With the rapid development of China' s tourism industry, the country in various regional economy hotels has sprung up everywhere. Economical hotels affected due to low prices of factors, more and more pro-consumer ga...With the rapid development of China' s tourism industry, the country in various regional economy hotels has sprung up everywhere. Economical hotels affected due to low prices of factors, more and more pro-consumer gaze. Customers source a large part of budget hotels are from users, how to promote their hotel through the Internet is a problem that must be considered by the economy hotel, the paper through the study of economy hotel email marketing strategy wants to Economical hotels certain significance.展开更多
The high-temperature(HT) and low-temperature(LT) hydrothermal stabilities of molecular-sieve-based catalysts are important for the selective catalytic reduction of NOx with ammonia(NH3-SCR). In this paper, we report a...The high-temperature(HT) and low-temperature(LT) hydrothermal stabilities of molecular-sieve-based catalysts are important for the selective catalytic reduction of NOx with ammonia(NH3-SCR). In this paper, we report a catalyst, Cu2+ loading SAPO-17, synthesized using cyclohexylamine(CHA), which is commercially available and inexpensive and is utilized in NH3-SCR reduction for the first time. After systematic investigations on the optimization of Si and Cu2+ contents, it was concluded that Cu-SAPO-17-8.0%-0.22 displays favorable catalytic performance, even after being heated at 353 K for 24 h and at 973 K for 16 h. Moreover, the locations of CHAs, host–guest interaction and the Bronsted acid sites were explored by Rietveld refinement against powder X-ray diffraction data of as-made SAPO-17-8.0%. The refinement results showed that two CHAs exist within one eri cage and that the protonated CHA forms a hydrogen bond with O4, which indicates that the proton bonding with O4 will form the Bronsted acid site after the calcination.展开更多
In this writing, I reconstruct the Principle of Complementarity in Quantum Mechanics, elaborated by Niels Bohr, and the conception of objectivity implied in it (and in Bohr's writings). Then, I connect it with the ...In this writing, I reconstruct the Principle of Complementarity in Quantum Mechanics, elaborated by Niels Bohr, and the conception of objectivity implied in it (and in Bohr's writings). Then, I connect it with the epistemological pragmatism of the philosopher Richard Rorty. My aim is to reinterpret some issues of this quantum description that concern the category of objectivity from the Rortian perspective in a plausible way. This allows me to connect in a positive and a negative sense some quantum (and Bohrian) assumptions to the Rortian perspective, but mainly, it allows to reconsider the framework of scientific objects from the modern perspective to a new pragmatist and anti-essentialist point of view.展开更多
Advancements in the internet technology triggered a line of developments in the field of marketing. As an alternative to the conventional shopping, online shopping over the internet has gained substantial share of ret...Advancements in the internet technology triggered a line of developments in the field of marketing. As an alternative to the conventional shopping, online shopping over the internet has gained substantial share of retail market. Customers get used to this new shopping venue and nowadays prefer it more and more according to the researchers, ten percent of the global population now uses internet for shopping. In this research, the author explored the relationship between the security measures implemented by a company, very active in the online shopping domain, and the customer trust and loyalty on the online services provided by this company. Findings of this research are based on survey data analyzed in SPSS. This research supports the existence of a relationship between the security of a company's website and customer trust and loyalty on the online services of this company When the perception of security measures improves, customer trust and loyalty increases accordingly展开更多
Intensity of competition, especially global competition, has driven many organizations to search for innovative ways to improve productivity and performance. This trend has led many firms to adopt approaches to implem...Intensity of competition, especially global competition, has driven many organizations to search for innovative ways to improve productivity and performance. This trend has led many firms to adopt approaches to implement cloud systems. Cloud systems have distinct characteristics that differentiate it from traditional internet services, due to a number of significant innovation factors. For example, firms need improved access to high-speed intemet as well as access to customer relationship management (CRM) and enterprise resource planning (ERP) capacities. This means that the interest of many firms in the implementation of cloud systems has increased. Although cloud systems are designed to facilitate knowledge transfer, currently, there is no method to ensure that knowledge transfer is useful or relevant to a firm. This in turn means that finns need to ensure that the cloud system has the capabilities to screen knowledge for compliance against some known knowledge characteristics. The use of cloud systems could result in an efficient delivery of innovation knowledge in an effective way. This paper presents an approach for assessment of the successful implementation of cloud systems. This paper also discusses the various success factors of cloud systems for global innovation.展开更多
Three guests with two moiety probes for different Cucurbit[n = 6—8]urils have been synthesized. They are N-(2-methylenethiophen)-adamataneamine, N-(2-methylene pyrrole)- adamataneamine and N-(2-methylenefurfuran)-ada...Three guests with two moiety probes for different Cucurbit[n = 6—8]urils have been synthesized. They are N-(2-methylenethiophen)-adamataneamine, N-(2-methylene pyrrole)- adamataneamine and N-(2-methylenefurfuran)-adamataneamine. The probes are methyle-nepyridyl typically for Q[6] and adamataneamine typically for Q[7]. The host-guest complexes of Cucurbit[n = 6—8]urils with these guests have been investigated by using NMR techniques and ESMS method. Also, thermoanalysis has been used for exploring relationship of enthalpy and stability of the host-guest complexes.展开更多
Based on specific host-guest interactions between amine-modified [3-cyclodextrin (CD-TAEA) and functional adamantane (AD) derivatives, a module-template strategy has been proposed for the construction of low-molec...Based on specific host-guest interactions between amine-modified [3-cyclodextrin (CD-TAEA) and functional adamantane (AD) derivatives, a module-template strategy has been proposed for the construction of low-molecular-weight cationic assem- blies for gene transport. This strategy offers great flexibility in terms of the introduction of mono- or multi-functionality by the inclusion of one or more adamantane-based modules with the desired functionalities. As proof of concept, phenylboronic acid (PB) containing adamantane (PB-AD) was used as a model module in the hope of offering enhanced cytosolic delivery in con- sideration of the special affinity of PB groups with cell membranes. The physicochemical properties of the complexes formed with plasmid DNA, such as particle size, zeta potential and morphology were investigated. Confocal laser scanning microsco- py and flow cytometry experiments demonstrated the important contribution of the functional PB-AD module to the consider- ably enhanced intracellular internalization and uptake by cellular nuclei. Compared to the parent CD-TAEA, PB-AD/CD- TAEA assemblies mediated higher transfection rates, which were even comparable to that of PEI25K. In addition, PB-AD/CD- TAEA displayed much lower cytotoxicity than PEI25K in both 293T and HeLa cell lines. The encouraging results suggest that CD-TAEA can be developed as a powerful template capable of readily accommodating various AD-based modules giving versatile functionalities for improved transfection.展开更多
CO2 capture,especially under low-pressure range,is of significance to maintain long-duration human operation in confined spaces and decrease the CO2 corrosion and freezing effect for the liquefaction of natural gas.He...CO2 capture,especially under low-pressure range,is of significance to maintain long-duration human operation in confined spaces and decrease the CO2 corrosion and freezing effect for the liquefaction of natural gas.Herein,we for the first time report a novel anion-functionalized ZU-16-Co(TIFSIX-3-Co,TIFSIX=hexafluorotitanate(TiF62−),3=pyrazine),which exhibits one-dimensional pore channels decorated by abundant F atoms,for efficient CO2 capture at a concentration around 400–10,000 ppm.Among its isostructural MFSIX-3(M=Si,Ti,Ge)family materials,ZU-16-Co with fine-tuned pore size of 3.62Åexhibits the highest CO2 uptake at 0.01 bar(10,000 ppm)and 1 bar(2.63 and 2.87 mmol g−,respectively).The high CO2 capture ability of ZU-16-Co originates from the fine-tuned pore dimensions with strong F⋯C=O host-guest interactions and relatively large pore volumes coming from its longer coordinated Ti-F-Co distance(3.9Å)in c direction.The excellent carbon trapping performance was further verified by dynamic breakthrough tests for CO2/N2(1/99 and 15/85)and CO2/CH4(50/50)mixtures.The adsorption and separation performances,resulting from the fine-tuned pore system with periodic arrays of exposed functionalities,demonstrate that ultramicroporous ZU-16-Co can be a promising adsorbent for low-concentration carbon capture.展开更多
A complex micelle as a hemoglobin functional model with the biaoactive function of reversible oxygen transfer has been constructed through the hierarchical assembly of the diblock copolymer poly(ethylene glycol)-blo...A complex micelle as a hemoglobin functional model with the biaoactive function of reversible oxygen transfer has been constructed through the hierarchical assembly of the diblock copolymer poly(ethylene glycol)-block- poly(4-vinylpyridine-co-N-heptyl-4-vinylpyridine) (PEG-b-P(4VP-co-4VPHep)), tetrakis(4-sulfonatophenyl)porphinato iron(II) (Fe(II)TPPS) and β-cyclodextrin (β-CD). The μ-oxo dimer of Fe(II)TPPS was successfully inhibited because the Fe(II)TPPS was included into the cavities of β-CDs through host-guest interaction. Fe(II)TPPS coordinated with pyridine groups functions as the active site to reversibly bind dioxygen. In adition, the host-guest inclusion (β-CD/Fe(II)TPPS) was encapsulated in the hydrophobic core of the complex micelle and tightly fixed by P4VP chains. The hydrophilic PEG blocks stretched in aqueous solution to constitute the shells which stabilize the structure of the complex micelle as well as endow the complex micelle with sufficient blood circulation time. Dioxygen can be bound to the Fe(II)TPPS located in the confined space and excellent reversibility of the binding-release process of dioxygen can be achieved. The quaternary amine N-heptyl-4-vinylpyridine can coerce abundant S2O4^2- ions into the core of the complex micelle to facilitate the self-reduction process. Dioxygen adducts (Fe(II)TPPS(O2)) were effectively protected by the double hydrophobic barriers constructed by the cavity of the cyclodextrin and the core of the complex micelle which enhances the ability to resist nucleophilic molecules. Therefore, the rationally designed amphiphilic structure can work as a promising artificial O2 carrier. Potentially, the complex micelle can be expected to improve the treatment of diseases linked with hypoxia.展开更多
文摘With the rapid development of China' s tourism industry, the country in various regional economy hotels has sprung up everywhere. Economical hotels affected due to low prices of factors, more and more pro-consumer gaze. Customers source a large part of budget hotels are from users, how to promote their hotel through the Internet is a problem that must be considered by the economy hotel, the paper through the study of economy hotel email marketing strategy wants to Economical hotels certain significance.
文摘The high-temperature(HT) and low-temperature(LT) hydrothermal stabilities of molecular-sieve-based catalysts are important for the selective catalytic reduction of NOx with ammonia(NH3-SCR). In this paper, we report a catalyst, Cu2+ loading SAPO-17, synthesized using cyclohexylamine(CHA), which is commercially available and inexpensive and is utilized in NH3-SCR reduction for the first time. After systematic investigations on the optimization of Si and Cu2+ contents, it was concluded that Cu-SAPO-17-8.0%-0.22 displays favorable catalytic performance, even after being heated at 353 K for 24 h and at 973 K for 16 h. Moreover, the locations of CHAs, host–guest interaction and the Bronsted acid sites were explored by Rietveld refinement against powder X-ray diffraction data of as-made SAPO-17-8.0%. The refinement results showed that two CHAs exist within one eri cage and that the protonated CHA forms a hydrogen bond with O4, which indicates that the proton bonding with O4 will form the Bronsted acid site after the calcination.
文摘In this writing, I reconstruct the Principle of Complementarity in Quantum Mechanics, elaborated by Niels Bohr, and the conception of objectivity implied in it (and in Bohr's writings). Then, I connect it with the epistemological pragmatism of the philosopher Richard Rorty. My aim is to reinterpret some issues of this quantum description that concern the category of objectivity from the Rortian perspective in a plausible way. This allows me to connect in a positive and a negative sense some quantum (and Bohrian) assumptions to the Rortian perspective, but mainly, it allows to reconsider the framework of scientific objects from the modern perspective to a new pragmatist and anti-essentialist point of view.
文摘Advancements in the internet technology triggered a line of developments in the field of marketing. As an alternative to the conventional shopping, online shopping over the internet has gained substantial share of retail market. Customers get used to this new shopping venue and nowadays prefer it more and more according to the researchers, ten percent of the global population now uses internet for shopping. In this research, the author explored the relationship between the security measures implemented by a company, very active in the online shopping domain, and the customer trust and loyalty on the online services provided by this company. Findings of this research are based on survey data analyzed in SPSS. This research supports the existence of a relationship between the security of a company's website and customer trust and loyalty on the online services of this company When the perception of security measures improves, customer trust and loyalty increases accordingly
文摘Intensity of competition, especially global competition, has driven many organizations to search for innovative ways to improve productivity and performance. This trend has led many firms to adopt approaches to implement cloud systems. Cloud systems have distinct characteristics that differentiate it from traditional internet services, due to a number of significant innovation factors. For example, firms need improved access to high-speed intemet as well as access to customer relationship management (CRM) and enterprise resource planning (ERP) capacities. This means that the interest of many firms in the implementation of cloud systems has increased. Although cloud systems are designed to facilitate knowledge transfer, currently, there is no method to ensure that knowledge transfer is useful or relevant to a firm. This in turn means that finns need to ensure that the cloud system has the capabilities to screen knowledge for compliance against some known knowledge characteristics. The use of cloud systems could result in an efficient delivery of innovation knowledge in an effective way. This paper presents an approach for assessment of the successful implementation of cloud systems. This paper also discusses the various success factors of cloud systems for global innovation.
文摘Three guests with two moiety probes for different Cucurbit[n = 6—8]urils have been synthesized. They are N-(2-methylenethiophen)-adamataneamine, N-(2-methylene pyrrole)- adamataneamine and N-(2-methylenefurfuran)-adamataneamine. The probes are methyle-nepyridyl typically for Q[6] and adamataneamine typically for Q[7]. The host-guest complexes of Cucurbit[n = 6—8]urils with these guests have been investigated by using NMR techniques and ESMS method. Also, thermoanalysis has been used for exploring relationship of enthalpy and stability of the host-guest complexes.
基金supported by the National Basic Research Program of China(2011CB606202)the National Natural Science Foundation of China(21174110)+1 种基金the Ministry of Education of China(20120141130003)the Fundamental Research Funds for the Central Universities(2012203020210)
文摘Based on specific host-guest interactions between amine-modified [3-cyclodextrin (CD-TAEA) and functional adamantane (AD) derivatives, a module-template strategy has been proposed for the construction of low-molecular-weight cationic assem- blies for gene transport. This strategy offers great flexibility in terms of the introduction of mono- or multi-functionality by the inclusion of one or more adamantane-based modules with the desired functionalities. As proof of concept, phenylboronic acid (PB) containing adamantane (PB-AD) was used as a model module in the hope of offering enhanced cytosolic delivery in con- sideration of the special affinity of PB groups with cell membranes. The physicochemical properties of the complexes formed with plasmid DNA, such as particle size, zeta potential and morphology were investigated. Confocal laser scanning microsco- py and flow cytometry experiments demonstrated the important contribution of the functional PB-AD module to the consider- ably enhanced intracellular internalization and uptake by cellular nuclei. Compared to the parent CD-TAEA, PB-AD/CD- TAEA assemblies mediated higher transfection rates, which were even comparable to that of PEI25K. In addition, PB-AD/CD- TAEA displayed much lower cytotoxicity than PEI25K in both 293T and HeLa cell lines. The encouraging results suggest that CD-TAEA can be developed as a powerful template capable of readily accommodating various AD-based modules giving versatile functionalities for improved transfection.
基金the National Natural Science Foundation of China(21938011,U1862110,21890764 and21725603)the National Program for Support of Top-notch Young Professionals(H.X.)。
文摘CO2 capture,especially under low-pressure range,is of significance to maintain long-duration human operation in confined spaces and decrease the CO2 corrosion and freezing effect for the liquefaction of natural gas.Herein,we for the first time report a novel anion-functionalized ZU-16-Co(TIFSIX-3-Co,TIFSIX=hexafluorotitanate(TiF62−),3=pyrazine),which exhibits one-dimensional pore channels decorated by abundant F atoms,for efficient CO2 capture at a concentration around 400–10,000 ppm.Among its isostructural MFSIX-3(M=Si,Ti,Ge)family materials,ZU-16-Co with fine-tuned pore size of 3.62Åexhibits the highest CO2 uptake at 0.01 bar(10,000 ppm)and 1 bar(2.63 and 2.87 mmol g−,respectively).The high CO2 capture ability of ZU-16-Co originates from the fine-tuned pore dimensions with strong F⋯C=O host-guest interactions and relatively large pore volumes coming from its longer coordinated Ti-F-Co distance(3.9Å)in c direction.The excellent carbon trapping performance was further verified by dynamic breakthrough tests for CO2/N2(1/99 and 15/85)and CO2/CH4(50/50)mixtures.The adsorption and separation performances,resulting from the fine-tuned pore system with periodic arrays of exposed functionalities,demonstrate that ultramicroporous ZU-16-Co can be a promising adsorbent for low-concentration carbon capture.
文摘A complex micelle as a hemoglobin functional model with the biaoactive function of reversible oxygen transfer has been constructed through the hierarchical assembly of the diblock copolymer poly(ethylene glycol)-block- poly(4-vinylpyridine-co-N-heptyl-4-vinylpyridine) (PEG-b-P(4VP-co-4VPHep)), tetrakis(4-sulfonatophenyl)porphinato iron(II) (Fe(II)TPPS) and β-cyclodextrin (β-CD). The μ-oxo dimer of Fe(II)TPPS was successfully inhibited because the Fe(II)TPPS was included into the cavities of β-CDs through host-guest interaction. Fe(II)TPPS coordinated with pyridine groups functions as the active site to reversibly bind dioxygen. In adition, the host-guest inclusion (β-CD/Fe(II)TPPS) was encapsulated in the hydrophobic core of the complex micelle and tightly fixed by P4VP chains. The hydrophilic PEG blocks stretched in aqueous solution to constitute the shells which stabilize the structure of the complex micelle as well as endow the complex micelle with sufficient blood circulation time. Dioxygen can be bound to the Fe(II)TPPS located in the confined space and excellent reversibility of the binding-release process of dioxygen can be achieved. The quaternary amine N-heptyl-4-vinylpyridine can coerce abundant S2O4^2- ions into the core of the complex micelle to facilitate the self-reduction process. Dioxygen adducts (Fe(II)TPPS(O2)) were effectively protected by the double hydrophobic barriers constructed by the cavity of the cyclodextrin and the core of the complex micelle which enhances the ability to resist nucleophilic molecules. Therefore, the rationally designed amphiphilic structure can work as a promising artificial O2 carrier. Potentially, the complex micelle can be expected to improve the treatment of diseases linked with hypoxia.