期刊文献+
共找到3篇文章
< 1 >
每页显示 20 50 100
水溶液中N-烷基亚胺二乙酸二氨铂(Ⅱ)配合物的^(13)C NMR研究
1
作者 江涛 杨志勇 +2 位作者 韩秀文 滕瑛 陆世维 《波谱学杂志》 CAS CSCD 1996年第2期113-120,共8页
在不同pH条件下以N-烷基亚胺二乙酸[R-N(CH2COOH)2,R=Me,i-Pr,n-Pr,HO—Et]为配体合成了一系列二氨铂(Ⅱ)类配合物.13CNMR(20MHz)研究结果表明该类配体均以N、O与铂配位,配... 在不同pH条件下以N-烷基亚胺二乙酸[R-N(CH2COOH)2,R=Me,i-Pr,n-Pr,HO—Et]为配体合成了一系列二氨铂(Ⅱ)类配合物.13CNMR(20MHz)研究结果表明该类配体均以N、O与铂配位,配位方式不随合成时pH值的改变而改变,在弱酸条件下,配合物处于交换平衡状态.平衡常数由不同pH下未配位羧基碳的化学位移计算而得. 展开更多
关键词 ^(13)C NMR 交换平衡态 铂配合物
下载PDF
Two-state energy model and experimental study of coal adsorb methane 被引量:2
2
作者 Zeng-Chao FENG Dong ZHAO Zhi-Xiang LIU Yan-Qi WANG Hong-Qiang GOU 《Journal of Coal Science & Engineering(China)》 2013年第4期488-492,共5页
There are two states of methane existing in coal, free methane and adsorptive methane. The two states of methane exchanged with each other which need the energy exchange with outside. It is released heat when methane ... There are two states of methane existing in coal, free methane and adsorptive methane. The two states of methane exchanged with each other which need the energy exchange with outside. It is released heat when methane adsorption on coal, instead of absorbed heat. According to the gas molecules Boltzmann energy distribution, is obtained the equilibrium equations of the two states of methane in coal, as well as the heat of adsorption equation when exchanged into each other. At the same time, high temperature experiments of methane adsorption on coal have been certificated to the theoretical model. At last the experimental results presented that: the two-state energy model could be accurately described the distribution of the two states of methane in the coal; the adsorption heat is related to the initial equilibrium state of methane adsorption; the adsorption heats are different with different coal ranks. 展开更多
关键词 two-state energy model adsorption heat chemical potential experimental study
下载PDF
Feedback control for manipulating magnetization in spin-exchange optical pumping system
3
作者 Ke Zhang Jun Li +2 位作者 Min Jiang Nan Zhao XinHua Peng 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2018年第8期27-32,共6页
Control of magnetization plays an important role in the scientific and technological field of manipulating spin systems. In this work, we study the problem of manipulating nuclear magnetization in the spin-exchange op... Control of magnetization plays an important role in the scientific and technological field of manipulating spin systems. In this work, we study the problem of manipulating nuclear magnetization in the spin-exchange optical pumping system, including accelerating the recovery of nuclear polarization and fixing it on a specific desired state. A real-time feedback control strategy is exploited here. We have also done some numerical simulations, with the results clearly demonstrating the effectiveness of our method, that the nuclear magnetization is able to be driven towards the equilibrium state at a much faster speed and also can be stabilized to a target state. We expect that our feedback control method can find applications in gyro experiments. 展开更多
关键词 optical pumping feedback control nuclear magnetic resonance state stabilization
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部