变换热交换器的防腐措施

变换热交换器的防腐措施任东（沈阳市辽中化工总厂化工研究所）我省一些小氮肥厂的变换热交换器的腐蚀，至今仍然是一个没有完全解决的问题。有些新安装的热交换器，使用几个月就被腐蚀穿漏，无法维持生产。有的寿命连一个月都不到就需更换，对生产威胁很大。变换热交换器...

变换热交换器的腐蚀与防腐的探讨

变换热交换器的腐蚀与防腐的探讨河南省化工设计院潘惠华，尹玉兰小化肥厂变换热交换器的腐蚀问题困扰不少生产厂家。有的使用一年，有的使用半年，更有甚者投入使用不到一个月就腐蚀穿孔，泄漏，被迫停产检修更换。这不仅浪费大量钢材，检修更换设备所造成的停产损失，远...

在用变换热交换器的腐蚀失效及检验要点

化工系统所用压力容器种类多，数量大；生产工艺复杂，运行参数高；同时介质又具有易燃、有毒、腐蚀等特性，故发生事故造成的危害性很大。不过每种化工工艺条件又具有相似性，使用中发生缺陷也有一定的规律。这就需要检验人员了解介质特性，熟悉生产工艺。

几类多元灰色关联模型性质的度量

文章针对多元灰色关联模型的适用范围和应用领域缺乏理论研究和依据的问题,将基于一元序列灰色关联度的平行性、一致性、仿射性和仿射变换保序性扩展至多元时间序列,并基于多元特性,给出了行交换变换不变性的定义,从理论角度对几类多元灰色关联度的性质进行了证明。研究表明,扩展灰色绝对关联度满足平行性,灰色网格关联度满足一致性,灰色矩阵相似关联度满足行交换变换不变性,没有任何一种关联度满足仿射性和仿射变换保序性。

OPTIMIZATION OF WDM OPTICAL PACKET SWITCHES WITH SPARSE WAVELENGTH CONVERTERS AND NON-DEGENERATE FIBER DELAY-LINES

This paper investigates the untraditional approach of contention resolution in Wavelength Division Multiplexing (WDM) Optical Packet Switching (OPS). The most striking characteristics of the developed switch architecture are: (1) Contention resolution is achieved by a combined sharing of Fiber Delay-Lines (FDLs) and Tunable Optical Wavelength Converters (TOWCs); (2) FDLs are arranged in non-degenerate form, i.e., non-uniform distribution of the delay lines; (3) TOWCs just can perform wavelength conversion in partial continuous wavelength channels, i.e., sparse wavelength conversion. The concrete configurations of FDLs and TOWCs are described and analyzed under non-bursty and bursty traffic scenarios. Simulation results demonstrate that for a prefixed packet loss probability constraint, e.g., 10-6, the developed architecture provides a different point of view in OPS design. That is, combined sharing of FDLs and TOWCs can, effectively, obtain a good tradeoff between the switch size and the cost, and TOWCs which are achieved in sparse form can also decrease the implementing complexity.

Unitary Transformation in kq Representation

In this paper,we discuss the unitary transformation induced by Z_6 rotations of noncommutative space onthe states |k,q,s〉,which plays a key role in construction for noncommutative solitons T^2/Z_6 by GHS method.As aresult,we prove a well-known 'Gauss Sum' formula in the number theory through a concise way.

Production of biodiesel from waste vegetable oil using impregnated diatomite as heterogenous catalyst

In this study, biodiesel was produced from waste vegetable oil using a heterogeneous base catalyst synthesized by impregnating potassium hydroxide(KOH) onto diatomite. Response surface methodology based on a central composite design was used to optimize four transesterification variables: temperature(30–120 °C), reaction time(2–6 h), methanol to oil mass ratio(10%–50%) and catalyst to oil mass ratio(2.1%–7.9%). A quadratic polynomial equation was obtained to correlate biodiesel yield to the transesterification variables. The diatomite–KOH catalyst was characterized using X-ray diffraction(XRD), Fourier transform infra-red spectroscopy(FTIR) and a scanning electron microscope(SEM) equipped with an energy dispersive X-ray detector(EDS). A maximum biodiesel yield of 90%(by mass) was obtained. The reaction conditions were as follows: methanol to oil mass ratio 30%, catalyst to oil mass ratio 5%, reaction time 4 h, and reaction temperature 75 °C. The XRD, FTIR and SEM(EDS) results confirm that the addition of KOH modifies the structure of diatomite. During impregnation and calcination of the diatomite catalyst the K2 O phase forms in the diatomite structural matrix and the active basicity of this compound facilitates the transesterification process. It is possible to recycle the diatomite–KOH catalyst up to three times. The crucial biodiesel properties from waste vegetable oil are within the American Standard Test Method specifications.

MoO_3/SO_4^(2-)-TiO_2 catalyst for transesterification of dimethyl cabonate with phenol

A new MoO3/SO4 2--TiO2 catalyst was prepared by a conventional impregnation of SO4 2-/TiO2 as carrier with an aqueous solution of ammonium molybdate and used for the synthesis of transesterification of dimethyl carbonate(DMC)with phenol.A series of MoO3/SO4 2--TiO2 catalysts with different MoO3 loadings were investigated and characterized using X-ray diffraction(XRD),Fourier transform infrared spectrometer(FTIR),NH3-temperature programmed desorption(NH3-TPD)and X-ray photoelectron spectroscopy(XPS).The results show that MoO3 loading is related to the activity of transesterification reaction.With the increase of MoO3 loading,the activity of transesterification reaction increases.The sulfur species in the catalyst have an influence on the molybdenum species,and lead to an increase in the electropositive of molybdenum,which promotes the catalytic activity of MoO3/SO4 2--TiO2.Among the series of catalysts prepared,MoO3/SO4 2--TiO2 with 10% MoO3 and 823 K calcinated is found to be the most active catalyst for transesterification reaction.Under the reaction conditions of 453 K and 12 h,the conversion of DMC is 30.5 %,and the yields of MPC and DPC reach 21.2 % and 8.7 %,respectively.

变换热交换器防堵和防腐

变换热交换器的腐蚀和堵塞是氮肥生产中的主要问题之一。 我厂变换工段工作压力为l.45MPa。1991年以前,我厂使用传统的列管式热交换器(管内走煤气、管间走变换气)经常不到半年时间,就会发生腐蚀和堵塞现象,被迫停车检修。通过多次解剖分析。

High-Performance AC-DC Power Electronic Converter Generator for Hybrid-Solar Vehicles

This paper describes the principles of operation and the physical model of an advanced AC-DC converter generator （with the electronic converter acting as an AC-DC rectifier with reverse-conducting MOSFETs （metal-oxide semiconductor field-effect transistors） as fast-electronic switches with a relatively low ON-state voltage drop） for HSVs. An AC-DC converter, when seen as an AC-DC rectifier, can be used in many fields, e.g., for multi-functional AC-DC/DC-AC convener generator^starter and conventional DC-AC convener motors and AC-DC converter generators or generator sets, welding machines, etc. The paper also describes a novel AC-DC convener, with reverse-conducting transistors and without the use of optoelectronic separation （which does not require a separate power supply）, which may be easily realized in IC （integrated-circuit） technology. Computer simulation allows for waveform evaluation for timing analysis of all components of the AC-DC-converter＇s physical model, both during normal operation as well as in some states of emergency. The paper also presents the results of bench experimental studies where the MOSFETs were used as fast-electronic switches with a relatively low ON-state voltage drop. For experimental studies, a novel AC-DC converter has been put together on the Mitsubishi FM600TU-3A module. The AC-DC converter with reverse-conducting transistors in a double-way connection has a lot of advantages compared to the conventional AC-DC convener acting as a diode rectifier, such as higher energy efficiency and greater reliability resulting from the lower temperature of electronic switches.

Influence of Humic Acid on Interaction of Ammonium and Potassium Ions on Clay Minerals

Interaction of ammonium (NH+4) and potassium (K+) is typical in field soils. However, the effects of organic matter on interaction of NH+4 and K+have not been thoroughly investigated. In this study, we examined the changes in major physicochemical properties of three clay minerals (kaolinite, illite, and montmorillonite) after humic acid (HA) coating and evaluated the influences of these changes on the interaction of NH+4 and K+on clay minerals using batch experiments. After HA coating, the cation exchange capacity (CEC) and specific surface area (SSA) of montmorillonite decreased significantly, while little decrease in CEC and SSA occurred in illite and only a slight increase in CEC was found in kaolinite. Humic acid coating significantly increased cation adsorption and preference for NH+4, and this effect was more obvious on clay minerals with a lower CEC. Results of Fourier transform infrared spectrometry analysis showed that HA coating promoted the formation of H-bonds between the adsorbed NH+4 and the organo-mineral complexes. HA coating increased cation fixation capacity on montmorillonite and kaolinite, but the opposite occurred on illite. In addition, HA coating increased the competitiveness of NH+4 on fixation sites. These results showed that HA coating affected both the nature of clay mineral surfaces and the reactions of NH+4 and K+with clay minerals, which might influence the availability of nutrient cations to plants in field soils amended with organic matter.

Compactness of the commutators of homogeneous singular integral operators

Let TΩ be the singular integral operator with kernel Ω（x）/｜x｜n where is homogeneous of degree zero, integrable and has mean value zero on the unit sphere Sn-1. In this paper, by Fourier transform estimates, Littlewood-Paley theory and approximation, the authors prove that if Ω∈（lnL）2 （Sn- 1）, then the commutator generated by TΩ and CMO（Rn） function, and the corresponding discrete maximal operator, are compact on LP（Rn, ｜s｜γp） for p∈ （1, ∞） and γp ∈ （-1, p-l）

The Majorana neutrino mass matrix indicated by the current data

The Majorana neutrino mass matrix combines information from the neutrino masses and the leptonic mixing in the flavor basis. Its invariance under some transformation matrices indicates the existence of certain residual symmetry. We offer an intuitive display of the structure of the Majorana neutrino mass matrix, using the whole set of the oscillation data. The structure is revealed depending on the lightest neutrino mass. We find that there are three regions with distinct characteristics of structure. A group effect and the μ-T exchange symmetry are observed. Six types of texture non-zeros are shown. Implications for flavor models are discussed.

Unexpected luminescence enhancement of upconverting nanocrystals by cation exchange with well retained small particle size

Highly luminescent upconversion nanoparticles （UCNPs） with small sizes are highly desirable for bioapplications. A facile in situ cation exchange strategy has been developed to greatly enhance the UC luminescence of hexagonal phase NaYF4 NPs while maintaining their small particle size and shape. Via a cation exchange treatment by hot-injecting Gd3＋ precursors into the as-prepared NPs solution without pre-separation, the naked-eye visible UC emission of the NPs was enhanced about 29 times under 980 nm near infrared （NIR） excitation with unchanged particle size. The cation exchange process was further demonstrated for the case of NaYF4 nanorods （NRs）. After the cation exchange, the nanorod was broken into two NPs with stronger emission. The cation exchanged hydrophobic UCNPs were further encapSulated with poly（amino acid） and successfully applied for targeted cancer cell UC luminescence imaging.