为探索土壤微形貌加工过程中从动型铲板式触土部件与土壤的互作机理,该研究基于离散元法(Discrete Element Method,DEM)与多体动力学(Multi-Body Dynamics,MBD)耦合算法建立铲板式滚动触土部件与土壤互作的离散元模型。通过EDEM-RecurDy...为探索土壤微形貌加工过程中从动型铲板式触土部件与土壤的互作机理,该研究基于离散元法(Discrete Element Method,DEM)与多体动力学(Multi-Body Dynamics,MBD)耦合算法建立铲板式滚动触土部件与土壤互作的离散元模型。通过EDEM-RecurDyn联合仿真探索滚动部件作业机理,以机具作业速度(0.6、1.0和1.4 m/s)为影响因素,求解机具作业所需水平牵引力与土壤微坑容积,并通过开展台架试验评价仿真模型准确性。耦合仿真结果表明:随机具作业速度的上升,x向水平牵引力和z向垂直力不断变大;机具在不同速度作业下的土壤表面形成的微坑容积分别为3310.91、3325.96和3384.47 mL;根据土壤压缩力、颗粒流向及动能变化,阐释了铲板式滚动触土部件作业过程中土壤微形貌的形成机理。将台架试验与仿真求解结果进行对比,x方向水平牵引力相对误差分别为5.02%、4.59%、4.11%,土壤表面微坑容积误差分别为6.23%、7.09%、5.64%,各作业速度下仿真模型具有较好的准确性。该研究所构建的DEM-MBD耦合模型可为探明铲板式滚动触土部件与土壤互作机理、机具几何结构优化、以及作业参数选择提供理论依据和技术参考。展开更多
We investigate the fluorescence quenching of Rhodamine 6G （R6G）, a well known laser dye with a high fluorescence quantum yield, by as-synthesized graphene oxide （GO） in aqueous solution, which is found to be rathe...We investigate the fluorescence quenching of Rhodamine 6G （R6G）, a well known laser dye with a high fluorescence quantum yield, by as-synthesized graphene oxide （GO） in aqueous solution, which is found to be rather efficient. By means of steady-state and time-resolved fluorescence spectroscopy combined with detailed analysis about the linear absorption vari- ation for this R6G-GO system, the pertinent quenching mechanism has been elucidated to be a combination of dynamic and static quenching. Possible ground-state complexes be- tween R6G and GO during the static quenching have also been suggested. Furthermore, the direction of photoindueed electron transfer between R6G and GO has been discussed.展开更多
Cell membranes play a crucial role in many biological functions of cells. A small change in the composition of cell membranes can strongly influence the functions of membrane-associated proteins, such as ion and water...Cell membranes play a crucial role in many biological functions of cells. A small change in the composition of cell membranes can strongly influence the functions of membrane-associated proteins, such as ion and water channels, and thus mediate the chemical and physical balance in cells. Such composition change could originate from the introduction of short-chain alcohols, or other anesthetics into membranes. In this work, we have applied sum frequency generation vibrational spectroscopy （SFG-VS）, supplemented by attenuated total reflectance Fourier transform infrared spectroscopy （ATR-FTIR）, to investigate interaction between methanol and 1,2-dimyristoyl-d54-sn-glycero-3-phosphocholine （d54-DMPC） lipid bilayers. Lipid＇s hydrocarbon interior is deuterated while its head group is hydrogenated. At the same time, CH3 symmetric stretch from methanol and lipid head amine group has different frequency, thus we can distinguish the behaviors of methanol, lipid head amine group, and lipid hydrocarbon interior. Based on the spectral feature of the bending mode of the water molecules replaced by methanol, we determined that the methanol molecules are intercalated into the region between amine and phosphate groups at the lipid hydrophilic head. The dipole of CH3 groups of methanol and lipid head, and the water O-H M1 adopt the same orientation directions. The introduction of methanol into the lipid hydrophilic head group can strongly perturb the entire length of the alkyl chains, resulting that the signals of CD2 and CD3 groups from both leaflets can not cancel each other.展开更多
Coal pillar design has historically assigned a factor of safety(Fo S) or stability factor(SF) according to their estimated strength and the assumed overburden load acting on them. Acceptable Fo S values have been assi...Coal pillar design has historically assigned a factor of safety(Fo S) or stability factor(SF) according to their estimated strength and the assumed overburden load acting on them. Acceptable Fo S values have been assigned based on past mining experience or a statistical link between Fo S and probability of failure(Po F). Pillar width-to-height(w/h) ratio has long been established as having a material influence on both pillar strength and its potential failure mode. However, there has been significant disagreement on using both factor of safety(Fo S) and w/h as part of pillar system stability criterion, as compared to using Fo S in isolation. This paper will argue that there are valid technical reasons to bring w/h ratio into system stability criteria(other than its influence on pillar strength), as it is related to the post-failure stiffness of the pillar, as measured in situ, and its interaction with overburden stiffness. When overburden stiffness is also brought into pillar system stability considerations, two issues emerge. The first is the width-todepth(W/D) ratio of the panel and whether it is sub-critical or super-critical from a surface subsidence perspective. The second relates to a re-evaluation of pillar Fo S based on whether the pillar is in an elastic or non-elastic(i.e., post-yield) state in its as-designed condition, as this is relevant to maintaining overburden stiffness at the highest possible level. The significance of the model is the potential to maximise both reserve recovery and mining efficiencies without any discernible increase in geotechnical risk, particularly in thick seams and higher depth of cover mining situations. At a time when mining economics are, at best, marginal, removing potentially unnecessary design conservatism is of interest to all mine operators and is an important topic for discussion amongst the geotechnical community.展开更多
The maximum Mode Ⅰ and Mode Ⅱ stress intensity factors(SIFs), KI,kmax(θ) and KII,kmax(θ)(0°<θ<360°), of inclined parallel multi-crack varying with relative positions(including horizontal and verti...The maximum Mode Ⅰ and Mode Ⅱ stress intensity factors(SIFs), KI,kmax(θ) and KII,kmax(θ)(0°<θ<360°), of inclined parallel multi-crack varying with relative positions(including horizontal and vertical spacings) are calculated by the complex function and integration method to analyze their interacting mechanism and determine the strengthening and weakening zone of SIFs. The multi-crack initiation criterion is established based on the ratio of maximum tension-shear SIF to predict crack initiation angle, load, and mechanism. The results show that multi-crack always initiates in Mode Ⅰ and the vertical spacing is better not to be times of half crack-length for crack-arrest, which is in good agreement with test results of the red-sandstone cube specimens with three parallel cracks under uniaxial compression. This can prove the validity of the multi-crack initiation criterion.展开更多
In order to evaluate the feasibility of safe mining close to the contact zone under reduced security coal pillar conditions at a coal mine in eastern China, the interaction mechanism of the interface between deep buri...In order to evaluate the feasibility of safe mining close to the contact zone under reduced security coal pillar conditions at a coal mine in eastern China, the interaction mechanism of the interface between deep buried sand and a paleo-weathered rock mass was investigated in the laboratory by direct shear testing. A DRS-1 high pressure soil shear testing machine and orthogonal design method were used in the direct shear tests. Variance and range methods were applied to analyze the sensitivity of each factor that has an influence on the mechanical characters of the interface. The test results show that the normal pressure is the main influencing factor for mechanical characteristics of the interface, while the lithological characters and roughness are minor factors; the shear stress against shear displacement curve for the interface shows an overall hyperbola relationship, no obvious peak stress and dilatancy was observed.When the normal pressure is 6 MPa, the shear strengths of interfaces with different roughness are basically the same, and when the normal pressure is more than 8 MPa, the larger the roughness of the interface, the larger will be the shear strength; the shear strength has a better linear relationship with the normal pressure, which can be described by a linear Mohr–Coulomb criterion.展开更多
基金This work was supported by the National Basic Research Program of China （No.2010CB923300）, the National Natural Science Foundation of China （No.91127042 and No.21173205）, the Chinese Academy of Sciences （No.XDB01020000）, the FR- FCUC （No.WK2340000012）, the USTC-NSRL Joint Funds （No.KY2340000021）, and the National Under- graduate Innovative Training Program of Ministry of Education （No.201210358064）.
文摘We investigate the fluorescence quenching of Rhodamine 6G （R6G）, a well known laser dye with a high fluorescence quantum yield, by as-synthesized graphene oxide （GO） in aqueous solution, which is found to be rather efficient. By means of steady-state and time-resolved fluorescence spectroscopy combined with detailed analysis about the linear absorption vari- ation for this R6G-GO system, the pertinent quenching mechanism has been elucidated to be a combination of dynamic and static quenching. Possible ground-state complexes be- tween R6G and GO during the static quenching have also been suggested. Furthermore, the direction of photoindueed electron transfer between R6G and GO has been discussed.
文摘Cell membranes play a crucial role in many biological functions of cells. A small change in the composition of cell membranes can strongly influence the functions of membrane-associated proteins, such as ion and water channels, and thus mediate the chemical and physical balance in cells. Such composition change could originate from the introduction of short-chain alcohols, or other anesthetics into membranes. In this work, we have applied sum frequency generation vibrational spectroscopy （SFG-VS）, supplemented by attenuated total reflectance Fourier transform infrared spectroscopy （ATR-FTIR）, to investigate interaction between methanol and 1,2-dimyristoyl-d54-sn-glycero-3-phosphocholine （d54-DMPC） lipid bilayers. Lipid＇s hydrocarbon interior is deuterated while its head group is hydrogenated. At the same time, CH3 symmetric stretch from methanol and lipid head amine group has different frequency, thus we can distinguish the behaviors of methanol, lipid head amine group, and lipid hydrocarbon interior. Based on the spectral feature of the bending mode of the water molecules replaced by methanol, we determined that the methanol molecules are intercalated into the region between amine and phosphate groups at the lipid hydrophilic head. The dipole of CH3 groups of methanol and lipid head, and the water O-H M1 adopt the same orientation directions. The introduction of methanol into the lipid hydrophilic head group can strongly perturb the entire length of the alkyl chains, resulting that the signals of CD2 and CD3 groups from both leaflets can not cancel each other.
文摘Coal pillar design has historically assigned a factor of safety(Fo S) or stability factor(SF) according to their estimated strength and the assumed overburden load acting on them. Acceptable Fo S values have been assigned based on past mining experience or a statistical link between Fo S and probability of failure(Po F). Pillar width-to-height(w/h) ratio has long been established as having a material influence on both pillar strength and its potential failure mode. However, there has been significant disagreement on using both factor of safety(Fo S) and w/h as part of pillar system stability criterion, as compared to using Fo S in isolation. This paper will argue that there are valid technical reasons to bring w/h ratio into system stability criteria(other than its influence on pillar strength), as it is related to the post-failure stiffness of the pillar, as measured in situ, and its interaction with overburden stiffness. When overburden stiffness is also brought into pillar system stability considerations, two issues emerge. The first is the width-todepth(W/D) ratio of the panel and whether it is sub-critical or super-critical from a surface subsidence perspective. The second relates to a re-evaluation of pillar Fo S based on whether the pillar is in an elastic or non-elastic(i.e., post-yield) state in its as-designed condition, as this is relevant to maintaining overburden stiffness at the highest possible level. The significance of the model is the potential to maximise both reserve recovery and mining efficiencies without any discernible increase in geotechnical risk, particularly in thick seams and higher depth of cover mining situations. At a time when mining economics are, at best, marginal, removing potentially unnecessary design conservatism is of interest to all mine operators and is an important topic for discussion amongst the geotechnical community.
基金The authors are grateful for the financial supports from the National Natural Science Foundation of China(51874351,51474251)Hunan Provincial Innovation Foundation For Postgraduate,China(CX2018B047)the Open Sharing Fund for the Large-scale Instruments and Equipments of Central South University,China(CSUZC201923).
文摘The maximum Mode Ⅰ and Mode Ⅱ stress intensity factors(SIFs), KI,kmax(θ) and KII,kmax(θ)(0°<θ<360°), of inclined parallel multi-crack varying with relative positions(including horizontal and vertical spacings) are calculated by the complex function and integration method to analyze their interacting mechanism and determine the strengthening and weakening zone of SIFs. The multi-crack initiation criterion is established based on the ratio of maximum tension-shear SIF to predict crack initiation angle, load, and mechanism. The results show that multi-crack always initiates in Mode Ⅰ and the vertical spacing is better not to be times of half crack-length for crack-arrest, which is in good agreement with test results of the red-sandstone cube specimens with three parallel cracks under uniaxial compression. This can prove the validity of the multi-crack initiation criterion.
基金the National Natural Science Foundation of China(Nos.41172290 and40572160)
文摘In order to evaluate the feasibility of safe mining close to the contact zone under reduced security coal pillar conditions at a coal mine in eastern China, the interaction mechanism of the interface between deep buried sand and a paleo-weathered rock mass was investigated in the laboratory by direct shear testing. A DRS-1 high pressure soil shear testing machine and orthogonal design method were used in the direct shear tests. Variance and range methods were applied to analyze the sensitivity of each factor that has an influence on the mechanical characters of the interface. The test results show that the normal pressure is the main influencing factor for mechanical characteristics of the interface, while the lithological characters and roughness are minor factors; the shear stress against shear displacement curve for the interface shows an overall hyperbola relationship, no obvious peak stress and dilatancy was observed.When the normal pressure is 6 MPa, the shear strengths of interfaces with different roughness are basically the same, and when the normal pressure is more than 8 MPa, the larger the roughness of the interface, the larger will be the shear strength; the shear strength has a better linear relationship with the normal pressure, which can be described by a linear Mohr–Coulomb criterion.
