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双馈风机与同步机小扰动功角互作用机理分析 被引量:26
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作者 薛安成 王清 毕天姝 《中国电机工程学报》 EI CSCD 北大核心 2016年第2期417-425,共9页
研究风机与同步机动态间的交互作用机理对于揭示风电并网对电力系统小扰动功角稳定特性的影响,指导含大规模风电的电力系统稳定控制具有重要的理论价值和现实意义。该文针对单双馈风机单同步机无穷大系统,从动态响应互作用的角度分析双... 研究风机与同步机动态间的交互作用机理对于揭示风电并网对电力系统小扰动功角稳定特性的影响,指导含大规模风电的电力系统稳定控制具有重要的理论价值和现实意义。该文针对单双馈风机单同步机无穷大系统,从动态响应互作用的角度分析双馈风机与同步机的交互作用机理。首先建立了同步机功角与双馈风机锁相环输出动态的小扰动分析模型。其次,基于小扰动分析模型解的特性,分析了不同锁相环输出动态对同步机功角动态响应的影响,以及同步机功角振荡对双馈风机锁相环输出动态的影响,揭示了双馈风机锁相环动态与同步机功角动态间的交互作用机理。研究结果表明,双馈风机锁相环和同步机动态间的交互影响与锁相环模态和同步机功角模态有关,当两模态振荡频率接近时,两模态阻尼特性将发生变化。最后,通过仿真与模态分析验证了该机理研究的正确性。 展开更多
关键词 小扰动功角稳定 双馈风机 互作用机理 锁相环 振荡模态
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移动图书馆用户信息行为对情境的作用机理研究 被引量:4
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作者 王福 梁玉芳 《图书馆》 CSSCI 北大核心 2018年第7期76-83,共8页
移动图书馆信息服务绩效决定于用户对信息接受过程的体验和感知。了解和掌握移动图书馆信息行为对信息接受情境的作用有助于发现新情境并改善其配置,进而提升服务质量。为此,从用户信息行为特征出发,对移动图书馆信息接受情境进行细化... 移动图书馆信息服务绩效决定于用户对信息接受过程的体验和感知。了解和掌握移动图书馆信息行为对信息接受情境的作用有助于发现新情境并改善其配置,进而提升服务质量。为此,从用户信息行为特征出发,对移动图书馆信息接受情境进行细化和重组,构建适合用户信息行为的信息接受情境,以各类移动图书馆为例探讨了用户信息行为对情境的作用效果。以"云舟"知识服务空间、移动知网及移动视觉搜索应用为例,对移动图书馆用户信息行为对情境的作用机理进行了实证研究,指明未来移动图书馆将向"云舟知识服务空间+移动知网+移动视觉搜索"的立体化、多层次方向发展,实现移动图书馆向数字微服务、数字微校园和数字微课堂的拓展和延伸。 展开更多
关键词 移动图书馆 信息接受情境 信息接受行为 互作用机理
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移动图书馆信息接受情境对用户信息行为的作用机理研究 被引量:16
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作者 王福 《国家图书馆学刊》 CSSCI 北大核心 2018年第1期19-30,共12页
移动图书馆信息接受情境与用户信息行为的适配程度决定了移动图书馆信息服务价值的大小。以移动图书馆信息接受情境单元为逻辑起点,从多个维度深入分析移动图书馆信息接受情境对用户信息行为的作用,探讨移动图书馆信息接受情境对用户信... 移动图书馆信息接受情境与用户信息行为的适配程度决定了移动图书馆信息服务价值的大小。以移动图书馆信息接受情境单元为逻辑起点,从多个维度深入分析移动图书馆信息接受情境对用户信息行为的作用,探讨移动图书馆信息接受情境对用户信息行为的作用机理,并以上海交通大学图书馆举办的毕业季活动和专题展览活动为例探讨情境对用户行为的作用效果。掌握移动图书馆信息接受情境对用户信息行为的作用机理有利于调控和引导用户行为以及对移动图书馆情境的改造,实现信息行为与情境的匹配,进而提升移动图书馆开发、建设和利用水平,促进知识创新和服务增值。 展开更多
关键词 移动图书馆 信息接受情境 信息接受行为 互作用机理
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基于CHIPIC软件的旭日型可调谐相对论磁控管的研究
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作者 赵桂莲 刘大刚 +1 位作者 李天明 刘腊群 《现代电子技术》 北大核心 2016年第5期140-142,146,共4页
理论推导了相对论磁控管中电子与高频场的互作用机理,采用CST软件研究冷腔状态下磁控管的π模频率,采用CHIPIC软件对磁控管进行三维粒子模拟研究,对比了10腔旭日型可调谐相对论磁控管冷热腔仿真及实验结果,验证了CHIPIC软件模拟此类器... 理论推导了相对论磁控管中电子与高频场的互作用机理,采用CST软件研究冷腔状态下磁控管的π模频率,采用CHIPIC软件对磁控管进行三维粒子模拟研究,对比了10腔旭日型可调谐相对论磁控管冷热腔仿真及实验结果,验证了CHIPIC软件模拟此类器件的正确性。研究结果表明,仿真结果与实验数据基本一致,频谱比较纯,输出比较稳定,为以后拓展旭日型可调谐相对论磁控管的调谐带宽奠定了基础。 展开更多
关键词 相对论磁控管 旭日型可调谐磁控管 CHIPIC 互作用机理
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旭日型可调谐相对论磁控管的研究与优化设计
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作者 赵桂莲 刘大刚 +1 位作者 李天明 刘腊群 《现代电子技术》 北大核心 2016年第18期142-145,共4页
理论推导了相对论磁控管中电子与高频场的互作用机理,分析了相对论磁控管阴极发射面高度、工作电压和磁场对其工作效率及调谐带宽的影响,得出进一步提高磁控管效率及调谐带宽的条件。对比了10腔旭日型可调谐相对论磁控管仿真及实验结果... 理论推导了相对论磁控管中电子与高频场的互作用机理,分析了相对论磁控管阴极发射面高度、工作电压和磁场对其工作效率及调谐带宽的影响,得出进一步提高磁控管效率及调谐带宽的条件。对比了10腔旭日型可调谐相对论磁控管仿真及实验结果,通过仿真手段进一步优化了该磁控管,提高了输出效率、拓展了调谐带宽。研究结果表明,优化后的10腔旭日型可调谐相对论磁控管具有37%的调谐带宽,电子转换效率最高达到17.9%,输出功率在1.1 GW以上。 展开更多
关键词 相对论磁控管 旭日型可调谐磁控管 互作用机理 电子转换效率
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How Graphene Oxide Quenches Fluorescence of Rhodamine 6G 被引量:1
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作者 樊凯利 郭镇坤 +4 位作者 耿志刚 葛晶 江申龙 胡嘉华 张群 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2013年第3期252-258,I0003,共8页
We investigate the fluorescence quenching of Rhodamine 6G (R6G), a well known laser dye with a high fluorescence quantum yield, by as-synthesized graphene oxide (GO) in aqueous solution, which is found to be rathe... We investigate the fluorescence quenching of Rhodamine 6G (R6G), a well known laser dye with a high fluorescence quantum yield, by as-synthesized graphene oxide (GO) in aqueous solution, which is found to be rather efficient. By means of steady-state and time-resolved fluorescence spectroscopy combined with detailed analysis about the linear absorption vari- ation for this R6G-GO system, the pertinent quenching mechanism has been elucidated to be a combination of dynamic and static quenching. Possible ground-state complexes be- tween R6G and GO during the static quenching have also been suggested. Furthermore, the direction of photoindueed electron transfer between R6G and GO has been discussed. 展开更多
关键词 Graphene oxide Rhodamine 6G Fluorescence quenching INTERACTION Mech-anism
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Methanol Perturbing Modeling Cell Membranes Investigated using Linear and Nonlinear Vibrational Spectroscopy 被引量:1
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作者 田康振 李红春 叶树集 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2013年第1期27-34,I0003,共9页
Cell membranes play a crucial role in many biological functions of cells. A small change in the composition of cell membranes can strongly influence the functions of membrane-associated proteins, such as ion and water... Cell membranes play a crucial role in many biological functions of cells. A small change in the composition of cell membranes can strongly influence the functions of membrane-associated proteins, such as ion and water channels, and thus mediate the chemical and physical balance in cells. Such composition change could originate from the introduction of short-chain alcohols, or other anesthetics into membranes. In this work, we have applied sum frequency generation vibrational spectroscopy (SFG-VS), supplemented by attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), to investigate interaction between methanol and 1,2-dimyristoyl-d54-sn-glycero-3-phosphocholine (d54-DMPC) lipid bilayers. Lipid's hydrocarbon interior is deuterated while its head group is hydrogenated. At the same time, CH3 symmetric stretch from methanol and lipid head amine group has different frequency, thus we can distinguish the behaviors of methanol, lipid head amine group, and lipid hydrocarbon interior. Based on the spectral feature of the bending mode of the water molecules replaced by methanol, we determined that the methanol molecules are intercalated into the region between amine and phosphate groups at the lipid hydrophilic head. The dipole of CH3 groups of methanol and lipid head, and the water O-H M1 adopt the same orientation directions. The introduction of methanol into the lipid hydrophilic head group can strongly perturb the entire length of the alkyl chains, resulting that the signals of CD2 and CD3 groups from both leaflets can not cancel each other. 展开更多
关键词 Sum frequency generation vibrational spectroscopy Cell membrane METHANOL INTERACTION MECHANISM
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An assessment of coal pillar system stability criteria based on a mechanistic evaluation of the interaction between coal pillars and the overburden 被引量:21
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作者 Reed Guy Mctyer Kent Frith Russell 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2017年第1期9-15,共7页
Coal pillar design has historically assigned a factor of safety(Fo S) or stability factor(SF) according to their estimated strength and the assumed overburden load acting on them. Acceptable Fo S values have been assi... Coal pillar design has historically assigned a factor of safety(Fo S) or stability factor(SF) according to their estimated strength and the assumed overburden load acting on them. Acceptable Fo S values have been assigned based on past mining experience or a statistical link between Fo S and probability of failure(Po F). Pillar width-to-height(w/h) ratio has long been established as having a material influence on both pillar strength and its potential failure mode. However, there has been significant disagreement on using both factor of safety(Fo S) and w/h as part of pillar system stability criterion, as compared to using Fo S in isolation. This paper will argue that there are valid technical reasons to bring w/h ratio into system stability criteria(other than its influence on pillar strength), as it is related to the post-failure stiffness of the pillar, as measured in situ, and its interaction with overburden stiffness. When overburden stiffness is also brought into pillar system stability considerations, two issues emerge. The first is the width-todepth(W/D) ratio of the panel and whether it is sub-critical or super-critical from a surface subsidence perspective. The second relates to a re-evaluation of pillar Fo S based on whether the pillar is in an elastic or non-elastic(i.e., post-yield) state in its as-designed condition, as this is relevant to maintaining overburden stiffness at the highest possible level. The significance of the model is the potential to maximise both reserve recovery and mining efficiencies without any discernible increase in geotechnical risk, particularly in thick seams and higher depth of cover mining situations. At a time when mining economics are, at best, marginal, removing potentially unnecessary design conservatism is of interest to all mine operators and is an important topic for discussion amongst the geotechnical community. 展开更多
关键词 Coa] pillars Stability OVERBURDEN Post-failure behaviour Stability criteria
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Interacting mechanism and initiation prediction of multiple cracks 被引量:4
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作者 Qing-qing SHEN Qiu-hua RAO +2 位作者 Zhuo LI Wei YI Dong-liang SUN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第3期779-791,共13页
The maximum Mode Ⅰ and Mode Ⅱ stress intensity factors(SIFs), KI,kmax(θ) and KII,kmax(θ)(0°<θ<360°), of inclined parallel multi-crack varying with relative positions(including horizontal and verti... The maximum Mode Ⅰ and Mode Ⅱ stress intensity factors(SIFs), KI,kmax(θ) and KII,kmax(θ)(0°<θ<360°), of inclined parallel multi-crack varying with relative positions(including horizontal and vertical spacings) are calculated by the complex function and integration method to analyze their interacting mechanism and determine the strengthening and weakening zone of SIFs. The multi-crack initiation criterion is established based on the ratio of maximum tension-shear SIF to predict crack initiation angle, load, and mechanism. The results show that multi-crack always initiates in Mode Ⅰ and the vertical spacing is better not to be times of half crack-length for crack-arrest, which is in good agreement with test results of the red-sandstone cube specimens with three parallel cracks under uniaxial compression. This can prove the validity of the multi-crack initiation criterion. 展开更多
关键词 interaction mechanism multi-crack initiation criterion initiation prediction multiple cracks stress intensity factor
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Interaction mechanism of the interface between a deep buried sand and a paleo-weathered rock mass using a high normal stress direct shear apparatus 被引量:4
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作者 Bai Hanying Li Wenping +2 位作者 Ding Qingfeng Wang Qiqing Yang Dongdong 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2015年第4期623-628,共6页
In order to evaluate the feasibility of safe mining close to the contact zone under reduced security coal pillar conditions at a coal mine in eastern China, the interaction mechanism of the interface between deep buri... In order to evaluate the feasibility of safe mining close to the contact zone under reduced security coal pillar conditions at a coal mine in eastern China, the interaction mechanism of the interface between deep buried sand and a paleo-weathered rock mass was investigated in the laboratory by direct shear testing. A DRS-1 high pressure soil shear testing machine and orthogonal design method were used in the direct shear tests. Variance and range methods were applied to analyze the sensitivity of each factor that has an influence on the mechanical characters of the interface. The test results show that the normal pressure is the main influencing factor for mechanical characteristics of the interface, while the lithological characters and roughness are minor factors; the shear stress against shear displacement curve for the interface shows an overall hyperbola relationship, no obvious peak stress and dilatancy was observed.When the normal pressure is 6 MPa, the shear strengths of interfaces with different roughness are basically the same, and when the normal pressure is more than 8 MPa, the larger the roughness of the interface, the larger will be the shear strength; the shear strength has a better linear relationship with the normal pressure, which can be described by a linear Mohr–Coulomb criterion. 展开更多
关键词 Deep buried sand Coal series Paleo-weathered rock mass Roughness of interface Mohr-Coulomb criterion
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Dissolution behaviors of Ta_2O_5,Nb_2O_5 and their mixture in KOH and H_2O system 被引量:3
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作者 王晓辉 郑诗礼 +1 位作者 徐红彬 张懿 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第10期2006-2011,共6页
The dissolution behaviors of Ta2O5,Nb2O5 and their mixture in KOH and H2O system were investigated.A L9(34) orthogonal design was used to study the effects of reaction temperature,mass ratio of KOH to Ta2O5,and reacti... The dissolution behaviors of Ta2O5,Nb2O5 and their mixture in KOH and H2O system were investigated.A L9(34) orthogonal design was used to study the effects of reaction temperature,mass ratio of KOH to Ta2O5,and reaction time on the dissolution rate of tantalum.It was found that the effect of reaction temperature on the dissolution rate of tantalum was much greater than that of the other factors.The results of factorial experiments showed that Ta2O5 was mainly transformed into insoluble potassium tantalate at low temperature(350 ℃) and transformed into soluble potassium tantalate at high temperature(450 ℃).The insoluble potassium tantalate was analyzed by XRD,which was proved to be KTaO3.Differently,almost all Nb2O5 was transformed into soluble potassium niobate at 350-450℃.As for the mixture of Ta2O5 and Nb2O5,the dissolution rate of tantalum increased and the dissolution rate of niobium decreased as an interaction existed between niobium and tantalum.And increasing the mole ratio of Nb2O5 to Ta2O5 in the mixture was beneficial to the dissolution of both Ta2O5 and Nb2O5.In addition,the mechanism of the interaction between niobium and tantalum was also investigated through phase and chemical analysis. 展开更多
关键词 TA2O5 NB2O5 KOH dissolution behavior mechanism SOLID-SOLUTION
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Inflammatory bowel disease requires the interplay between innate and adaptive immune signals 被引量:10
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作者 Dayna Shi Jyoti Das Gobardhan Das 《Cell Research》 SCIE CAS CSCD 2006年第1期70-74,共5页
Inflammatory bowl disease (IBD) is a type 1 T helper cell (Th1)-mediated autoimmune disease. Various studies have revealed that environmental pathogens also play a significant role in the initiation and progressio... Inflammatory bowl disease (IBD) is a type 1 T helper cell (Th1)-mediated autoimmune disease. Various studies have revealed that environmental pathogens also play a significant role in the initiation and progression of this disease. Interestingly, the pathogenesis of IBD has been shown to be related to nitric oxide (NO) released from innate immune cells. Although NO is known to be highly toxic to the gut epithelia, there is very little information about the regulation of NO production, One major question in the etiology of IBD is how Thl cells and pathogens interact in the induction of IBD. In present study, we focused on the regulation of NO. We show that macrophages require both interferon-γ, (IFN-γ)-mediated and TLR4-mediated signals for the production of NO, which causes inflammation in the intestine and subsequently IBD. Thus, IBD is the result of concerted actions of innate immune signals, such as the binding of LPS to TLR-4, and adaptive immune signals, such as IFN-γ produced by Thl cells. 展开更多
关键词 COLITIS innate immunity adaptive immunity nitric oxide TLR-mediated signaling
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Interaction between anti-shear galleries and surrounding rock in the right-bank slope of Dagangshan hydropower station 被引量:1
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作者 LI Lian-chong XING Ya-zi +3 位作者 LIU Xing-zong MA Ke XU Nu-wen ZHANG Fei 《Journal of Mountain Science》 SCIE CSCD 2017年第7期1428-1444,共17页
The fight-bank slope of the Dagangshan hydropower station located in Southwest China is a highly unloaded rock slope. Moreover, large-scale natural faults were detected in the slope body; some excavation-induced unloa... The fight-bank slope of the Dagangshan hydropower station located in Southwest China is a highly unloaded rock slope. Moreover, large-scale natural faults were detected in the slope body; some excavation-induced unloading fractures were discovered at elevations between lo75m and 1146m. Because of poor tectonic stability, the excavation work was suspended in September 2009, and six large- scale anti-shear galleries were employed to replace the weak zone in the slope body to reinforce the fight- bank slope. In this study, based on microseismic- monitoring technology and a numerical-simulation method, the stabilities of the slope with and without the reinforcement are analysed. An in-situ microseismic-monitofing system is used to obtain quantitative information about the damage location, extent, energy, and magnitude of the rocks. Thus, any potential sliding block in the fight-bank slope can be identified. By incorporating the numerical results along with the microseismic-monitoring data, the stress concentration is found to largely occur aroundthe anti-shear galleries, and the seismic deformation near the anti-shear galleries is apparent, particularly at elevations of 121o, 118o, 115o, and 112om. To understand the interaction mechanism between the anti-shear gallery and the surrounding rock, a 2D simulation of the potential damage process occurring in an anti-shear gallery is performed. The numerical simulation helps in obtaining additional information about the stress distribution and failure-induced stress re-distribution in the vicinity of the anti-shear galleries that cannot be directly observed in the field. Finally, the potential sliding surface of the right-bank slope is numerically obtained, which generally agrees with the spatial distribution of the in-situ monitored microseismic events. The safety factor of the slope reinforced with the anti-shear gallery increases by approximately 36.2%. Both the numerical results and microseismic data show that the anti-shear galleries have a good reinforcement effect. 展开更多
关键词 Slope stability Microseismic monitoring Numerical simulation Safety factor Anti-sheargallery
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Research on the width of filling body in gob-side entry retaining with high-water materials 被引量:10
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作者 Chang Qingliang Tang Weijun +1 位作者 Xu Ying Zhou Huaqiang 《International Journal of Mining Science and Technology》 EI CSCD 2018年第3期519-524,共6页
To determine the filling body's width along the gob-side remained roadway which is underneath the gob,the authors analyzed the interaction mechanism between the roof and the supporting body along the remained road... To determine the filling body's width along the gob-side remained roadway which is underneath the gob,the authors analyzed the interaction mechanism between the roof and the supporting body along the remained roadway, based on the elastic thin plate theory of the stope roof. The stress state and mechanical response of the filling body along the remained roadway were studied. Specifically, firstly, the supporting pressure of the coal pillar which is on one side of the gob-side remained roadway was deduced.Also, an equation that is used to calculate the width of the balance area in the stress limit state was acquired. Then, an equation that is used to calculate the roof cutting force on one side of the supporting body was obtained. By using FLAC3D, the authors investigated the displacement field and stress field response laws of rock masses around the roadway with different filling body's widths. The results show that with the filling body's width increasing, the supporting ability of the filling body increases.Meanwhile, the rock mass displacement around the roadway and the filling body deformation decrease.The better the filling body's supporting effect is, the higher the roof cutting force will be. When the filling body's width is larger than 3.0 m, its internal bearing ability becomes stable and the filling body's deformation became non-apparent. Finally, analysis shows that the filling body's width should be 2.5 m.Furthermore, the authors conducted field tests in the supply roadway 1204, using high-water materials and acquired expected outcomes. 展开更多
关键词 Gob-side entry retaining High-water materials Numerical simulation Support along the roadway
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Quantum theory analysis on microscopic mechanism of the interaction of laser with cell membrane 被引量:2
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作者 XU Lin ZHANG Can-bang +3 位作者 WANG Sheng-yu LI Ling WANG Rui-li ZHOU Ling-yun 《Optoelectronics Letters》 EI 2007年第3期234-236,共3页
On the basis of liquid crystal model with the electric dipole moment of cell membrane,the microscopic mechanism of the electricity and thermology effects of interaction of laser with cell membrane is researched by ele... On the basis of liquid crystal model with the electric dipole moment of cell membrane,the microscopic mechanism of the electricity and thermology effects of interaction of laser with cell membrane is researched by electromagnetic,quantum mechanics and quantum statistics. We derive the formulas on the polarization effects and "temperature-rising effect" of laser-cell membrane interaction. The results of the theoretical research can explain some experiments. 展开更多
关键词 激光 细胞膜 作用 显微机制 量子理论分析
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Interaction mechanism between carboxylmethyl cellulose and iron ore concentrates in iron ore agglomeration 被引量:1
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作者 杨桂明 范晓慧 +3 位作者 陈许玲 袁礼顺 黄晓贤 李曦 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第4期1241-1246,共6页
Carboxylmethyl cellulose(CMC) has become a commercial organic binder in agglomeration of iron ore concentrates. The relative molecular mass and degree of substitution(DS) of CMC have a large impact on its binding perf... Carboxylmethyl cellulose(CMC) has become a commercial organic binder in agglomeration of iron ore concentrates. The relative molecular mass and degree of substitution(DS) of CMC have a large impact on its binding performance. The interaction mechanism between CMC and iron ore particles was analyzed through Zeta potential measurements, adsorption measurements and infrared spectra. The results show that the interaction is chemical adsorption-oriented and the CMC's adsorption performance is related to the properties of CMC as well as the type of iron oxides. CMC has a greater affinity to Fe2O3 than Fe3O4, and CMC with higher relative molecular mass shows a higher adsorption isotherm. Pelletization of practical iron ore concentrates added with CMC further illustrates that CMC with higher relative molecular mass or DS exhibits a better binding performance, which is consistent with the results of adsorption tests. 展开更多
关键词 carboxylmethyl cellulose iron ore concentrate interaction mechanism adsorption agglomeration
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Adsorption Mechanism of Water Molecule on Goethite(010) Surface
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作者 XIU Fangyuan ZHOU Long +1 位作者 XIA Shuwei YU Liangmin 《Journal of Ocean University of China》 SCIE CAS 2016年第6期1021-1026,共6页
Abstract Goethite widely exists among ocean sediments; it plays an important role in fixing heavy metals and adsorbing organic contaminants. So the understanding of the adsorbing process of water molecule on its surfa... Abstract Goethite widely exists among ocean sediments; it plays an important role in fixing heavy metals and adsorbing organic contaminants. So the understanding of the adsorbing process of water molecule on its surface will be very helpful to further reveal such environmental friendly processes. The configuration, electronic properties and interaction energy of water molecules adsorbed on pnma goethite (010) surface were investigated in detail by using density functional theory on 6-31G (d,p) basis set and projec- tor-augment wave (PAW) method. The mechanism of the interaction between goethite surface and H20 was proposed. Despite the differences in total energy, there are four possible types of water molecule adsorption configurations on goethite (010) surface (Aa, Ab, Ba, Bb), forming coordination bond with surface Fe atom. Results of theoretical modeling indicate that the dissociation process of adsorbed water is an endothermic reaction with high activation energy. The dissociation of adsorbed water molecule is a proton transportation process between water's O atoms and surface. PDOS results indicate that the bonding between 1-120 and (010) surface is due to the overlapping of water's 2p orbitals and Fe's 3d orbitals. These results clarify the mechanism on how adsorbed water is dissociated on the surface of goethite and potentially provide useful information of the surface chemistry of goethite. 展开更多
关键词 density functional theory GOETHITE WATER ADSORPTION
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Mechanism research of gas and coal dust explosion 被引量:1
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作者 ZHANG Yan-song HAN Li-li WANG Lei 《Journal of Coal Science & Engineering(China)》 2009年第2期171-174,共4页
Combined with the experimental results from the large tunnel of the ChongqingResearch Institute,the mechanism of gas and coal dust explosion was studied.Someconcepts about gas and coal dust explosion were introduced s... Combined with the experimental results from the large tunnel of the ChongqingResearch Institute,the mechanism of gas and coal dust explosion was studied.Someconcepts about gas and coal dust explosion were introduced such as the form conditionand influential factors.Gas and coal dust explosion propagation was researched and thelifting process of coal dust was simulated.When an explosion occurred due to great mixtureof gas and air,the maximum explosion pressure appeared in the neighborhood of theexplosion source point.Before it propagated to the tunnel of the deposited coal dust,themaximum explosion pressure appeared to be in declining trend.Part of the energy waslost in the process of raising the deposited coal dust through a shock wave,so the maximumexplosion pressure was smallest on the foreside of the deposited coal dust sector.On the deposited coal dust sector,the explosion pressure rapidly increased and droppedoff after achieving the largest peak value.Because of coal dust participation in the explosion,the flame velocity rose rapidly on the deposited coal dust and achieved a basic stablevalue;coal dust was ignited to explode by initial laminar flame,and the laminar flametransformed into turbulent flame.The turbulence transformed the flame fold into a funnelshape and the shock wave interacted with the flame,so the combustion rate rose and thepressure wave was further enhanced.The regeneration mechanism between the flamecombustion rate and the aerodynamic flowing structure achieved the final critical state forforming the detonation. 展开更多
关键词 gas and coal dust explosion mechanism research influence factor coal dust hoisted process
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Molecular Dynamics Simulation on Scale Inhibition Mechanism of Polyepoxysuccinic Acid to Calcium Sulphate 被引量:5
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作者 Jian-ping Zeng Feng-he Wang +1 位作者 Chen Zhou Xue-dong Gong 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2012年第2期219-225,I0004,共8页
Molecular dynamics simulation has been performed to simulate the interaction between PESA and the (001) face of anhydrite crystal CaSO4 at different temperatures with the presence of various number of H2O molecules.... Molecular dynamics simulation has been performed to simulate the interaction between PESA and the (001) face of anhydrite crystal CaSO4 at different temperatures with the presence of various number of H2O molecules. The results show that PESA can effectively prevent the growth of CaSO4 scale at 323-343 K. At the same temperature, the binding energy between PESA and the (001) face of CaSO4 for systems with various number of H2O has the order of E-bind(OH2O)〉Ebind(200-400H2O)〉E, bind(lOOH2O). For the same system at different temperatures the binding energies are close and are mainly contributed from the Coulomb interaction, including ionic bonds. The bonds are formed between the calcium atoms of anhydrite scale crystal and the Hydrogen bonds are formed between the O oxygen atoms of the carboxyl group of PESA. atoms of the carboxyl group of PESA and the H atoms of H2O. van der Waals interaction is conducive to the stability of the system of PESA, H2O, and CaSO4. The radial distribution functions of O(carbonyl of PESA)-H(H2O), O(CaSO4)-H(H2O), and O(CaSO4)-H(PESA) imply that solvents have effects on the anti-scale performance of PESA to CaSO4. 展开更多
关键词 Polyepoxysuccinic acid Calcium sulphate Molecular dynamics Binding en-ergy Radial distribution function
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The Mechanism of Henipavirus Fusion:Examining the Relationships between the Attachment and Fusion Glycoproteins
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作者 Andrew C. Hickey Christopher C. Broder 《Virologica Sinica》 SCIE CAS CSCD 2009年第2期110-120,共11页
The henipaviruses,represented by Nipah virus and Hendra virus,are emerging zoonotic viral pathogens responsible for repeated outbreaks associated with high morbidity and mortality in Australia,Southeast Asia,India and... The henipaviruses,represented by Nipah virus and Hendra virus,are emerging zoonotic viral pathogens responsible for repeated outbreaks associated with high morbidity and mortality in Australia,Southeast Asia,India and Bangladesh. These viruses enter host cells via a class I viral fusion mechanism mediated by their attachment and fusion envelope glycoproteins;efficient membrane fusion requires both these glycoproteins in conjunction with specific virus receptors present on susceptible host cells. The henipavirus attachment glycoprotein interacts with a cellular B class ephrin protein receptor triggering conformational alterations leading to the activation of the viral fusion(F) glycoprotein. The analysis of monoclonal antibody(mAb) reactivity with G has revealed measurable alterations in the antigenic structure of the glycoprotein following its binding interaction with receptor. These observations only appear to occur with full-length native G glycoprotein,which is a tetrameric oligomer,and not with soluble forms of G(sG) ,which are disulfide-linked dimers. Single amino acid mutations in a heptad repeat-like structure within the stalk domain of G can disrupt its association with F and subsequent membrane fusion promotion activity. Notably,these mutants of G also appear to confer a post-receptor bound conformation implicating the stalk domain as an important element in the G glycoprotein's structure and functional relationship with F. Together,these observations suggest fusion is dependent on a specific interaction between the F and G glycoproteins of the henipaviruses. Further,receptor binding induces measurable changes in the G glycoprotein that appear to be greatest in respect to the interactions between the pairs of dimers comprising its native tetrameric structure. These receptor-induced conformational changes may be associated with the G glycoprotein's promotion of the fusion activity of F. 展开更多
关键词 Hendra virus Nipah virus Henipavirus PARAMYXOVIRUS Viral entry
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