期刊文献+
共找到4篇文章
< 1 >
每页显示 20 50 100
亚表面引发原子转移自由基聚合制备牢固的嵌入式聚合物刷 被引量:2
1
作者 马正峰 刘强 +4 位作者 吴杨 李斌 于波 刘钦泽 周峰 《中国科学:化学》 CAS CSCD 北大核心 2018年第12期1611-1618,共8页
本文展示了一种新的材料表面改性方法:原子转移自由基聚合(sSI-ATRP)的亚表面修饰,即通过ATRP反应在聚合物材料界面嵌入聚合物刷,构筑稳定的、厚的聚合物亚表面层.首先,将ATRP引发剂分子通过共价键引入到丙烯酸树脂、聚氨酯、聚酯、环... 本文展示了一种新的材料表面改性方法:原子转移自由基聚合(sSI-ATRP)的亚表面修饰,即通过ATRP反应在聚合物材料界面嵌入聚合物刷,构筑稳定的、厚的聚合物亚表面层.首先,将ATRP引发剂分子通过共价键引入到丙烯酸树脂、聚氨酯、聚酯、环氧树脂等聚合物材料中,然后该基底材料在含有催化剂的单体溶液中引发表面原子转移自由基聚合.表面接枝的亲水聚合物刷使材料的表面变得亲水并发生溶胀,使得单体溶液可以进一步接触到材料内部的引发剂而引发新的ATRP反应,该过程不断重复,最后在基材表面上形成几十微米厚的聚合物刷改性的亚表面层.与传统的表面接枝的聚合物刷相比,这种嵌入式的聚合物刷赋予材料表面改性层更好的机械性能,可承受高载摩擦和更好的抗海生物附着特性,且在改性亚表面层破坏后,不需要引发剂修饰组装而再次重复引发聚合改性. 展开更多
关键词 聚合物刷 亚表面层 原子转移自由基引发聚合 表面改性 可再引发
原文传递
5-100A整流管芯片台面造型与电压击穿
2
作者 程德明 胡建业 胡文新 《科技传播》 2012年第19期85-86,共2页
对5-100A整流管芯片的垂直边缘面的各种台面结构,根据电中性原理,讨论了其内部关于正负电荷、电力线、电场强度和等势线的分布关系,推导出了各种台面结构在反向电压下的击穿状态理论。选择合适的化学腐蚀造型工艺,使产品在加上反向雪崩... 对5-100A整流管芯片的垂直边缘面的各种台面结构,根据电中性原理,讨论了其内部关于正负电荷、电力线、电场强度和等势线的分布关系,推导出了各种台面结构在反向电压下的击穿状态理论。选择合适的化学腐蚀造型工艺,使产品在加上反向雪崩电压时处于体击穿状态,避免表面击穿或亚表面层击穿。 展开更多
关键词 垂直边缘面 台面造型 表面软击穿 雪崩体击穿 亚表面层击穿
下载PDF
ZOOPLANKTON COMMUNITY STRUCTURE OF THE SEA SURFACE MICROLAYER NEAR NUCLEAR POWER PLANTS AND MARINE FISH CULTURE ZONES IN DAYA BAY 被引量:1
3
作者 杨宇峰 王肇鼎 +1 位作者 潘明祥 焦念志 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2002年第2期129-134,共6页
The authors’ surveys in May-June 1999 (two cruises) at six sampling stations near nuclear power plants (NPP) and marine fish culture zones in Daya Bay, Guangdong, revealed species composition, densities and body-size... The authors’ surveys in May-June 1999 (two cruises) at six sampling stations near nuclear power plants (NPP) and marine fish culture zones in Daya Bay, Guangdong, revealed species composition, densities and body-size of the sea surface microlayer (SM) zooplankton (>35 μm). Results showed that protozoans and copepod nauplii were the predominant components, accounting for 65.40% to 95.56% of total zooplankton in abundance. The size-frequency distributions showed that the frequency of micro-zooplankton (0.02-0.2 mm) reached 0.8235. The SM zooplankton community structure revealed in the present study was quite different from that revealed by investigations in the 1980s in Daya Bay. Difference of sampling method has important influence on the obtained zooplankton community structure. SM zooplankton consisted of micro- and mesozooplankton (0.2-2.0 mm), with micro-zooplankton being predominant. Some possible cause-effect relations between the zooplankton community structure and mariculture, nuclear power plants cooling systems and sampling method are discussed. 展开更多
关键词 ZOOPLANKTON sea surface microlayer Daya Bay
下载PDF
Enhanced performances of polypropylene membranes by molecular layer deposition of polyimide 被引量:1
4
作者 Sen Xiong Ting Sheng +3 位作者 Liang Kong Zhaoxiang Zhong Jun Huang Yong Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2016年第7期843-849,共7页
Molecular layer deposition (MLD) for the deposition of polyimide (PI) at low temperature of 110 ℃ has been firstly introduced into the field of membrane separation. With the optimized MLD deposition parameters, s... Molecular layer deposition (MLD) for the deposition of polyimide (PI) at low temperature of 110 ℃ has been firstly introduced into the field of membrane separation. With the optimized MLD deposition parameters, such low de- position temperature has successfully expanded the application of MLD for the surface modification of polymeric materials. Globular PI particulates grow on both the free surfaces as well as the pore walls of the polypropylene (PP) membranes as isolated islands during progressive precursor exposures. The PI-deposited PP membranes ex- hibit synergistically improved performances in various aspects. Evidently improved surface hydrophilicity and per- meation performance (30%) have been achieved v/a the MLD deposition of polyimide films. The overall separation efficiency maintained higher than 85% even after 250 cycles of MLD deposition. More importantly, the thermal sta- bility has been improved and the integrity of the porous structure for PI-deposited PP membranes has been well preserved even after harsh treatment, which ensures its potential application in industries. 展开更多
关键词 Molecular layer depositionPolyimidePolypropyleneMembranesModification
下载PDF
上一页 1 下一页 到第
使用帮助 返回顶部