites is debatable, limiting the ability to characterize these reservoir successfully. Based on the investigation of the representative Dukouhe, Luojiazhai, and Puguang areas, this issue was addressed by examining the distribution, petrology, and geochemistry of the dolomites, the most comprehensive study to date was provided. Dolomitization occurred at a very early stage of diagenesis, as shown by the petrological features of the rock fabric. Vadose silt, which is composed primarily of dolomitic clasts, is found in the primary and secondary pores of the oolitic dolomite. This indicates that the overlying strata were subjected to dolomitization when the Feixianguan formation was located in the vadose zone. Therefore, it may be inferred that the dolomitization which occurred before the formation was exposed to meteoric conditions. The spatial distribution and geochemical characteristics of the dolomite indicate that dolomitization occurred as a result of seepage reflux. The degree of dolomitization decreases with increasing distance from the evaporative lagoon. Furthermore, the type and porosity of the dolomite vary in different zones of the upward-shoaling sequence, with the porosity gradually decreasing from the highest layer to the lowest layer. This reflects a close relationship between dolomitization and seawater evaporation during the formation of the dolomite. Geochemical analysis provided further evidence for the relationship between the dolomitization fluid and the coeval seawater. The 87Sr/86Sr and 813C isotopes, as well as the abundances of trace elements, Fe and Mn, indicate that seawater concentrated by evaporation acted as the dolomitization fluid. These results also show that dolomitization most likely occurred in a semi-closed diagenetic environment. Therefore, the main mechanism of oolitic dolomite formation is seepage reflux, which occurred at an early stage of diagenesis.